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公开(公告)号：US20060051591A1
公开(公告)日：2006-03-09
申请号：US11217728
申请日：2005-09-01
CPC分类号： C08G18/8175 , B33Y70/00 , C09D175/14 , Y10T428/31551
摘要： The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.
摘要翻译： 本发明涉及一种制备粘合剂的方法，其包含1）脲基甲酸酯基团，2）与烯键式不饱和化合物反应的基团与暴露于光化辐射（辐射固化基团）和3）任选的NCO-反应性基团反应的基团， A）一种或多种含有脲二酮基团的NCO-官能化合物，B）一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应的基团，其在暴露于光化辐射下聚合（辐射 - 固化基团），然后C）与除了B）之外的一种或多种饱和的含羟基化合物，在D存在下，具有OH官能度> = 2的这些化合物中的至少一种，含有一种或多种 脂肪族或脂环族羧酸的铵盐或鏻盐，与化合物C）的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。
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公开(公告)号：US20050209361A1
公开(公告)日：2005-09-22
申请号：US11080176
申请日：2005-03-14
申请人： Christophe Detrembleur , Jan Weikard , Dorota Greszta-Franz , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
发明人： Christophe Detrembleur , Jan Weikard , Dorota Greszta-Franz , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
IPC分类号： C08G18/16 , C08G18/67 , C08G18/78 , C09D175/16 , C08G2/00
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/166 , C08G18/672 , C09D175/16 , C08G18/3206
摘要： Process for preparing binders including reacting A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds containing groups capable of participating in polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and contain isocyanate-reactive groups, followed by C) reaction with one or more hydroxyl-containing compounds other than B), wherein at least one of these compounds has an OH functionality of ≧2, D) in the presence of one or more compounds containing phenoxide groups, as catalysts, and E) optionally auxiliaries and additives, where the reaction with compounds of component C) proceeds at least proportionally with the formation of allophanate groups and where and including binders containing allophanate groups and groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and optionally also contain NCO-reactive groups. The binders are used in coating compositions used to coat substrates.
摘要翻译： 制备粘合剂的方法包括使A）一种或多种含有脲二酮基团的NCO-官能化合物与B）一种或多种含有能够在曝光于光化辐射下参与与烯属不饱和化合物聚合反应的基团的化合物，并含有异氰酸酯反应性基团， 随后C）与除B）之外的一种或多种含羟基化合物反应，其中这些化合物中的至少一种具有> = 2的OH官能度，D）在一种或多种含有酚盐的化合物的存在下，作为催化剂 和E）任选的助剂和添加剂，其中与组分C）的化合物的反应至少与形成脲基甲酸酯基团成比例地进行，并且其中和包括含有脲基甲酸酯基团和能够与烯属不饱和化合物进行聚合反应的基团的粘合剂 暴露于光化辐射，并且任选地还含有NCO-反应性基团。 粘合剂用于涂覆基材的涂料组合物中。
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公开(公告)号：US20080214691A1
公开(公告)日：2008-09-04
申请号：US12072022
申请日：2008-02-22
申请人： Christophe Detrembleur , Jan Weikard , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
发明人： Christophe Detrembleur , Jan Weikard , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
IPC分类号： C08F2/46
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/1816 , C08G18/1875 , C08G18/672 , C08G18/798 , C09D175/16
摘要： A process for preparing binders containing allophanate groups which contain, at the oxygen atom of the allophanate group that is bonded via two single bonds, organic radicals with activated groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation; the process includes reacting A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and C) optionally further NCO-reactive compounds, and D) in the presence of one or more compounds containing phenoxide groups, as catalysts. The binders can be used in preparing coatings, coating materials, coating compositions, adhesives, printing inks, casting resins, dental compounds, sizes, photoresists, stereolithography systems, resins for composite materials and sealants.
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公开(公告)号：US08604097B2
公开(公告)日：2013-12-10
申请号：US13015118
申请日：2011-01-27
申请人： Jan Weikard , Christophe Detrembleur , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
发明人： Jan Weikard , Christophe Detrembleur , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/672 , C08G18/798 , C08G18/8166 , C09D175/14 , C09D175/16
摘要： The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting, at temperatures of ≦130° C., A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.
摘要翻译： 本发明涉及通过在130℃的温度下反应制备含有脲基甲酸酯基的辐射固化粘合剂的方法，A）一种或多种含有脲二酮基团的化合物与B）一种或多种含有基团的OH-官能化合物 在曝光于光化辐射（辐射固化基团）时与烯键式不饱和化合物反应，C）任选除B）之外的NCO-反应性化合物，在D）含有至少一种锌化合物的催化剂存在下，向 通过打开脲二酮环形成脲基甲酸酯基。 本发明还涉及通过本发明的方法获得的粘合剂和包含这些粘合剂的涂料组合物。
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公开(公告)号：US08202618B2
公开(公告)日：2012-06-19
申请号：US12651576
申请日：2010-01-04
IPC分类号： C09D175/16 , C08F2/46 , C08G18/04 , C08G18/16 , C08G18/70
CPC分类号： C08G18/8175 , B33Y70/00 , C09D175/14 , Y10T428/31551
摘要： The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.
摘要翻译： 本发明涉及一种制备粘合剂的方法，其包含1）脲基甲酸酯基团，2）与烯键式不饱和化合物反应的基团与暴露于光化辐射（辐射固化基团）和3）任选的NCO-反应性基团反应的基团， A）一种或多种含有脲二酮基团的NCO-官能化合物，B）一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射（辐射 - 固化基团），然后C）与除了B）之外的一种或多种饱和的含羟基化合物，在D的存在下，在具有OH官能度≥2的这些化合物中的至少一种的化合物中含有一种或多种铵 脂肪族或脂环族羧酸的盐或鏻盐，与化合物C）的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。
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公开(公告)号：US20100105792A1
公开(公告)日：2010-04-29
申请号：US12651576
申请日：2010-01-04
IPC分类号： C08G59/68
CPC分类号： C08G18/8175 , B33Y70/00 , C09D175/14 , Y10T428/31551
摘要： The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.
摘要翻译： 本发明涉及一种制备粘合剂的方法，其包含1）脲基甲酸酯基团，2）与烯键式不饱和化合物反应的基团与暴露于光化辐射（辐射固化基团）和3）任选的NCO-反应性基团反应的基团， A）一种或多种含有脲二酮基团的NCO-官能化合物，B）一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射（辐射 - 固化基团），然后C）与除了B）之外的一种或多种饱和的含羟基化合物，在D的存在下，在具有OH官能度≥2的这些化合物中的至少一种的化合物中含有一种或多种铵 脂肪族或脂环族羧酸的盐或鏻盐，与化合物C）的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。
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公开(公告)号：US20110124805A1
公开(公告)日：2011-05-26
申请号：US13015118
申请日：2011-01-27
申请人： Jan Weikard , Christophe Detrembleur , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
发明人： Jan Weikard , Christophe Detrembleur , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
IPC分类号： C08L75/12 , C07D251/04
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/672 , C08G18/798 , C08G18/8166 , C09D175/14 , C09D175/16
摘要： The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting at temperatures of ≦130° C. A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.
摘要翻译： 本发明涉及通过在温度为130℃的温度下反应制备含有脲基甲酸酯基的辐射固化粘合剂的方法。A）一种或多种含有脲二酮基团的化合物与B）一种或多种含OH官能化合物， 在曝光于光化辐射（辐射固化基团）时与烯属不饱和化合物反应，C）任选除B）之外的NCO-反应性化合物，在D）含有至少一种锌化合物的催化剂存在下反应形成 脲基甲酸酯基通过开放脲二酮环。 本发明还涉及通过本发明的方法获得的粘合剂和包含这些粘合剂的涂料组合物。
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公开(公告)号：US07381785B2
公开(公告)日：2008-06-03
申请号：US11080176
申请日：2005-03-14
申请人： Christophe Dètrembleur , Jan Weikard , Dorota Greszta-Franz , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
发明人： Christophe Dètrembleur , Jan Weikard , Dorota Greszta-Franz , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
IPC分类号： C08G18/78 , C08G18/67 , C08G18/16 , C09D175/16
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/166 , C08G18/672 , C09D175/16 , C08G18/3206
摘要： Process for preparing binders including reacting A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds containing groups capable of participating in polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and contain isocyanate-reactive groups, followed by C) reaction with one or more hydroxyl-containing compounds other than B), wherein at least one of these compounds has an OH functionality of≧2, D) in the presence of one or more compounds containing phenoxide groups, as catalysts, and E) optionally auxiliaries and additives, where the reaction with compounds of component C) proceeds at least proportionally with the formation of allophanate groups and where and including binders containing allophanate groups and groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and optionally also contain NCO-reactive groups. The binders are used in coating compositions used to coat substrates.
摘要翻译： 制备粘合剂的方法包括使A）一种或多种含有脲二酮基团的NCO-官能化合物与B）一种或多种含有能够在曝光于光化辐射下参与与烯属不饱和化合物聚合反应的基团的化合物，并含有异氰酸酯反应性基团， 随后C）与除B）之外的一种或多种含羟基化合物反应，其中这些化合物中的至少一种具有> = 2的OH官能度，D）在一种或多种含有酚盐的化合物的存在下，作为催化剂 和E）任选的助剂和添加剂，其中与组分C）的化合物的反应至少与形成脲基甲酸酯基团成比例地进行，并且其中和包括含有脲基甲酸酯基团和能够与烯属不饱和化合物进行聚合反应的基团的粘合剂 暴露于光化辐射，并且任选地还含有NCO-反应性基团。 粘合剂用于涂覆基材的涂料组合物中。
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19.发明授权Coating composition containing UV-curable urethane (meth)acrylates containing isocyanate groups and urethane (meth)acrylates containing hydroxyl groups 有权含有含有异氰酸酯基的UV固化性氨基甲酸酯（甲基）丙烯酸酯和含有羟基的氨基甲酸酯（甲基）丙烯酸酯）的涂料组合物公开(公告)号：US06500876B2
公开(公告)日：2002-12-31
申请号：US09811032
申请日：2001-03-16
申请人： Jan Weikard , Michael Sonntag , Holger Mundstock
发明人： Jan Weikard , Michael Sonntag , Holger Mundstock
IPC分类号： C08G1810
CPC分类号： C08G18/672 , C08G18/8175 , C09D175/16 , Y10T428/31551
摘要： The invention relates to coating compositions containing: a) urethane (meth)acrylates that contain (meth)acryloyl groups and free isocyanate groups, b) urethane (meth)acrylates that contain (meth)acryloyl groups and free hydroxyl groups, c) the UV initiators that initiate radical polymerization and d) optionally, one or more compounds that react with isocyanates.
摘要翻译： 本发明涉及包含：a）含有（甲基）丙烯酰基和游离异氰酸酯基的氨基甲酸酯（甲基）丙烯酸酯，b）含有（甲基）丙烯酰基和游离羟基的氨基甲酸酯（甲基）丙烯酸酯，c）UV 引发自由基聚合的引发剂和d）任选的一种或多种与异氰酸酯反应的化合物。
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公开(公告)号：US06380308B1
公开(公告)日：2002-04-30
申请号：US09711743
申请日：2000-11-13
IPC分类号： C08G1863
CPC分类号： C08L51/04 , C08F279/02 , C08G18/635 , C09D151/04 , C09D175/04 , Y10T428/31551
摘要： The invention relates to a binder composition containing A) 50-90 parts by wt. of OH-functional graft copolymer resins prepared from a) 0.1 to 10 parts by wt. of polybutadiene, b) 5 to 60 parts by wt. of an unsaturated aromatic monomer, c) 10 to 50 parts by wt. of a hydroxyalkyl ester of (meth)acrylic acid, d) 5 to 70 parts by wt. of a cycloaliphatic ester of (meth)acrylic acid, e) 5 to 50 parts by wt. of an aliphatic ester of (meth)acrylic acid, f) 0.1 to 5 parts by wt. of a mono-olifinically unsaturated mono- or dicarboxylic acid and/or maleic or fumaric acid half esters, B) 0.1 to 5 parts by wt. of a polyfunctional crosslinking agent.
摘要翻译： 本发明涉及一种粘合剂组合物，其包含A）50-90重量份 由以下制备的OH官能接枝共聚物树脂：0.1〜10重量份 的聚丁二烯，b）5〜60重量份。 的不饱和芳族单体，c）10至50重量份。 的（甲基）丙烯酸的羟烷基酯，d）5〜70重量份。 的（甲基）丙烯酸的脂环族酯，e）5〜50重量份 的（甲基）丙烯酸的脂肪族酯，f）0.1〜5重量份。 的单烯烃不饱和单羧酸和/或马来酸或富马酸半酯，B）0.1至5重量份。 的多官能交联剂。
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