公开(公告)号：US4659856A

公开(公告)日：1987-04-21

申请号：US775138

申请日：1985-09-12

Applicant: Hartmut Springer ,  Gerd Konig

Inventor： Hartmut Springer ,  Gerd Konig

IPC: C07C317/18 ,  C07C381/02 ,  C07F9/09 ,  D06P1/651 ,  C07C141/18 ,  C07C69/017 ,  C07C147/10 ,  C07F9/145

CPC classification number: D06P1/65193 ,  C07C317/18 ,  C07C381/02 ,  C07F9/091

Abstract: Compounds of the general formula (1) ##STR1## in which the Zs, preferably identical to each other, each denote a hydroxy group or a sulfato, thiosulfato or phosphato group. They can be prepared by first converting biphenyl by sulfochlorination into biphenyl-4,4'-disulfochloride, then reducing the latter with an alkali metal or alkaline earth metal sulfite or hydrogensulfite to sulfinic acid, and in turn reacting the latter with ethylene oxide to give 4,4'-bis-(.beta.-hydroxyethylsulfonyl)-biphenyl, which can be esterified in conventional manner. They are used for modifying and improving the physical and coloristic properties of materials made of natural and/or synthetic polyamide fibers and/or polyurethane fibers and as auxiliaries in dyeing processes for such fiber materials.

Abstract translation: 其中Z，优选彼此相同的通式（1）的化合物（1）各自表示羟基或硫酸根，硫代硫酸根或磷酸根。 它们可以通过首先通过磺基氯化将联苯转化为联苯-4,4'-二磺酰氯，然后用碱金属或碱土金属亚硫酸盐或亚硫酸氢盐将其还原成亚磺酸，然后将其与环氧乙烷反应，得到 4,4'-双 - （β-羟乙基磺酰基） - 联苯，其可以常规方式酯化。 它们用于改善和改善由天然和/或合成聚酰胺纤维和/或聚氨酯纤维制成的材料的物理和色彩特性，并用作这种纤维材料的染色工艺中的助剂。

公开(公告)号：US4033980A

公开(公告)日：1977-07-05

申请号：US281790

申请日：1972-08-18

Applicant: Fritz Meininger ,  Klaus Hunger ,  Hartmut Springer

Inventor： Fritz Meininger ,  Klaus Hunger ,  Hartmut Springer

IPC: C09B47/26 ,  C09B62/457 ,  C09B47/04

CPC classification number: C09B62/457 ,  C09B47/26

Abstract: A water-soluble phthalocyanine dyestuff of the formula ##STR1## IN WHICH Pc represents copper phthalocyanine, nickel phthalocyanine or cobalt phthalocyanine, R.sub.3 represents lower alkyl, B represents --CH.sub.2 --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --NH--, ##STR2## A represents phenylene or phenylene substituted by lower alkyl, lower alkoxy, carboxyl, hydroxyl, sulfo, nitro, chlorine or bromine, or naphthylene, X represents --CH.sub.2 -- or ##STR3## R.sub.1 and R.sub.2 each stand for hydrogen, lower alkyl, hydroxyethyl, sulfoethyl, carboxyethyl, benzyl, phenyl, carboxyphenylene or sulfophenylene, or together with the nitrogen atom piperidyl or morpholyl, n and m each represent 0 or 1, a, b and c each stand for a number from 1 to 4, the sum of a, b and c being at most 6, said dyestuff being suitable for the dyeing or printing of leather or textile materials consisting of native or regenerated cellulose, silk or polyamides, the dyeings and prints obtained on said materials being distinguished by deep tints and very good fastness properties to light and to wetting.

Abstract translation: 下式的水溶性酞菁染料Pc表示铜酞菁，镍酞菁或酞菁酞菁，R3表示低级烷基，B表示-CH2-CH2-，-CH2-CH2-NH-， + R A表示被低级烷基，低级烷氧基，羧基，羟基，磺基，硝基，氯或溴取代的亚苯基或亚苯基，或亚萘基，X表示-CH 2 - 或R 1，R 2各自代表氢，低级 烷基，羟乙基，磺乙基，羧乙基，苄基，苯基，羧基亚苯基或磺基亚苯基，或与氮原子一起为哌啶基或吗啉基，n和m各自表示0或1，a，b和c各自表示1至4的数， a，b和c的总和最多为6，所述染料适用于由天然或再生纤维素，丝或聚酰胺组成的皮革或纺织材料的染色或印花，所述材料上得到的染色和印刷品由深度 色泽和非常好的牢度 性能要光亮和润湿。

公开(公告)号：US3966704A

公开(公告)日：1976-06-29

申请号：US409813

申请日：1973-10-26

Applicant: Fritz Meininger ,  Klaus Hunger ,  Hartmut Springer

Inventor： Fritz Meininger ,  Klaus Hunger ,  Hartmut Springer

IPC: C09B62/515 ,  C09B45/18 ,  C09B45/32 ,  D06P3/60

CPC classification number: C09B62/515

Abstract: New valuable metal complex compounds, preferably copper, nickel, chromium or cobalt complex compounds, of monoazo dyestuffs which in the metal-free form and in form of the free acid correspond to the general formula (1) ##SPC1##In which one A stands for the group of the formula (2)HO -- R -- N = -- (2)wherein HO--R-- represents the radical of a coupling component of the series of the acetoacetic acid arylamide, barbituric acid, pyrazolone or of naphthalene, the hydroxyl group of which is in a vicinal position with regard to the azo group, and the other A stands for a hydroxyl group, X for a vinyl group or for a group having the formula --CH.sub.2 --CH.sub.2 --Z, wherein Z represents the hydroxyl group or an organic or inorganic radical capable of being split off by an alkaline agent, n represents the number 1 or 2 and m a number of from 1 to 3, and processes to prepare them, said dyestuffs being suitable for the dyeing and printing of different materials, such as wool, silk, poly amide fiber materials or leather, especially of cellulose-containing materials such as cotton, regenerated cellulose and linen, yielding intense dyeings and prints of high tinctorial strength which exhibit good to very good fastnesses to light, wet processing, washing, perspiration, steaming, ironing and rubbing and are resistant to chemical solvents.

Abstract translation: 新的有价值的金属配合物化合物，优选铜，镍，铬或钴配位化合物，以无金属形式和游离酸形式的单偶氮染料对应于通式（1）。其中A代表基团 （2）HO-R-N = - （2）其中HO-R-表示一系列乙酰乙酸芳基酰胺，巴比妥酸，吡唑啉酮或萘的偶联组分的基团，其羟基 相对于偶氮基而言位于相邻位置，另一个A表示羟基，X表示乙烯基或具有式-CH 2 -CH 2 -Z的基团，其中Z表示羟基或有机基团 或能够被碱性试剂分解的无机基团，n表示数字1或2，马克数1〜3，制备方法，所述染料适用于不同材料的染色和印刷，例如 羊毛，丝绸，聚酰胺纤维材料或皮革 特别是含纤维素的材料如棉花，再生纤维素和亚麻，产生强烈的着色力和高着色强度的印花，表现出良好的非常好的耐光牢度，湿法加工，洗涤，出汗，蒸，熨烫和摩擦。 化学溶剂。

公开(公告)号：US5021559A

公开(公告)日：1991-06-04

申请号：US526176

申请日：1990-05-21

Applicant: Hartmut Springer ,  Uwe Reiher

Inventor： Hartmut Springer ,  Uwe Reiher

IPC: C09B62/51 ,  C07C317/36 ,  C09B62/44 ,  C09B62/507 ,  D06P3/10 ,  D06P3/66

CPC classification number: C07C317/36 ,  C09B62/4411 ,  C09B62/507

Abstract: Water-soluble azo compounds of the general formula D--N.dbd.N--K are described, which have advantageous fiber-reactive dye properties and dye carboxamido-containing and in particular hydroxy-containing materials, such as wool and in particular cellulose fiber materials, in hues which have high color strength and good fastness properties.In the formula D--N.dbd.N--K, the symbols have the following meanings:D is a radical of the general formula ##STR1## in which Y is a vinyl group or an ethyl group which can be eliminated in the .beta.-position by an alkaline radical and R is a hydrogen atom, a nitro, lower alkyl, lower alkoxy, carboxyl or hydroxyl group or a halogen atom;K is a radical of a mono-coupleable water-soluble coupling component, which can additionally contain an azo group, or the radical of a doubly-coupleable water-soluble coupling component, each from the series of aminobenzenes, phenols, naphthols, aminonaphthols, acylaminonaphthols, dihydroxynaphthalenesulfonic acids, phenylazoaminonaphtholsulfonic acids, naphthylazoaminonaphtholsulfonic acids, 5-pyrazolones, 5-aminopyrazoles, acetoacetylarylides, 2-hydroxy-6-pyridones and hydroxyquinolines, it also being possible for K to contain, in addition to the substituents customary in dyes, one or more fiber-reactive groups. Furthermore, precursors of these azo compounds of the general formula ##STR2## are described, in which G is an amino or nitro group, R has the abovementioned meaning and Y' is a .beta.-hydroxyethyl group or has one of the meanings given above for Y.

Abstract translation: 描述了通式为DN = NK的水溶性偶氮化合物，其具有有利的纤维反应性染料性质和含有羧酰氨基的染料，特别是含有羟基的材料，例如羊毛，特别是纤维素纤维材料，其具有 色牢度高，牢度好。 在式DN = NK中，符号具有以下含义：D是通式“IMAGE”的基团，其中Y是乙烯基或乙基，其可以在碱性基团的β-位中被除去， R是氢原子，硝基，低级烷基，低级烷氧基，羧基或羟基或卤素原子; K是单偶联水溶性偶联组分的基团，其可另外含有偶氮基团或双偶联水溶性偶联组分的基团，每个基团由一系列氨基苯，酚，萘酚，氨基萘酚， 酰基氨基萘酚，二羟基萘磺酸，苯偶氮基萘酚磺酸，萘基偶氮基萘酚磺酸，5-吡唑啉酮，5-氨基吡唑，乙酰乙酰芳基，2-羟基-6-吡啶酮和羟基喹啉，除了染料中常规的取代基外，K还可以含有 或更多的纤维反应性基团。 此外，描述了这些通式为“IMAGE”的偶氮化合物的前体，其中G是氨基或硝基，R具有上述含义，Y'是β-羟乙基，或具有上面给出的含义之一 Y.

公开(公告)号：US4851542A

公开(公告)日：1989-07-25

申请号：US76749

申请日：1987-07-23

Applicant: Gunther Schwaiger ,  Hartmut Springer

Inventor： Gunther Schwaiger ,  Hartmut Springer

IPC: C07D249/18 ,  C07D249/20 ,  C09B62/503 ,  C09B62/507

CPC classification number: C07D249/20 ,  C07D249/18 ,  C09B62/5033

Abstract: N.sub.1 -substituted 1H-benzotriazole hydroxyethyl sulfone compounds, a process for their preparation and their use for the preparation of dyestuffs. Compounds of the general formula ##STR1## in which R is hydrogen or alkyl which has 1 to 6 carbon atoms and can be substituted by hydroxy, sulfo, carboxy, phosphono and/or cyano, W denotes a divalent, optionally substituted aliphatic radical, (C.sub.5 -C.sub.10)-cycloaliphatic radical which is optionally substituted by alkyl, aliphatic-(C.sub.5 -C.sub.8)-cycloaliphatic radical which is optionally substituted by alkyl, optionally substituted araliphatic radical or optionally substituted aromatic carbocyclic radical, it being possible for the aliphatic radicals in W to be interrupted by hetero groups of the formulae --O--, --S--, --SO.sub.2 --, --CO--, 1,4-piperidino, --NH-- and --N(R')-- in which R' is an alkyl group which has 1 to 6 carbon atoms and can be substituted, or is an alkanoyl group having 2 to 5 C atoms, and/or for the aliphatic radicals and aryl radicals to be attached to one another through such a hetero group, and R* denotes hydrogen, alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 5 carbon atoms, halogen, carboxy or sulfo.They are used as intermediates for the preparation of dyestuffs, such as fiber-reactive triphendioxazine dyestuffs, and can be prepared by reducing the nitro group in a compound of the general formula ##STR2## in which R, R* and W have the abovementioned meaning and A is a hydrogen atom or an acyl radical, to the amino group and diazotizing this amino group, whereupon cyclization takes place to give the benzotriazole, and, if necessary, subsequently eliminating the acyl radical by hydrolysis.

Abstract translation: N1取代的1H-苯并三唑羟乙基砜化合物，其制备方法及其用于制备染料的用途。 通式为“IMAGE”的化合物，其中R为氢或具有1至6个碳原子并可被羟基，磺基，羧基，膦酰基和/或氰基取代的烷基，W表示二价，任选取代的脂族基团（ 任选被烷基，任选取代的芳脂族基团或任选取代的芳族碳环基团取代的烷基，脂族 - （C 5 -C 8） - 环脂族基团取代的C 5 -C 10） - 环脂族基团， W被式-O - ， - S - ， - SO 2 - ， - CO-，1,4-哌啶子基，-NH-和-N（R'） - 的杂基中断，其中R'是烷基 具有1至6个碳原子并且可被取代的基团，或具有2至5个C原子的烷酰基，和/或通过这种杂基团彼此连接的脂族基团和芳基，R * 表示氢，具有1至6个碳原子的烷基，具有1至5个碳原子的烷氧基，卤素， 羧基或磺基。 它们用作制备染料的中间体，例如纤维反应性三苯并二恶嗪染料，并且可以通过还原其中R，R *和W具有上述含义的通式“IMAGE”的化合物中的硝基来制备 并且A是氢原子或酰基，并且对该氨基进行重氮化，随后进行环化以得到苯并三唑，并且如果需要，随后通过水解除去酰基。

公开(公告)号：US4786728A

公开(公告)日：1988-11-22

申请号：US909010

申请日：1986-09-18

Applicant: Gunther Schwaiger ,  Hartmut Springer ,  Walter Helmling

Inventor： Gunther Schwaiger ,  Hartmut Springer ,  Walter Helmling

IPC: C09B19/00 ,  C07C67/00 ,  C07C313/00 ,  C07C317/14 ,  C07C317/22 ,  C07C317/34 ,  C07C317/36 ,  C07C317/46 ,  C07C317/48 ,  C07C323/65 ,  C07D498/04 ,  C09B62/503 ,  D06P1/384 ,  D06P3/10 ,  D06P3/66 ,  C09B19/02

CPC classification number: C09B62/5033

Abstract: Triphendioxazine compounds with properties of fiber-reactive dyestuffs corresponding to the general formula ##STR1## in which T is an optionally substituted alkyl group with 1 to 6 carbon atoms, excluding a radical of the group Y defined below, it also being possible for the alkyl group to be interrupted by hetero atoms, or is an optionally substituted aryl group,B is an oxygen or sulfur atom or an amino group,W is a divalent, optionally substituted aliphatic, cycloaliphatic, araliphatic or aromatic-carbocyclic radical or a benzotriazole radical combined with one of these radicals, it being possible for the aliphatic radicals to be interrupted by hetero groups and/or for aliphatic and aryl radicals to be bonded to one another by a hetero group,R is hydrogen, alkyl with 1 to 6 carbon atoms, alkoxy with 1 to 5 carbon atoms, halogen, carboxy or sulfo,X.sup.1 is hydrogen, halogen, cycloalkyl, aralkyloxy, alkoxy, aryloxy, alkyl, aryl, aralkyl, cyano, carboxy, carbalkoxy, arylamino, carbamoyl, which is optionally substituted, alkanoylamino or aroylamino,X.sup.2 can have the meaning of X.sup.1,n represents the number 1 or 2,Y is the vinyl group or an ethyl group which is substituted in the .beta.-position by a substituent which can be eliminated with an alkaliand the molecule (1) contains at least one sulfo or sulfato group.

Abstract translation: 对应于通式（1）的纤维活性染料性质的三苯并二恶嗪化合物，其中T是具有1-6个碳原子的任选取代的烷基，不包括下面定义的基团Y的基团，也是可能的 由于烷基被杂原子中断，或是任选取代的芳基，B是氧或硫原子或氨基，W是二价，任选取代的脂族，脂环族，芳脂族或芳族 - 碳环基或 苯并三唑基与这些基团中的一个结合，脂族基团可以被杂基和/或通过杂基团彼此键合的脂族和芳基自由中断，R是氢，具有1至6个的烷基 碳原子，具有1至5个碳原子的烷氧基，卤素，羧基或磺基，X 1是氢，卤素，环烷基，芳烷氧基，烷氧基，芳氧基，烷基，芳基，芳烷基，氰基，羧基，烷氧基，芳基氨基， 乙酰基，其可以被取代，烷酰基氨基或芳酰基氨基，X 2可以具有X 1的含义，n表示数字1或2，Y是乙烯基或在β-位置被取代基取代的乙基，该取代基可以是 用碱去除，分子（1）含有至少一个磺基或硫酸根基团。

公开(公告)号：US4782150A

公开(公告)日：1988-11-01

申请号：US84427

申请日：1987-08-11

Applicant: Hartmut Springer ,  Walter Helmling ,  Gunther Schwaiger

Inventor： Hartmut Springer ,  Walter Helmling ,  Gunther Schwaiger

IPC: C09B19/00 ,  C07C67/00 ,  C07C313/00 ,  C07C317/22 ,  C07C317/36 ,  C07C323/25 ,  C07D498/04 ,  C09B62/503 ,  C09B19/02

CPC classification number: C09B62/5033

Abstract: Water-soluble triphendioxazine compounds which have valuable fiber-reactive dyestuff properties and correspond to the general formula (1) and dye materials, in particular cellulose fiber materials, containing carboxamide and/or hydroxy groups in fast shades. ##STR1## in which: B is a group --O--, --S--, --NH-- or --N(R')-- in which R' is alkyl having 1 to 6 carbon atoms;R* is hydrogen or optionally substituted lower alkyl or optionally substituted aryl;W and W.sup.1 independently of one another are each a divalent aliphatic radical or a cycloaliphatic radical which is optionally substituted by lower alkyl or an aliphatic-cycloaliphatic radical which is optionally substituted by lower alkyl, it being possible for the aliphatic radicals to be interrupted by one or more groups --O--, --S--, --SO.sub.2 --, --CO--, 1,4-piperidino, --NH-- and --N(R.sup.o)-- in which R.sup.o has the meaning of R' or is lower alkanoyl;the groupings --B--W.sup.1 --N(R*)-- and --N(R*)--W--B 13 independently of one another each represent the divalent radical of a five-membered or six-membered, saturated heterocyclic structure containing two N atoms, or the groupings --B--W.sup.1 -- and --W--B-- independently of one another each represent the divalent radical of a five-membered or six-membered, saturated heterocyclic structure which contains two N atoms and which is attached by means of one of the two N atoms, via a C.sub.2 -C.sub.4 -alkylene, to the groupings --N(R*)--A or A--N(R*)--, respectively;is benzoyl, naphthoyl, N-phenylcarbamoyl or N-naphthylcarbamoyl in which the phenyl and naphthyl radicals can be substituted, at least one of these being a group which imparts solubility in water;X.sup.1 and X.sup.2 independently of one another are each hydrogen, halogen, lower alkyl, lower alkoxy or optionally substituted aryl;Y is vinyl or a .beta.-substituted ethyl;and the compounds necessarily contain at least two sulfo groups.

Abstract translation: 具有有价值的纤维反应性染料性能并对应于通式（1）的染料和特别是纤维素纤维材料的水溶性三苯并二恶嗪化合物，其特征在于纤维素纤维材料，其具有快速阴影的羧酰胺和/或羟基。 （1）其中：B是-O - ， - S-，-NH-或-N（R'） - 基团，其中R'是具有1至6个碳原子的烷基; R *是氢或任选取代的低级烷基或任选取代的芳基; W和W1彼此独立地是二价脂族基团或脂环族基团，其任选被低级烷基或任选被低级烷基取代的脂族 - 脂环族基团取代，脂族基团可能被一个 或更多的基团-O - ， - S - ， - SO 2 - ， - CO-，1,4-哌啶子基，-NH-和-N（Ro） - ，其中Ro具有R'或低级烷酰基的含义; B-W1-N（R *） - 和-N（R *）-WB 13彼此独立地分别代表含有两个N原子的五元或六元饱和杂环结构的二价基团， 或基团-B-W1-和-WB-彼此独立地各自表示含有两个N原子的五元或六元饱和杂环结构的二价基团，并且其通过二者之一连接 N原子通过C 2 -C 4亚烷基分别连接到-N（R *）-A或AN（R *） - 基团上; 是苯甲酰基，萘甲酰基，N-苯基氨基甲酰基或N-萘基氨基甲酰基，其中苯基和萘基可以被取代，这些中的至少一个是赋予在水中溶解度的基团; X1和X2各自独立地为氢，卤素，低级烷基，低级烷氧基或任选取代的芳基; Y是乙烯基或β-取代的乙基; 并且化合物必然含有至少两个磺基。

公开(公告)号：US4775746A

公开(公告)日：1988-10-04

申请号：US913693

申请日：1986-09-30

Applicant: Hartmut Springer ,  Michael Kunze ,  Marcos Segal ,  Werner H. Russ

Inventor： Hartmut Springer ,  Michael Kunze ,  Marcos Segal ,  Werner H. Russ

IPC: C07D251/52 ,  C07D251/70 ,  C09B62/51 ,  D06P1/384 ,  D06P3/10 ,  D06P3/66 ,  C09B62/507

CPC classification number: C09B62/51

Abstract: Water-soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally mononsubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;Y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl;the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.

Abstract translation: 具有符合式（1）的纤维反应性染料性质的水溶性偶氮化合物，其中D表示苯或萘环; R1表示氢，烷基，烷氧基，磺基或羧基; R 2表示氢，烷基，烷氧基，磺基，羧基，取代或未取代的芳基，羟基，硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基，取代或未取代的烷氧基或芳氧基，硫代，取代或未取代的烷基硫醚或芳基硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; B羟基，任选取代的烷氧基或芳氧基，硫代，任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢，碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; Y表示β-硫代硫代乙基，β-磷酰乙基，β-氯乙基，乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中：A为氯或溴，B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基，m表示数1，基团-SO 2 Y与D键合，D， R2，R，M，n，p和Y具有上述含义。 新的偶氮化合物染料纤维材料，如羊毛，特别是纤维素，具有强烈和快速的色调。

公开(公告)号：US4118186A

公开(公告)日：1978-10-03

申请号：US796039

申请日：1977-05-11

Applicant: Erich Feess ,  Hartmut Springer ,  Willy Gronen

Inventor： Erich Feess ,  Hartmut Springer ,  Willy Gronen

IPC: D06M13/02 ,  C09B1/32 ,  C09B5/14 ,  C09B7/02 ,  C09B19/02 ,  C09B29/01 ,  C09B29/15 ,  C09B29/20 ,  C09B29/50 ,  C09B33/153 ,  C09B35/215 ,  C09B47/26 ,  C09B69/00 ,  D06M13/322 ,  D06M13/325 ,  D06M13/335 ,  D06M13/35 ,  D06M13/355 ,  D06M13/402 ,  D06M13/438 ,  D06P1/00 ,  D06P1/14 ,  D06P3/52 ,  D06P3/60 ,  C09B27/00 ,  C07D249/00 ,  D06M13/38

CPC classification number: C09B7/02 ,  C09B1/325 ,  C09B19/02 ,  C09B29/0007 ,  C09B29/0014 ,  C09B29/103 ,  C09B29/20 ,  C09B29/366 ,  C09B33/153 ,  C09B35/215 ,  C09B47/26 ,  C09B5/14 ,  C09B69/00 ,  D06P1/0048 ,  D06P1/14 ,  D06P3/527 ,  D06P3/6091

Abstract: A process for the fixation of organic dyestuffs on materials having a fibrous structure had been found, in which an organic dyestuff containing one or several groups of the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each represent a non-ionic, anionic or cationic substituent, with the exception of a primary or secondary amino group or the salts thereof, is applied in dissolved form onto said materials and subsequently subjected to the action of nitrous acid. The process yields fiber materials on which active substances, such as dyestuffs, brighteners, mothproofing agents, water-repellent agents, etc., are fixed fast; the novel process is especially and advantageously suitable in combination with the ice-color technique.

Abstract translation: 发现有机染料固定在具有纤维结构的材料上的方法，其中含有一种或几种式（I）的有机染料（I）其中R1，R2，R3和R4各自代表 非离子，阴离子或阳离子取代基，除了伯或仲氨基或其盐，以溶解的形式施加到所述材料上，随后经受亚硝酸的作用。 该方法产生纤维材料，其上活性物质如染料，增白剂，防虫剂，防水剂等被快速固定; 该新颖方法特别且有利地适用于冰色技术。

公开(公告)号：US4045428A

公开(公告)日：1977-08-30

申请号：US603914

申请日：1975-08-12

Applicant: Fritz Meininger ,  Klaus Hunger ,  Hartmut Springer

Inventor： Fritz Meininger ,  Klaus Hunger ,  Hartmut Springer

IPC: C09B62/51 ,  C09B62/50 ,  C09B62/74 ,  D06P1/06 ,  D06P1/38

CPC classification number: C09B62/51

Abstract: A water-soluble monoazo-dyestuff of the formula (1) ##STR1## in which X represents --CH=CH.sub.2 or --CH.sub.2 --CH.sub.2 --Z, the radical Z stands for hydroxyl, sulfato, chlorine, bromine, lower alkyl-sulfonyloxy, lower alkyl-sulfonylamino, phenyl-sulfonyloxy, lower alkyl-phenyl-sulfonyloxy, phenyl-sulfonylamino, lower alkyloyloxy, monosulfobenzoyloxy, phenoxy, di-(lower alkyl)-amino, tri-(lower alkyl)-ammonium, thiosulfato or phosphato, and A is a radical of a coupling component of the aminobenzene, hydroxybenzene amino-naphthalene, hydroxynaphthalene, N-naphthyl- or N-phenyl-amino-pyrazole, N-naphthyl- or N-phenyl-pyrazolone or of the acetoacetanilide series, the coupling component containing at least one water-solubilizing group, and a process for preparing these dyestuffs which are very suitable for the dyeing and printing of native and synthetic carbonamide-groups containing and native, regenerated or synthetic hydroxy-groups containing material, and yield, especially on cellulose fibrous materials in the presence of alkaline agents dyeings and prints of good to very good fastnesses to light and to wet-processing and of good stability to alkalis. The novel dyestuffs also have a very good color-build-up and yield dyeings and prints of high tinetorial strength.

Abstract translation: 式（1）（1）＆lt; IMAGE＆gt;的水溶性单偶氮染料，其中X表示-CH = CH 2或-CH 2 -CH 2 -Z，基团Z代表羟基，硫酸根合，氯，溴，低级烷基 - 磺酰氧基，低级烷基 - 磺酰基氨基，苯基 - 磺酰氧基，低级烷基 - 苯基 - 磺酰氧基，苯基 - 磺酰基氨基，低级烷氧基，单磺酰基苯甲酰氧基，苯氧基，二 - （低级烷基） - 氨基，三 - （低级烷基） - 铵， 磷酸盐和A是氨基苯，羟基苯氨基萘，羟基萘，N-萘基或N-苯基 - 氨基 - 吡唑，N-萘基或N-苯基 - 吡唑啉酮或乙酰乙酰苯胺系列的偶联组分的基团 ，含有至少一种水溶性基团的偶联组分和这些染料的制备方法非常适用于染色和印刷含天然和合成的含碳酰胺基团和天然的，再生的或合成的含羟基的材料，以及 产率，特别是纤维素纤维材料 在碱性染料和印刷品存在下，具有良好至非常好的耐光牢度和湿法加工性能以及对碱的稳定性。 新颖的染料也具有非常好的色素积累和产生高的色谱强度的染色和印花。