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    High-solids binder compositions and their use
    1.
    发明授权
    High-solids binder compositions and their use 有权
    高固体粘合剂组合物及其用途

    公开(公告)号：US06380308B1

    公开(公告)日：2002-04-30

    申请号：US09711743

    申请日：2000-11-13

    申请人： Christian Wamprecht ,  Michael Sonntag ,  Holger Mundstock

    发明人： Christian Wamprecht ,  Michael Sonntag ,  Holger Mundstock

    IPC分类号： C08G1863

    CPC分类号： C08L51/04 ,  C08F279/02 ,  C08G18/635 ,  C09D151/04 ,  C09D175/04 ,  Y10T428/31551

    摘要： The invention relates to a binder composition containing A) 50-90 parts by wt. of OH-functional graft copolymer resins prepared from a) 0.1 to 10 parts by wt. of polybutadiene, b) 5 to 60 parts by wt. of an unsaturated aromatic monomer, c) 10 to 50 parts by wt. of a hydroxyalkyl ester of (meth)acrylic acid, d) 5 to 70 parts by wt. of a cycloaliphatic ester of (meth)acrylic acid, e) 5 to 50 parts by wt. of an aliphatic ester of (meth)acrylic acid, f) 0.1 to 5 parts by wt. of a mono-olifinically unsaturated mono- or dicarboxylic acid and/or maleic or fumaric acid half esters, B) 0.1 to 5 parts by wt. of a polyfunctional crosslinking agent.

    摘要翻译： 本发明涉及一种粘合剂组合物，其包含A）50-90重量份 由以下制备的OH官能接枝共聚物树脂：0.1〜10重量份 的聚丁二烯，b）5〜60重量份。 的不饱和芳族单体，c）10至50重量份。 的（甲基）丙烯酸的羟烷基酯，d）5〜70重量份。 的（甲基）丙烯酸的脂环族酯，e）5〜50重量份 的（甲基）丙烯酸的脂肪族酯，f）0.1〜5重量份。 的单烯烃不饱和单羧酸和/或马来酸或富马酸半酯，B）0.1至5重量份。 的多官能交联剂。

    Binder mixtures of polyaspartates and sulfonate-modified polyisocyanates
    5.
    发明申请
    Binder mixtures of polyaspartates and sulfonate-modified polyisocyanates 审中-公开
    聚天冬氨酸盐和磺酸盐改性的多异氰酸酯的粘合剂混合物

    公开(公告)号：US20060247371A1

    公开(公告)日：2006-11-02

    申请号：US11410405

    申请日：2006-04-25

    申请人： Holger Mundstock ,  Meike Niesten ,  Nicole Reidenbach ,  Jorg Schmitz

    发明人： Holger Mundstock ,  Meike Niesten ,  Nicole Reidenbach ,  Jorg Schmitz

    IPC分类号： C08G18/08

    CPC分类号： C08G18/3821 ,  C08G18/3256 ,  C08G18/775 ,  C08G18/792 ,  C09D175/12

    摘要： The present invention relates to two-component coating systems for the production of polyurea coatings containing A) a sulfonate group-containing polyisocyanate and B) an amino-functional polyaspartate corresponding to formula (I) wherein X represents the n-valent organic group obtained by removing the primary amino groups from an n-valent polyamine, R1, R2 represent the same or different organic groups, which are inert to isocyanate groups under the reaction conditions, and n represents an integer of at least 2. The present invention also relates to coatings obtained from these coating systems.

    摘要翻译： 本发明涉及用于制备聚脲涂料的双组分涂料体系，其包含A）含磺酸基团的多异氰酸酯和B）对应于式（I）的氨基官能聚天冬氨酸酯，其中X表示通过以下步骤获得的n价有机基团： 从n价多胺除去伯氨基，R 1，R 2表示在反应条件下对异氰酸酯基团是惰性的相同或不同的有机基团， 并且n表示至少为2的整数。本发明还涉及从这些涂布体系获得的涂层。

    Radiation-curing binders and a process for their preparation
    6.
    发明授权
    Radiation-curing binders and a process for their preparation 有权
    辐射固化粘合剂及其制备方法

    公开(公告)号：US08202618B2

    公开(公告)日：2012-06-19

    申请号：US12651576

    申请日：2010-01-04

    申请人： Jan Weikard ,  Christoph Gurtler ,  Wolfgang Fischer ,  Jorg Schmitt ,  Holger Mundstock

    发明人： Jan Weikard ,  Christoph Gurtler ,  Wolfgang Fischer ,  Jorg Schmitt ,  Holger Mundstock

    IPC分类号： C09D175/16 ,  C08F2/46 ,  C08G18/04 ,  C08G18/16 ,  C08G18/70

    CPC分类号： C08G18/8175 ,  B33Y70/00 ,  C09D175/14 ,  Y10T428/31551

    摘要： The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.

    摘要翻译： 本发明涉及一种制备粘合剂的方法，其包含1）脲基甲酸酯基团，2）与烯键式不饱和化合物反应的基团与暴露于光化辐射（辐射固化基团）和3）任选的NCO-反应性基团反应的基团， A）一种或多种含有脲二酮基团的NCO-官能化合物，B）一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射（辐射 - 固化基团），然后C）与除了B）之外的一种或多种饱和的含羟基化合物，在D的存在下，在具有OH官能度≥2的这些化合物中的至少一种的化合物中含有一种或多种铵 脂肪族或脂环族羧酸的盐或鏻盐，与化合物C）的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。

    RADIATION-CURING BINDERS AND A PROCESS FOR THEIR PREPARATION
    7.
    发明申请
    RADIATION-CURING BINDERS AND A PROCESS FOR THEIR PREPARATION 有权
    辐射固化粘合剂及其制备方法

    公开(公告)号：US20100105792A1

    公开(公告)日：2010-04-29

    申请号：US12651576

    申请日：2010-01-04

    申请人： Jan Weikard ,  Christoph Gürtler ,  Wolfgang Fischer ,  Jörg Schmitt ,  Holger Mundstock

    发明人： Jan Weikard ,  Christoph Gürtler ,  Wolfgang Fischer ,  Jörg Schmitt ,  Holger Mundstock

    IPC分类号： C08G59/68

    CPC分类号： C08G18/8175 ,  B33Y70/00 ,  C09D175/14 ,  Y10T428/31551

    摘要： The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.

    摘要翻译： 本发明涉及一种制备粘合剂的方法，其包含1）脲基甲酸酯基团，2）与烯键式不饱和化合物反应的基团与暴露于光化辐射（辐射固化基团）和3）任选的NCO-反应性基团反应的基团， A）一种或多种含有脲二酮基团的NCO-官能化合物，B）一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射（辐射 - 固化基团），然后C）与除了B）之外的一种或多种饱和的含羟基化合物，在D的存在下，在具有OH官能度≥2的这些化合物中的至少一种的化合物中含有一种或多种铵 脂肪族或脂环族羧酸的盐或鏻盐，与化合物C）的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。

    Compounds containing allophanate, isocyanate and ortho ester groups and their use as binders
    8.
    发明申请
    Compounds containing allophanate, isocyanate and ortho ester groups and their use as binders 审中-公开
    含有脲基甲酸酯，异氰酸酯和原酸酯基团的化合物及其作为粘合剂的用途

    公开(公告)号：US20070238837A1

    公开(公告)日：2007-10-11

    申请号：US11401427

    申请日：2006-04-10

    申请人： Dieter Mager ,  Holger Mundstock ,  Meike Niesten ,  Jorg Schmitz

    发明人： Dieter Mager ,  Holger Mundstock ,  Meike Niesten ,  Jorg Schmitz

    IPC分类号： C08F283/04

    CPC分类号： C08G18/284 ,  C08G18/7837 ,  C09D175/06

    摘要： The present invention relates to a process for preparing compounds which contain allophanate groups, free NCO groups and polyortho ester groups by reacting A) one or more aliphatic and/or cycloaliphatic polyisocyanates with B) one or more polyortho esters containing at least one hydroxyl group per molecule to form NCO-functional polyurethanes and then reacting some or all of the urethane groups to form allophanate groups. The present invention relates to compounds obtained by this process and to their use as binders in coating, sealant and adhesive compositions that also contain catalysts and optionally additives.

    摘要翻译： 本发明涉及通过使A）一种或多种脂族和/或脂环族多异氰酸酯与B）一种或多种含有至少一个羟基的聚原酸酯来制备含有脲基甲酸酯基团，游离NCO基团和聚酯酯基团的化合物的方法 分子以形成NCO官能的聚氨酯，然后使一些或所有的氨基甲酸酯基团反应形成脲基甲酸酯基团。 本发明涉及通过该方法获得的化合物及其作为粘合剂在包含催化剂和任选的添加剂的涂料，密封剂和粘合剂组合物中的用途。

    Radiation-curing binders and a process for their preparation
    9.
    发明申请
    Radiation-curing binders and a process for their preparation 有权
    辐射固化粘合剂及其制备方法

    公开(公告)号：US20060052527A1

    公开(公告)日：2006-03-09

    申请号：US11217725

    申请日：2005-09-01

    申请人： Jan Weikard ,  Dorota Greszta-Franz ,  Wolfgang Fischer ,  Jorg Schmitz ,  Holger Mundstock ,  Christophe Detrembleur

    发明人： Jan Weikard ,  Dorota Greszta-Franz ,  Wolfgang Fischer ,  Jorg Schmitz ,  Holger Mundstock ,  Christophe Detrembleur

    IPC分类号： C08G18/08

    CPC分类号： C08G18/798 ,  C08G18/672 ,  C08G18/7837 ,  C08G18/8009 ,  C08G18/8166 ,  C09D175/14 ,  C09D175/16

    摘要： The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more zinc compounds, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.

    摘要翻译： 本发明涉及一种制备粘合剂的方法，其包含1）脲基甲酸酯基团，2）与烯键式不饱和化合物反应的基团与暴露于光化辐射（辐射固化基团）和3）任选的NCO-反应性基团反应的基团， A）一种或多种含有脲二酮基团的NCO-官能化合物，B）一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应的基团，其与曝光于光化辐射（辐射 - 固化基团），然后C）与除了B）之外的一种或多种饱和的含羟基化合物，在D存在下，具有OH官能度> = 2的这些化合物中的至少一种，含有一种或多种 锌化合物，与化合物C）的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。

    Low viscosity allophanates containing actinically curable groups
    10.
    发明申请
    Low viscosity allophanates containing actinically curable groups 有权
    含有光化学可固化基团的低粘度脲基甲酸酯

    公开(公告)号：US20060052526A1

    公开(公告)日：2006-03-09

    申请号：US11217207

    申请日：2005-09-01

    申请人： Jan Weikard ,  Christophe Detrembleur ,  Dorota Greszta-Franz ,  Frank Richter ,  Wolfgang Fischer ,  Jorg Schmitz ,  Holger Mundstock

    发明人： Jan Weikard ,  Christophe Detrembleur ,  Dorota Greszta-Franz ,  Frank Richter ,  Wolfgang Fischer ,  Jorg Schmitz ,  Holger Mundstock

    IPC分类号： C08G18/08

    CPC分类号： C08G18/7837 ,  B33Y70/00 ,  C08G18/672 ,  C08G18/798 ,  C08G18/8166 ,  C09D175/14 ,  C09D175/16

    摘要： The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting at temperatures of ≦130° C. A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.

    摘要翻译： 本发明涉及一种通过在<= 130℃的温度下反应制备含有脲基甲酸酯基的辐射固化粘合剂的方法。A）一种或多种含有脲二酮基团的化合物与B）一种或多种含OH官能化合物， 在曝光于光化辐射（辐射固化基团）时与烯属不饱和化合物反应，C）任选除B）之外的NCO-反应性化合物，在D）含有至少一种锌化合物的催化剂存在下反应形成 脲基甲酸酯基通过开放脲二酮环。 本发明还涉及通过本发明的方法获得的粘合剂和包含这些粘合剂的涂料组合物。