RADIATION-CURING BINDERS AND A PROCESS FOR THEIR PREPARATION
    1.
    发明申请
    RADIATION-CURING BINDERS AND A PROCESS FOR THEIR PREPARATION 有权
    辐射固化粘合剂及其制备方法

    公开(公告)号:US20100105792A1

    公开(公告)日:2010-04-29

    申请号:US12651576

    申请日:2010-01-04

    IPC分类号: C08G59/68

    摘要: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.

    摘要翻译: 本发明涉及一种制备粘合剂的方法,其包含1)脲基甲酸酯基团,2)与烯键式不饱和化合物反应的基团与暴露于光化辐射(辐射固化基团)和3)任选的NCO-反应性基团反应的基团, A)一种或多种含有脲二酮基团的NCO-官能化合物,B)一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射(辐射 - 固化基团),然后C)与除了B)之外的一种或多种饱和的含羟基化合物,在D的存在下,在具有OH官能度≥2的这些化合物中的至少一种的化合物中含有一种或多种铵 脂肪族或脂环族羧酸的盐或鏻盐,与化合物C)的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。

    Radiation-curing binders and a process for their preparation
    2.
    发明授权
    Radiation-curing binders and a process for their preparation 有权
    辐射固化粘合剂及其制备方法

    公开(公告)号:US07666970B2

    公开(公告)日:2010-02-23

    申请号:US11217728

    申请日:2005-09-01

    摘要: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.

    摘要翻译: 本发明涉及一种制备粘合剂的方法,其包含1)脲基甲酸酯基团,2)与烯键式不饱和化合物反应的基团与暴露于光化辐射(辐射固化基团)和3)任选的NCO-反应性基团反应的基团, A)一种或多种含有脲二酮基团的NCO-官能化合物,B)一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射(辐射 - 固化基团),然后C)与除了B)之外的一种或多种饱和的含羟基化合物,在D的存在下,在具有OH官能度≥2的这些化合物中的至少一种的化合物中含有一种或多种铵 脂肪族或脂环族羧酸的盐或鏻盐,与化合物C)的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。

    Process for preparing hydroxyalkyl(meth) acrylates using Lewis acid catalysts
    5.
    发明授权
    Process for preparing hydroxyalkyl(meth) acrylates using Lewis acid catalysts 有权
    使用路易斯酸催化剂制备(甲基)丙烯酸羟烷基酯的方法

    公开(公告)号:US07659425B2

    公开(公告)日:2010-02-09

    申请号:US11356334

    申请日:2006-02-16

    IPC分类号: C07C67/26 C07C69/52

    CPC分类号: C07C67/26 C07C69/54

    摘要: The present invention relates to a process for preparing hydroxyalkyl (meth)acrylates by reacting at least one compound A which contains at least one epoxide group with at least one compound B which contains at least one carboxylic acid group, wherein A and/or B also contains at least one (meth)acrylate group, in the presence of Lewis acid catalysts, each of which contains at least one directly bonded di(cyclo)alkylamino group.

    摘要翻译: 本发明涉及通过使至少一种含有至少一个环氧基的化合物A与至少一种含有至少一个羧酸基团的化合物B反应来制备(甲基)丙烯酸羟烷基酯的方法,其中A和/或B也是 在路易斯酸催化剂存在下含有至少一种(甲基)丙烯酸酯基团,其各自含有至少一个直接键合的二(环)烷基氨基。

    METHOD FOR ACTIVATING DOUBLE METAL CYANIDE CATALYSTS FOR THE PRODUCTION OF POLYETHER CARBONATE POLYOLS
    8.
    发明申请
    METHOD FOR ACTIVATING DOUBLE METAL CYANIDE CATALYSTS FOR THE PRODUCTION OF POLYETHER CARBONATE POLYOLS 有权
    用于生产聚碳酸酯多元醇的双金属氰化物催化剂的活化方法

    公开(公告)号:US20140221602A1

    公开(公告)日:2014-08-07

    申请号:US14232633

    申请日:2012-07-16

    IPC分类号: C08G64/32

    摘要: The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts with heterocumulenes for the preparation of polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances, and to a process for the preparation of polyether carbonate polyols from one or more H-functional starter substances, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, characterized in that (α) under an inert gas atmosphere, under an atmosphere of an inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, at temperatures of from 90 to 150° C., the DMC catalyst is mixed with a heterocumulene and H-functional starter substance, (β) alkylene oxide is added at temperatures of from 100 to 150° C. to the mixture from step (α) under an inert gas atmosphere, under an atmosphere of an inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, and (γ) one or more alkylene oxides and carbon dioxide are metered continuously into the mixture resulting from step (β).

    摘要翻译: 本发明涉及一种用于通过在一种或多种H功能性起始剂存在下通过二氧化碳(CO 2)与氧化烯的催化共聚来制备聚醚碳酸酯多元醇的异氰脲酸双金属氰化物(DMC)催化剂的活化方法 以及在双金属氰化物催化剂存在下从一种或多种H官能起始物质,一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法,其特征在于(α)在惰性 气体气氛中,在惰性气体/二氧化碳混合气氛下或在纯二氧化碳气氛下,在90〜150℃的温度下,将DMC催化剂与杂多烯和H官能起始物质(&bgr ;)在惰性气体气氛下,在惰性气体/二氧化碳气氛下,将氧化烯在100至150℃的温度下加入步骤(α)的混合物中 或者在纯二氧化碳气氛下,将(γ)一种或多种烯化氧和二氧化碳连续计量到由步骤(bgr)得到的混合物中。