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公开(公告)号：US06001413A
公开(公告)日：1999-12-14
申请号：US36000
申请日：1998-03-06
摘要： Disclosed is a method for producing organic EL devices stably having intended capabilities. The method comprises cleaning an electrode-mounted substrate 17 followed by forming a plurality of film layers including organic layers and a counter electrode layer, on the electrode mounted on the substrate, successively one after another in vacuum, wherein the time just after the finish of cleaning the electrode-mounted substrate 17 and before the start of forming the first film layer on the electrode 12 is shorter than the time within which the value of the contact angle with water of the surface of the electrode 12 just after the finish of cleaning it increases by 30.degree. in vacuum. In producing organic EL devices having a plurality, n=1, 2, 3, . . . , of film layers on an electrode-mounted substrate, the time just after the finish of forming the n'th film layer and before the start of forming the next (n+1)'th film layer is shorter than the time within which the value of the contact angle with water of the surface of the n'th film layer just after having been formed increases by 30.degree. in vacuum. In the organic EL devices produced, the interfaces between the adjacent layers are protected from being contaminated with impurities.
摘要翻译： 公开了一种稳定地具有预期能力的有机EL器件的制造方法。 该方法包括清洁电极安装的基板17，随后在真空中依次连续地在安装在基板上的电极上形成包括有机层和对电极层的多个膜层，其中刚刚完成之后的时间 清洁电极安装基板17，并且在电极12上开始形成第一膜层之前，比刚刚完成清洁之后电极12的表面与水的接触角的值的时间短 在真空中增加30°。 在制造具有多个n = 1,2,3的有机EL器件时。 。 。 在电极安装基板上的薄膜层，形成第n薄膜层之后的时间和形成下一个（n + 1）薄膜层之前的时间短于其中 刚刚形成第n层的表面与水接触角的值在真空中增加30°。 在所生产的有机EL器件中，相邻层之间的界面被保护以免被杂质污染。
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公开(公告)号：US5336546A
公开(公告)日：1994-08-09
申请号：US971817
申请日：1993-02-03
CPC分类号： H05B33/14 , C09K11/06 , H01L51/0069 , H01L51/007 , H01L2251/308 , H01L51/005 , H01L51/5012 , H01L51/5092 , Y10S428/917 , Y10T428/24917 , Y10T428/31688
摘要： An organic electroluminescence device including an oxadiazole or thiadiazole compound interposed between two electrons. The compound is of the formula ##STR1## wherein Z.sup.1 and Z.sup.2 are each an unsubstituted or substituted aromatic group; Y.sup.1 and Y.sup.2 are each an unsubstituted or substituted aromatic group; Q is --O--, --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --; or --C(CH.sub.3).sub.2 ; and X is --O-- or --S--. The organic electroluminescence device has a high brightness, a high luminous efficiency and a long service life.
摘要翻译： PCT No.PCT / JP92 / 00835 Sec。 371日期：1993年2月3日 102（e）日期1993年2月3日PCT提交1992年7月2日PCT公布。 出版物WO93 / 01252 日期：1993年1月21日。一种有机电致发光器件，其包括插入在两个电子之间的恶二唑或噻二唑化合物。 该化合物具有下式：其中Z 1和Z 2各自为未取代或取代的芳族基团; Y1和Y2各自为未取代或取代的芳族基团; Q是-O-，-CH 2 - ， - CH 2 -CH 2 - ; 或-C（CH 3）2; X是-O-或-S-。 有机电致发光元件的亮度高，发光效率高，使用寿命长。
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公开(公告)号：US07501189B2
公开(公告)日：2009-03-10
申请号：US11254852
申请日：2005-10-21
IPC分类号： H01L51/54
CPC分类号： H01L51/006 , C07C211/54 , C07C211/58 , C07C211/61 , C07C2601/14 , C07C2603/24 , C07C2603/54 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , H01L51/0052 , H01L51/0054 , H01L51/0056 , H01L51/0058 , H01L51/007 , H01L51/0081 , H01L51/5036 , H01L2251/308 , H05B33/14 , Y10S428/917 , Y10T428/24942
摘要： A white organic electroluminescent device (1) including an emitting layer (5, 6 and 7) interposed between an anode (2) and a cathode (9), the emitting layer (5, 6 and 7) emitting blue light, green light and red light, the emitting layer (6) containing a green dopant that is an aromatic amine compound represented by formula (1), wherein A1, A2 and R12 are a hydrogen atom, an alkyl group, an aryl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an arylamino group, an alkylamino group or a halogen atom; d and e are independently 1 to 5; h is 1 to 9; R11 is a secondary or tertiary alkyl or cycloalkyl group; f is 1 to 9; g is 0 to 8 and f+g+h is 2 to 10.
摘要翻译： 一种白色有机电致发光器件（1），包括介于阳极（2）和阴极（9）之间的发射层（5,6和7），发射蓝光的发光层（5,6和7），绿光和 红色光，包含作为由式（1）表示的芳族胺化合物的绿色掺杂剂的发光层（6），其中A1，A2和R12是氢原子，烷基，芳基，环烷基， 烷氧基，芳氧基，芳基氨基，烷基氨基或卤素原子; d和e独立地为1〜5; h为1〜9; R11是仲或叔烷基或环烷基; f为1〜9; g为0〜8，f + g + h为2〜10。
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14.发明申请公开(公告)号：US20140014183A1
公开(公告)日：2014-01-16
申请号：US14001844
申请日：2012-03-29
申请人： Ryoji Maeda , Hiroshi Tokailin
发明人： Ryoji Maeda , Hiroshi Tokailin
IPC分类号： H01L51/00
CPC分类号： H01L51/0078 , B82Y10/00 , H01L51/0046 , H01L51/0056 , H01L51/0059 , H01L51/006 , H01L51/0064 , H01L51/008 , H01L51/4246 , H01L2251/308 , Y02E10/549
摘要： An organic thin film solar cell including a cathode, a charge-generating layer and an anode being sequentially stacked, which further comprises a charge-transporting layer having a carrier mobility of 1×10−9 cm2/Vs or more at an electric field intensity of 0 V/cm between the cathode and the charge-generating layer and/or between the anode and the charge-generating layer.
摘要翻译： 包括依次堆叠的阴极，电荷产生层和阳极的有机薄膜太阳能电池，还包括电场强度为1×10 -9 cm 2 / Vs以上的载流子迁移率的电荷输送层 在阴极和电荷产生层之间和/或阳极和电荷产生层之间为0V / cm。
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15.发明申请PHENANTHROLINE COMPOUND, ELECTRON TRANSPORT MATERIAL OBTAINED FROM SAID COMPOUND, AND ORGANIC THIN-FILM SOLAR CELL COMPRISING SAID COMPOUND 审中-公开苯并噻唑化合物，由化合物获得的电子运输材料和包含化合物的有机薄膜太阳能电池公开(公告)号：US20130180590A1
公开(公告)日：2013-07-18
申请号：US13812448
申请日：2011-07-27
申请人： Keiichi Yasukawa , Ryoji Maeda , Hiroshi Tokailin
发明人： Keiichi Yasukawa , Ryoji Maeda , Hiroshi Tokailin
IPC分类号： H01L51/00 , H01G9/20 , C07D471/04
CPC分类号： H01L51/0072 , B82Y10/00 , C07D471/04 , C09B57/00 , H01G9/2009 , H01G9/2072 , H01L51/0046 , H01L51/0056 , H01L51/006 , H01L51/424 , H01L51/4273 , H01L2251/308 , Y02E10/549
摘要： A compound represented by the following formula (1), wherein L is a single bond or a divalent group, and is bonded at any one of the 6th, 8th and the 9th positions indicated by * of 1,10-phenanthroline; Rg is a substituted or unsubstituted benzene ring or a substituted or unsubstituted naphthalene ring; and X is an oxygen atom or N—R4.
摘要翻译： 由下式（1）表示的化合物，其中L是单键或二价基团，并且在1,10-菲咯啉的*表示的第6位，第8位和第9位的任何一个上键合; Rg是取代或未取代的苯环或取代或未取代的萘环; X为氧原子或N-R4。
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公开(公告)号：US20060127698A1
公开(公告)日：2006-06-15
申请号：US11254852
申请日：2005-10-21
CPC分类号： H01L51/006 , C07C211/54 , C07C211/58 , C07C211/61 , C07C2601/14 , C07C2603/24 , C07C2603/54 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , H01L51/0052 , H01L51/0054 , H01L51/0056 , H01L51/0058 , H01L51/007 , H01L51/0081 , H01L51/5036 , H01L2251/308 , H05B33/14 , Y10S428/917 , Y10T428/24942
摘要： A white organic electroluminescent device (1) including an emitting layer (5, 6 and 7) interposed between an anode (2) and a cathode (9), the emitting layer (5, 6 and 7) emitting blue light, green light and red light, the emitting layer (6) containing a green dopant that is an aromatic amine compound represented by formula (1), wherein A1, A2 and R12 are a hydrogen atom, an alkyl group, an aryl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an arylamino group, an alkylamino group or a halogen atom; d and e are independently 1 to 5; h is 1 to 9; R11 is a secondary or tertiary alkyl or cycloalkyl group; f is 1 to 9; g is 0 to 8 and f+g+h is 2 to 10.
摘要翻译： 一种白色有机电致发光器件（1），包括介于阳极（2）和阴极（9）之间的发射层（5,6和7），发射蓝光的发光层（5,6和7），绿光和 红光，包含作为由式（1）表示的芳族胺化合物的绿色掺杂剂的发光层（6），其中A 1，A 2和R 2 > 12是氢原子，烷基，芳基，环烷基，烷氧基，芳氧基，芳基氨基，烷基氨基或卤素原子; d和e独立地为1〜5; h为1〜9; R 11是仲或叔烷基或环烷基; f为1〜9; g为0〜8，f + g + h为2〜10。
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公开(公告)号：US06786789B2
公开(公告)日：2004-09-07
申请号：US09809244
申请日：2001-03-16
申请人： Toshio Sakai , Mitsuru Eida , Hiroshi Tokailin
发明人： Toshio Sakai , Mitsuru Eida , Hiroshi Tokailin
IPC分类号： H01J926
CPC分类号： H01L51/56 , C02F3/04 , C02F3/101 , C05F17/00 , H01L21/67236 , H01L51/0001 , H01L51/0096 , H01L51/524 , H05B33/10 , Y02E10/549 , Y02P20/145 , Y02P70/521 , Y02W10/15 , Y02W30/43
摘要： Provided are a producing apparatus and a producing process which make it possible to obtain effectively an organic EL display device capable of suppressing the generation of dark spots for a long time even in a high temperature environment. Therefore, an apparatus for producing an organic EL display device comprises a first unit for carrying a supporting substrate in, a second unit for heating at least the supporting substrate before forming an organic luminescence medium, thereby performing a dehydration treatment, a third unit for forming the organic luminescence medium and an upper element, and a fourth unit for sealing the periphery of the apparatus with a sealing member, wherein the first unit is arranged between the second unit and the third unit, a first carrying device is set up in the first unit, and a second carrying device is arranged between the third unit and the fourth unit.
摘要翻译： 提供一种能够有效地获得即使在高温环境下能够长时间抑制黑斑产生的有机EL显示装置的制造装置和制造方法。因此，有机EL显示器的制造装置 装置包括用于承载支撑衬底的第一单元，用于在形成有机发光介质之前至少加热支撑衬底的第二单元，从而进行脱水处理，用于形成有机发光介质的第三单元和上部元件，以及 第四单元，用于用密封构件密封设备的周边，其中第一单元布置在第二单元和第三单元之间，第一承载装置设置在第一单元中，第二承载装置设置在第二单元之间， 第三单位和第四单位。
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18.发明授权公开(公告)号：US06633121B2
公开(公告)日：2003-10-14
申请号：US09767018
申请日：2001-01-23
IPC分类号： H05B3304
CPC分类号： H05B33/10 , H01L27/322 , H01L27/3244 , H01L27/3295 , H01L51/5088 , H01L51/5092 , H01L51/5237 , H01L51/5284 , H01L51/56 , H05B33/04
摘要： An organic electroluminescent device including a lower electrode, an organic light-emission medium, and an upper electrode on a support substrate, wherein the water content of the organic light-emission medium does not exceed 0.05 wt. %. By so controlling the water content of the organic light-emission medium, it is possible to prevent shrinkage of a light-emission area based on production of non-emission parts or non-emission spots for a long time at both high temperature and room temperature conditions. A method of making the organic electroluminescent device is disclosed also.
摘要翻译： 一种有机电致发光器件，包括在支撑衬底上的下电极，有机发光介质和上电极，其中有机发光介质的含水量不超过0.05重量％。 ％。 通过这样控制有机发光介质的含水量，可以防止在高温和室温下长时间产生非发射部分或非发光斑点的发光区域的收缩 条件。 还公开了制造有机电致发光器件的方法
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公开(公告)号：US07210979B2
公开(公告)日：2007-05-01
申请号：US10802802
申请日：2004-03-18
申请人： Toshio Sakai , Mitsuru Eida , Hiroshi Tokailin
发明人： Toshio Sakai , Mitsuru Eida , Hiroshi Tokailin
IPC分类号： H01J9/24
CPC分类号： H01L51/56 , C02F3/04 , C02F3/101 , C05F17/00 , H01L21/67236 , H01L51/0001 , H01L51/0096 , H01L51/524 , H05B33/10 , Y02E10/549 , Y02P20/145 , Y02P70/521 , Y02W10/15 , Y02W30/43
摘要： Provided are a producing apparatus and a producing process which make it possible to obtain effectively an organic EL display device capable of suppressing the generation of dark spots for a long time even in a high temperature environment. Therefore, an apparatus for producing an organic EL display device comprises a first unit for carrying a supporting substrate in, a second unit for heating at least the supporting substrate before forming an organic luminescence medium, thereby performing a dehydration treatment, a third unit for forming the organic luminescence medium and an upper element, and a fourth unit for sealing the periphery of the apparatus with a sealing member, wherein the first unit is arranged between the second unit and the third unit, a first carrying device is set up in the first unit, and a second carrying device is arranged between the third unit and the fourth unit.
摘要翻译： 提供一种制造装置和制造方法，其能够有效地获得能够长时间即使在高温环境下也能够抑制黑斑的产生的有机EL显示装置。 因此，有机EL显示装置的制造装置包括：第一单元，用于承载支撑基板;第二单元，用于在形成有机发光介质之前至少加热支撑基板，从而进行脱水处理;第三单元，用于形成 有机发光介质和上部元件;以及第四单元，用于用密封构件密封设备的周边，其中第一单元布置在第二单元和第三单元之间，第一承载装置设置在第一 单元，并且第二承载装置布置在第三单元和第四单元之间。
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公开(公告)号：US20070075635A1
公开(公告)日：2007-04-05
申请号：US11439272
申请日：2006-05-24
IPC分类号： H01L51/54
CPC分类号： H01L51/5048 , H01L51/0058 , H01L51/0059 , H01L51/006 , H01L51/0081 , H01L51/5088 , H01L2251/308 , Y10T428/24942
摘要： An organic electroluminescent device (1) comprising, a cathode (80), an anode (20), an emitting layer (50) provided between the cathode and the anode, and at least a first layer (30) and a second layer (40) stacked between the anode (20) and the emitting layer (50) in this order from the anode (20) side, the first layer (30) having a hole mobility of 7.0×10−4 (cm2/Vs, electric field intensity: 2.5×104 (V/cm)) or more, the second layer (40) having a hole mobility of 7.0×10−4 (cm2/Vs, electric field intensity: 2.5×104 (V/cm)) or more, and a main compound which forms the first layer (30) differing from a main compound which forms the second layer (40).
摘要翻译： 一种有机电致发光器件（1），包括阴极（80），阳极（20），设置在阴极和阳极之间的发光层（50），以及至少第一层（30）和第二层（40） ）从阳极（20）侧依次堆叠在阳极（20）和发光层（50）之间，第一层（30）的空穴迁移率为7.0×10 -4（cm （V / cm））或更高，第二层（40）的空穴迁移率为7.0×10 6（V / cm） -4（cm 2 / Vs，电场强度：2.5×10 4（V / cm））以上，形成第一 层（30）与形成第二层（40）的主化合物不同。
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