公开(公告)号：US08622780B2

公开(公告)日：2014-01-07

申请号：US13402974

申请日：2012-02-23

申请人： Hisao Ikeda ,  Junichiro Sakata ,  Satoshi Seo ,  Yuji Iwaki

发明人： Hisao Ikeda ,  Junichiro Sakata ,  Satoshi Seo ,  Yuji Iwaki

IPC分类号： H01J9/24

CPC分类号： C23C14/505 ,  C23C14/044 ,  C23C14/24 ,  C23C14/548 ,  H01L51/001 ,  H01L51/006 ,  H01L51/5052 ,  H01L51/5088 ,  H01L2251/5315 ,  H01L2251/5323 ,  H05B33/10 ,  H05B33/22

摘要： To provide a light-emitting element and a light-emitting device which can be designed and manufactured with redundancy. A light-emitting element of the invention includes a pair of electrode, and a layer containing a light-emissive substance between the pair of electrodes. The layer containing a light-emissive substance includes a layer containing a composite material, and the layer containing a composite material includes an organic compound and an inorganic compound. The concentration ratio of the organic compound to the inorganic compound changes periodically. The layer containing a composite maternal can be changed in electrical characteristics without changing the composition ratio of the organic compound to the inorganic compound in the layer or changing the kind of compounds used for the layer.

摘要翻译： 提供可以冗余设计和制造的发光元件和发光器件。 本发明的发光元件包括一对电极和在该对电极之间含有发光物质的层。 包含发光物质的层包括含有复合材料的层，并且包含复合材料的层包括有机化合物和无机化合物。 有机化合物与无机化合物的浓度比周期性变化。 含有复合母体的层可以改变电特性，而不改变层中的有机化合物与无机化合物的组成比，或改变用于该层的化合物的种类。

公开(公告)号：US08586197B2

公开(公告)日：2013-11-19

申请号：US11884548

申请日：2006-02-21

申请人： Shunpei Yamazaki ,  Hisao Ikeda ,  Satoshi Seo ,  Junichiro Sakata ,  Yuji Iwaki

发明人： Shunpei Yamazaki ,  Hisao Ikeda ,  Satoshi Seo ,  Junichiro Sakata ,  Yuji Iwaki

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： H01L51/5278 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/186 ,  H01L51/0059 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5048 ,  H01L2251/305 ,  H01L2251/308 ,  H01L2251/5315 ,  H01L2251/5323 ,  H05B33/14

摘要： A composite material includes an organic compound represented by the following general formula (1) and an inorganic compound, where, in the general formula (1), R1 to R24 is identical to or different from one another, and represent any of hydrogen, an alkyl group, an alkoxy group, an aryl group, and an arylalkyl group. A light emitting element includes the composite material and a light emitting device and an electronic appliance includes the light emitting element. The composite material has an excellent carrier transporting property and an excellent carrier injecting property with respect to the organic compound along with high visible light transmittance. By utilizing the composite material, a current excitation type light emitting element requiring low driving voltage and having excellent light emitting efficiency is obtained. By using the light emitting element, a light emitting device consuming low power and an electronic appliance including the light emitting device is provided.

摘要翻译： 复合材料包括由以下通式（1）表示的有机化合物和无机化合物，其中在通式（1）中，R 1至R 24彼此相同或不同，并且表示氢， 烷基，烷氧基，芳基和芳基烷基。 发光元件包括复合材料，发光器件和电子器件包括发光元件。 该复合材料具有优异的载流子传输性能和相对于有机化合物的优异载流子注入性以及高可见光透射率。 通过利用复合材料，可以获得需要低驱动电压且发光效率优异的电流激励型发光元件。 通过使用发光元件，提供消耗低功率的发光器件和包括发光器件的电子器件。

公开(公告)号：US08541114B2

公开(公告)日：2013-09-24

申请号：US13568155

申请日：2012-08-07

申请人： Yuji Iwaki ,  Satoshi Seo ,  Takahiro Kawakami ,  Hisao Ikeda ,  Junichiro Sakata ,  Tomoya Aoyama

发明人： Yuji Iwaki ,  Satoshi Seo ,  Takahiro Kawakami ,  Hisao Ikeda ,  Junichiro Sakata ,  Tomoya Aoyama

IPC分类号： H05B33/12

CPC分类号： H01L51/0052 ,  H01L51/0071 ,  H01L51/0081 ,  H01L51/5052 ,  H01L51/5088 ,  H05B33/22 ,  Y10S428/917

摘要： A light emitting device comprises a pair of electrodes and a mixed layer provided between the pair of electrodes. The mixed layer contains an organic compound which contains no nitrogen atoms, i.e., an organic compound which dose not have an arylamine skeleton, and a metal oxide. As the organic compound, an aromatic hydrocarbon having an anthracene skeleton is preferably used. As such an aromatic hydrocarbon, t-BuDNA, DPAnth, DPPA, DNA, DMNA, t-BuDBA, and the like are listed. As the metal oxide, molybdenum oxide, vanadium oxide, ruthenium oxide, rhenium oxide, and the like are preferably used. Further, the mixed layer preferably shows absorbance per 1 μm of 1 or less or does not show a distinct absorption peak in a spectrum of 450 to 650 nm when an absorption spectrum is measured.

摘要翻译： 发光器件包括一对电极和设置在该对电极之间的混合层。 混合层含有不含氮原子的有机化合物即不具有芳胺骨架的有机化合物和金属氧化物。 作为有机化合物，优选使用具有蒽骨架的芳香族烃。 作为这样的芳烃，列举了t-BuDNA，DPAnth，DPPA，DNA，DMNA，t-BuDBA等。 作为金属氧化物，优选使用氧化钼，氧化钒，氧化钌，氧化铼等。 此外，当测量吸收光谱时，混合层优选显示1个或更少的1个吸光度，或者在450-650nm的光谱中不显示不同的吸收峰。

公开(公告)号：US20090058267A1

公开(公告)日：2009-03-05

申请号：US10584308

申请日：2005-11-28

申请人： Harue Nakashima ,  Sachiko Kawakami ,  Daisuke Kumaki ,  Satoshi Seo ,  Hisao Ikeda ,  Junichiro Sakata ,  Yuji Iwaki

发明人： Harue Nakashima ,  Sachiko Kawakami ,  Daisuke Kumaki ,  Satoshi Seo ,  Hisao Ikeda ,  Junichiro Sakata ,  Yuji Iwaki

IPC分类号： H01J1/63

CPC分类号： H01L51/0059 ,  H01L27/3244 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0069 ,  H01L51/0072 ,  H01L51/5052 ,  H01L51/5206 ,  H01L2251/5315 ,  H01L2251/5323

摘要： One object of the present invention is to provide a light emitting element that includes an organic compound and an inorganic compound and has low driving voltage. The light emitting element of the invention includes a plurality of layers between a pair of electrodes, wherein the plurality of layers includes a layer that contains a carbazole derivative represented by a general formula (1) and an inorganic compound exhibiting an electron accepting property with respect to the carbazole derivative. By utilizing this structure, electrons are transported between the carbazole derivative and the inorganic compound and carriers are internally generated, and hence, the driving voltage of the light emitting element can be reduced.

摘要翻译： 本发明的一个目的是提供一种包含有机化合物和无机化合物并具有低驱动电压的发光元件。 本发明的发光元件包括一对电极之间的多个层，其中多个层包括含有由通式（1）表示的咔唑衍生物的层和表现出电子接受性的无机化合物 涉及咔唑衍生物。 通过利用这种结构，电子在咔唑衍生物和无机化合物之间传输，并且载体在内部产生，因此可以降低发光元件的驱动电压。

公开(公告)号：US20090026917A1

公开(公告)日：2009-01-29

申请号：US11909051

申请日：2006-04-10

申请人： Hisao Ikeda ,  Junichiro Sakata ,  Satoshi Seo ,  Yuji Iwaki

发明人： Hisao Ikeda ,  Junichiro Sakata ,  Satoshi Seo ,  Yuji Iwaki

IPC分类号： H01J1/62 ,  C23C16/00

CPC分类号： C23C14/505 ,  C23C14/044 ,  C23C14/24 ,  C23C14/548 ,  H01L51/001 ,  H01L51/006 ,  H01L51/5052 ,  H01L51/5088 ,  H01L2251/5315 ,  H01L2251/5323 ,  H05B33/10 ,  H05B33/22

摘要： To provide a light-emitting element and a light-emitting device which can be designed and manufactured with redundancy. A light-emitting element of the invention includes a pair of electrode, and a layer containing a light-emissive substance between the pair of electrodes. The layer containing a light-emissive substance includes a layer containing a composite material, and the layer containing a composite material includes an organic compound and an inorganic compound. The concentration ratio of the organic compound to the inorganic compound changes periodically. The layer containing a composite maternal can be changed in electrical characteristics without changing the composition ratio of the organic compound to the inorganic compound in the layer or changing the kind of compounds used for the layer.

摘要翻译： 提供可以冗余设计和制造的发光元件和发光器件。 本发明的发光元件包括一对电极和在该对电极之间含有发光物质的层。 包含发光物质的层包括含有复合材料的层，并且包含复合材料的层包括有机化合物和无机化合物。 有机化合物与无机化合物的浓度比周期性变化。 含有复合母体的层可以改变电特性，而不改变层中的有机化合物与无机化合物的组成比，或改变用于该层的化合物的种类。

公开(公告)号：US20060263638A1

公开(公告)日：2006-11-23

申请号：US11435996

申请日：2006-05-18

申请人： Takahiro Kawakami ,  Tomoya Aoyama ,  Junichiro Sakata ,  Hisao Ikeda ,  Satoshi Seo ,  Yuji Iwaki

发明人： Takahiro Kawakami ,  Tomoya Aoyama ,  Junichiro Sakata ,  Hisao Ikeda ,  Satoshi Seo ,  Yuji Iwaki

IPC分类号： H01L51/54 ,  H05B33/12

CPC分类号： H01L51/5088 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0081 ,  H01L51/5092

摘要： It is an object of the present invention to provide a functional layer for protecting a light emitting element from being deteriorated by a physical or chemical influence when the light emitting element is manufactured or driven, and to attain extension of lifetime of an element and improvement of element characteristics without increasing a drive voltage and degrading transmittance and color purity by providing such a functional layer. One feature of the present invention is to provide a buffer layer made of a composite material for a light emitting element including aromatic hydrocarbon containing at least one vinyl skeleton and metal oxide in part of a light emitting substance containing layer, in the light emitting element formed by interposing the light emitting substance containing layer between a pair of electrodes. The composite material for a light emitting element for forming the buffer layer of the present invention has high conductivity and is superior in transparency.

摘要翻译： 本发明的目的是提供一种功能层，用于在制造或驱动发光元件时保护发光元件免受物理或化学影响而劣化，并且使元件的使用寿命延长 元件特性，而不增加驱动电压并通过提供这样的功能层降低透射率和色纯度。 本发明的一个特征是提供一种由发光元件的复合材料制成的缓冲层，该发光元件包括含有至少一种乙烯基骨架的芳族烃和部分含有发光物质的层中的金属氧化物，在形成的发光元件中 通过将发光物质含有层插入在一对电极之间。 本发明的缓冲层形成用发光元件用复合材料的导电性高，透明性优异。

公开(公告)号：US20120149140A1

公开(公告)日：2012-06-14

申请号：US13402974

申请日：2012-02-23

申请人： Hisao Ikeda ,  Junichiro Sakata ,  Satoshi Seo ,  Yuji Iwaki

发明人： Hisao Ikeda ,  Junichiro Sakata ,  Satoshi Seo ,  Yuji Iwaki

IPC分类号： H01L33/02

CPC分类号： C23C14/505 ,  C23C14/044 ,  C23C14/24 ,  C23C14/548 ,  H01L51/001 ,  H01L51/006 ,  H01L51/5052 ,  H01L51/5088 ,  H01L2251/5315 ,  H01L2251/5323 ,  H05B33/10 ,  H05B33/22

摘要： To provide a light-emitting element and a light-emitting device which can be designed and manufactured with redundancy. A light-emitting element of the invention includes a pair of electrode, and a layer containing a light-emissive substance between the pair of electrodes. The layer containing a light-emissive substance includes a layer containing a composite material, and the layer containing a composite material includes an organic compound and an inorganic compound. The concentration ratio of the organic compound to the inorganic compound changes periodically. The layer containing a composite maternal can be changed in electrical characteristics without changing the composition ratio of the organic compound to the inorganic compound in the layer or changing the kind of compounds used for the layer.

摘要翻译： 提供可以冗余设计和制造的发光元件和发光器件。 本发明的发光元件包括一对电极和在该对电极之间含有发光物质的层。 包含发光物质的层包括含有复合材料的层，并且包含复合材料的层包括有机化合物和无机化合物。 有机化合物与无机化合物的浓度比周期性变化。 含有复合母体的层可以改变电特性，而不改变层中的有机化合物与无机化合物的组成比，或改变用于该层的化合物的种类。

公开(公告)号：US07883788B2

公开(公告)日：2011-02-08

申请号：US12859811

申请日：2010-08-20

申请人： Takahiro Kawakami ,  Tomoya Aoyama ,  Junichiro Sakata ,  Hisao Ikeda ,  Satoshi Seo ,  Yuji Iwaki

发明人： Takahiro Kawakami ,  Tomoya Aoyama ,  Junichiro Sakata ,  Hisao Ikeda ,  Satoshi Seo ,  Yuji Iwaki

IPC分类号： H05B33/12

CPC分类号： H01L51/5088 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0081 ,  H01L51/5092

摘要： It is an object of the present invention to provide a functional layer for protecting a light emitting element from being deteriorated by a physical or chemical influence when the light emitting element is manufactured or driven, and to attain extension of lifetime of an element and improvement of element characteristics without increasing a drive voltage and degrading transmittance and color purity by providing such a functional layer. One feature of the present invention is to provide a buffer layer made of a composite material for a light emitting element including aromatic hydrocarbon containing at least one vinyl skeleton and metal oxide in part of a light emitting substance containing layer, in the light emitting element fowled by interposing the light emitting substance containing layer between a pair of electrodes. The composite material for a light emitting element for forming the buffer layer of the present invention has high conductivity and is superior in transparency.

摘要翻译： 本发明的目的是提供一种功能层，用于在制造或驱动发光元件时保护发光元件免受物理或化学影响而劣化，并且使元件的使用寿命延长 元件特性，而不增加驱动电压并通过提供这样的功能层降低透射率和色纯度。 本发明的一个特征是提供一种由发光元件的复合材料构成的缓冲层，所述缓冲层包含发光元件的一部分中包含至少一个乙烯基骨架的芳族烃和部分发光物质含有层中的金属氧化物， 通过将发光物质含有层插入在一对电极之间。 本发明的缓冲层形成用发光元件用复合材料的导电性高，透明性优异。

公开(公告)号：US20090026922A1

公开(公告)日：2009-01-29

申请号：US11918569

申请日：2006-04-17

申请人： Yuji Iwaki ,  Satoshi Seo ,  Takahiro Kawakami ,  Hisao Ikeda ,  Junichiro Sakata

发明人： Yuji Iwaki ,  Satoshi Seo ,  Takahiro Kawakami ,  Hisao Ikeda ,  Junichiro Sakata

IPC分类号： H01J63/04

CPC分类号： H01L51/5048

摘要： One aspect of the present invention is a light emitting element having a layer including an aromatic hydrocarbon and a metal oxide between a pair of electrodes. The kind of aromatic hydrocarbon is not particularly limited; however, an aromatic hydrocarbon having hole mobility of 1×10−6 cm2/Vs or more is preferable. As such aromatic hydrocarbon, for example, 2-tert-butyl-9,10-di(2-naphthyl)anthracene, anthracene, 9,10-diphenylanthracene, tetracene, rubrene, perylene, 2,5,8,11-tetra(tert-butyl)perylene, and the like are given. As the metal oxide, a metal which shows an electron-accepting property to the aromatic hydrocarbon is preferable. As such metal oxide, for example, molybdenum oxide, vanadium oxide, ruthenium oxide, rhenium oxide, and the like are given.

摘要翻译： 本发明的一个方面是具有在一对电极之间具有芳香族烃和金属氧化物的层的发光元件。 芳烃的种类没有特别限定， 然而，优选空穴迁移率为1×10 -6 cm 2 / Vs以上的芳香族烃。 作为这样的芳烃，例如，2-叔丁基-9,10-二（2-萘基）蒽，蒽，9,10-二苯基蒽，并四苯，红荧烯，苝，2,5,8,11-四 叔丁基）苝等。 作为金属氧化物，优选对芳族烃表现出电子接受性的金属。 作为这样的金属氧化物，例如可以举出氧化钼，氧化钒，氧化钌，氧化铼等。

公开(公告)号：US20080136325A1

公开(公告)日：2008-06-12

申请号：US11884548

申请日：2006-02-21

申请人： Shunpei Yamazaki ,  Hisao Ikeda ,  Satoshi Seo ,  Junichiro Sakata ,  Yuji Iwaki

发明人： Shunpei Yamazaki ,  Hisao Ikeda ,  Satoshi Seo ,  Junichiro Sakata ,  Yuji Iwaki

IPC分类号： H01J1/62 ,  C09K11/06

CPC分类号： H01L51/5278 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/186 ,  H01L51/0059 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5048 ,  H01L2251/305 ,  H01L2251/308 ,  H01L2251/5315 ,  H01L2251/5323 ,  H05B33/14

摘要： A composite material includes an organic compound represented by the following general formula (1) and an inorganic compound, where, in the general formula (1), R1 to R24 is identical to or different from one another, and represent any of hydrogen, an alkyl group, an alkoxy group, an aryl group, and an arylalkyl group. A light emitting element includes the composite material and a light emitting device and an electronic appliance includes the light emitting element. The composite material has an excellent carrier transporting property and an excellent carrier injecting property with respect to the organic compound along with high visible light transmittance. By utilizing the composite material, a current excitation type light emitting element requiring low driving voltage and having excellent light emitting efficiency is obtained. By using the light emitting element, a light emitting device consuming low power and an electronic appliance including the light emitting device is provided.

摘要翻译： 复合材料包括由以下通式（1）表示的有机化合物和无机化合物，其中在通式（1）中，R 1至R 24 彼此相同或不同，并且表示氢，烷基，烷氧基，芳基和芳烷基中的任一个。 发光元件包括复合材料，发光器件和电子器件包括发光元件。 该复合材料具有优异的载流子传输性能和相对于有机化合物的优异载流子注入性以及高可见光透射率。 通过利用复合材料，可以获得需要低驱动电压且发光效率优异的电流激励型发光元件。 通过使用发光元件，提供消耗低功率的发光器件和包括发光器件的电子器件。