-
11.发明授权公开(公告)号：US06572787B1
公开(公告)日：2003-06-03
申请号：US09600066
申请日：2000-07-10
申请人： Hans Michiel Huisman , Patrick Dennis Lawrence Mercera , Coen Willem Johannes Pieterse , David Schaddenhorst , Ronald Jan Schoonebeek
发明人： Hans Michiel Huisman , Patrick Dennis Lawrence Mercera , Coen Willem Johannes Pieterse , David Schaddenhorst , Ronald Jan Schoonebeek
IPC分类号： C07C104
CPC分类号： C01B3/386 , B01J23/46 , B01J23/56 , C01B3/40 , C01B2203/0261 , C01B2203/0495 , C01B2203/061 , C01B2203/062 , C01B2203/066 , C01B2203/1005 , C01B2203/1064 , C01B2203/1082 , C01B2203/1088 , C01B2203/1241 , C01B2203/1247 , C01B2203/1676 , Y02P20/52
摘要： A catalyst comprising a catalytically active metal, selected from Ru, Rh, Os and Ir, associated with at least one inorganic metal cation or precursor thereof, wherein the inorganic metal cation or precursor thereof is present in intimate association supported on or with the catalytically active metal, a process for the preparation of the catalyst, and a process for the preparation of carbon monoxide and/or hydrogen from a hydrocarbonaceous feedstock using the catalyst.
摘要翻译： 一种催化剂，其包含与至少一种无机金属阳离子或其前体相关的选自Ru，Rh，Os和Ir的催化活性金属，其中无机金属阳离子或其前体以与催化活性 金属，制备催化剂的方法，以及使用该催化剂从烃原料制备一氧化碳和/或氢的方法。
-
公开(公告)号：US08497310B2
公开(公告)日：2013-07-30
申请号：US12643706
申请日：2009-12-21
申请人： Arend Hoek , Hans Michiel Huisman
发明人： Arend Hoek , Hans Michiel Huisman
IPC分类号： C07C27/00
CPC分类号： B01J8/0278 , B01J8/065 , B01J8/22 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J2208/00548 , B01J2219/00038 , C10G2/332 , C10G2/341 , C10G2/342
摘要： The present invention relates to a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle (i.e. between regenerations or between start-up with freshly loaded catalyst and the first regeneration) by catalytic conversion of synthesis gas in a multiple reactor arrangement comprising at least two parallel operating reactors containing a catalyst capable of converting synthesis gas to hydrocarbons, and each reactor having a different relative reaction rate, wherein synthesis gas is distributed to each reactor at a feed rate proportional to the relative reaction rate in the respective reactor. It further relates to a reactor arrangement suitable for operating the process according to the invention for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle by catalytic conversion of synthesis gas comprising at least two parallel operating reactors, each containing a catalyst, wherein the reactors are connected to a common header for the distribution of synthesis gas to the reactors, and wherein the common header comprises a distribution means for selectively controlling the amount of synthesis gas fed to each reactor.
摘要翻译： 本发明涉及在生产周期（即，在再生之间或在新鲜负载的催化剂的启动与第一次再生之间）中生产通常为气态的，通常为液体的和任选的常规固体烃的方法，其通过多次合成气的催化转化 反应器装置包括至少两个并联的操作反应器，其包含能够将合成气转化为烃的催化剂，每个反应器具有不同的相对反应速率，其中合成气以与该反应器中的相对反应速率成正比的进料速率分配给每个反应器 相应的反应器。 本发明还涉及一种适用于操作根据本发明的方法的反应器装置，用于在生产循环期间通过催化转化包含至少两个平行操作反应器的催化转化来生产通常为气态的，通常为固体的烃，每个反应器含有催化剂 ，其中所述反应器连接到用于将合成气分配到所述反应器的公共集管，并且其中所述公共集管包括用于选择性地控制供给到每个反应器的合成气量的分配装置。
-
公开(公告)号：US07820726B2
公开(公告)日：2010-10-26
申请号：US11920207
申请日：2006-05-11
申请人： Anthony Malcolm Rigby , Jill Hui Chiun Chieng , Gijsbert Jan Van Heeringen , Hans Michiel Huisman
发明人： Anthony Malcolm Rigby , Jill Hui Chiun Chieng , Gijsbert Jan Van Heeringen , Hans Michiel Huisman
IPC分类号： C07C27/00
CPC分类号： C10L3/102 , B01D53/1412 , B01D53/1462 , C10L3/10 , Y02C10/06
摘要： A process for the production of normally gaseous, normally liquid and optionally normally solid hydrocarbons from a light hydrocarbonaceous feed gas stream, which feed gas stream includes sulphur compounds and carbon dioxide, the process comprising the steps of: (i) removing at least most of the sulphur compounds from the feed gas stream by an aqueous amine process in one or more reactors, optionally followed by on or more further treatment processes; (ii) controlling where necessary the amount of carbon dioxide in the feed gas stream in step (i) so as to be in the range 0.25-2.0 v/v&, preferably 0.5-1.5 v/v %, of the processed feed stream; (iii) using the feed gas stream of step (ii) to provide synthesis gas; and (iv) catalytic converting the synthesis gas of step (iii) at an elevated temperature and pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons.
摘要翻译： 一种从轻质烃类进料气流生产通常为气态，通常为液态和任选通常为固体烃的方法，该原料气流包含硫化合物和二氧化碳，该方法包括以下步骤：（i）将至少大部分 来自原料气流中的硫化合物通过一个或多个反应器中的胺水溶液方法，任选地随后进行一个或多个进一步的处理过程; （ii）在必要时控制步骤（i）中进料气流中二氧化碳的量为处理进料流的0.25-2.0v / v，优选0.5-1.5v / v％的范围; （iii）使用步骤（ii）的原料气流提供合成气; 和（iv）在升高的温度和压力下催化转化步骤（iii）的合成气，以获得通常为气态的，通常为液体的和任选通常为固体的烃。
-
公开(公告)号：US20090099269A1
公开(公告)日：2009-04-16
申请号：US11920207
申请日：2006-05-11
申请人： Anthony Malcolm Rigby , Jill Hui Chiun Chieng , Gijsbert Jan Van Heeringen , Hans Michiel Huisman
发明人： Anthony Malcolm Rigby , Jill Hui Chiun Chieng , Gijsbert Jan Van Heeringen , Hans Michiel Huisman
IPC分类号： C07C1/12
CPC分类号： C10L3/102 , B01D53/1412 , B01D53/1462 , C10L3/10 , Y02C10/06
摘要： A process for the production of normally gaseous, normally liquid and optionally normally solid hydrocarbons from a light hydrocarbonaceous feed gas stream, which feed gas stream includes sulphur compounds and carbon dioxide, the process comprising the steps of: (i) removing at least most of the sulphur compounds from the feed gas stream by an aqueous amine process in one or more reactors, optionally followed by on or more further treatment processes; (ii) controlling where necessary the amount of carbon dioxide in the feed gas stream in step (i) so as to be in the range 0.25-2.0 v/v&, preferably 0.5-1.5 v/v %, of the processed feed stream; (iii) using the feed gas stream of step (ii) to provide synthesis gas; and (iv) catalytic converting the synthesis gas of step (iii) at an elevated temperature and pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons.
摘要翻译： 一种从轻质烃类进料气流生产通常为气态，通常为液态和任选通常为固体烃的方法，该原料气流包含硫化合物和二氧化碳，该方法包括以下步骤：（i）将至少大部分 来自原料气流中的硫化合物通过一个或多个反应器中的胺水溶液方法，任选地随后进行一个或多个进一步的处理过程; （ii）在必要时控制步骤（i）中进料气流中二氧化碳的量为处理进料流的0.25-2.0v / v，优选0.5-1.5v / v％的范围; （iii）使用步骤（ii）的原料气流提供合成气; 和（iv）在升高的温度和压力下催化转化步骤（iii）的合成气，以获得通常为气态的，通常为液体的和任选通常为固体的烃。
-
公开(公告)号：US07855236B2
公开(公告)日：2010-12-21
申请号：US12096412
申请日：2006-12-06
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , C10G2300/1022 , C10G2300/4081
摘要： Method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which process comprises the steps of: (i) providing the synthesis gas; and (ii) catalytically converting the synthesis gas at an elevated temperature and a steady state total reactor pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons; the method comprising admixing the synthesis gas of step (i) with one or more inert gases to form an admixture stream prior to catalytically converting the synthesis gas in step (ii) at the steady state total reactor pressure and wherein as the activity of the catalyst converting the synthesis gas proceeds towards a steady state, the amount of inert gas(es) in the admixture stream is reduced.
摘要翻译： 开始用于从合成气中产生通常为气态，通常为液态和任选通常为固体烃的稳态过程的方法，该方法包括以下步骤：（i）提供合成气; 和（ii）在升高的温度和稳态的总反应器压力下催化转化合成气以获得通常为气态的，通常为液体的和任选的通常为固体的烃; 该方法包括将步骤（i）的合成气与一种或多种惰性气体混合以在稳定状态的总反应器压力下催化转化步骤（ii）中的合成气之前形成混合物流，并且其中作为催化剂的活性 合成气转化为稳定状态，混合物流中的惰性气体的量减少。
-
公开(公告)号：US20100160461A1
公开(公告)日：2010-06-24
申请号：US12643706
申请日：2009-12-21
申请人： Arend HOEK , Hans Michiel Huisman
发明人： Arend HOEK , Hans Michiel Huisman
CPC分类号： B01J8/0278 , B01J8/065 , B01J8/22 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J2208/00548 , B01J2219/00038 , C10G2/332 , C10G2/341 , C10G2/342
摘要： The present invention relates to a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle (i.e. between regenerations or between start-up with freshly loaded catalyst and the first regeneration) by catalytic conversion of synthesis gas in a multiple reactor arrangement comprising at least two parallel operating reactors containing a catalyst capable of converting synthesis gas to hydrocarbons, and each reactor having a different relative reaction rate, wherein synthesis gas is distributed to each reactor at a feed rate proportional to the relative reaction rate in the respective reactor. It further relates to a reactor arrangement suitable for operating the process according to the invention for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle by catalytic conversion of synthesis gas comprising at least two parallel operating reactors, each containing a catalyst, wherein the reactors are connected to a common header for the distribution of synthesis gas to the reactors, and wherein the common header comprises a distribution means for selectively controlling the amount of synthesis gas fed to each reactor.
摘要翻译： 本发明涉及在生产周期（即，在再生之间或在新鲜负载的催化剂的启动与第一次再生之间）中生产通常为气态的，通常为液体的和任选的常规固体烃的方法，其通过多次合成气的催化转化 反应器装置包括至少两个并联的操作反应器，其包含能够将合成气转化为烃的催化剂，每个反应器具有不同的相对反应速率，其中合成气以与该反应器中的相对反应速率成正比的进料速率分配给每个反应器 相应的反应器。 本发明还涉及一种适用于操作根据本发明的方法的反应器装置，用于在生产循环期间通过催化转化包含至少两个平行操作反应器的催化转化来生产通常为气态的，通常为固体的烃，每个反应器含有催化剂 ，其中所述反应器连接到用于将合成气分配到所述反应器的公共集管，并且其中所述公共集管包括用于选择性地控制供给到每个反应器的合成气量的分配装置。
-
17.发明申请公开(公告)号：US20080275144A1
公开(公告)日：2008-11-06
申请号：US12096412
申请日：2006-12-06
IPC分类号： C07C1/04
CPC分类号： C10G2/32 , C10G2300/1022 , C10G2300/4081
摘要： Method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which process comprises the steps of: (i) providing the synthesis gas; and (ii) catalytically converting the synthesis gas at an elevated temperature and a steady state total reactor pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons; the method comprising admixing the synthesis gas of step (i) with one or more inert gases to form an admixture stream prior to catalytically converting the synthesis gas in step (ii) at the steady state total reactor pressure and wherein as the activity of the catalyst converting the synthesis gas proceeds towards a steady state, the amount of inert gas(es) in the admixture stream is reduced.
摘要翻译： 开始用于从合成气中产生通常为气态，通常为液态和任选通常为固体烃的稳态过程的方法，该方法包括以下步骤：（i）提供合成气; 和（ii）在升高的温度和稳态的总反应器压力下催化转化合成气以获得通常为气态的，通常为液体的和任选的通常为固体的烃; 该方法包括将步骤（i）的合成气与一种或多种惰性气体混合以在稳定状态的总反应器压力下催化转化步骤（ii）中的合成气之前形成混合物流，并且其中作为催化剂的活性 合成气转化为稳定状态，混合物流中的惰性气体的量减少。
-
公开(公告)号：US06806297B2
公开(公告)日：2004-10-19
申请号：US10276615
申请日：2002-11-18
IPC分类号： C07C2700
CPC分类号： C10G2/30 , C01B3/386 , C01B2203/0261 , C01B2203/0405 , C01B2203/0415 , C01B2203/045 , C01B2203/0485 , C01B2203/062 , C01B2203/065 , C01B2203/0883 , C01B2203/0894 , C01B2203/1023 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/127 , C07C1/0485 , C07C2521/06 , C07C2523/75
摘要： A process for producing normally liquid hydrocarbon products from a hydrocarbonaceous feedstock, especially from normally gaseous hydrocarbon feed, having the following steps: (a) partial oxidation of the normally gaseous hydrocarbon feed at elevated pressure using air or oxygen enriched air as oxidant, to obtain a syngas mixture having hydrogen, carbon monoxide and nitrogen; (b) converting hydrogen and carbon monoxide obtained in step (a) into a normally liquid hydrocarbon product and a normally gaseous hydrocarbon product; (c) separating from the reaction mixture obtained in step (b) an off-gas mixture having nitrogen, normally gaseous hydrocarbon product, and unconverted hydrogen, carbon monoxide and normally gaseous hydrocarbon feed, insofar as such unconverted components are present; (d) combusting at least a part of the off-gas mixture in a steam raising apparatus, producing steam of an elevated pressure; and (e) expanding the steam produced in step (d) for compressing the air or oxygen enriched air and/or the normally gaseous hydrocarbon feed used in step (a); and a plant having equipment in a line-up suitable for carrying out the process.
摘要翻译： 一种从含烃原料，特别是通常气态烃进料生产常规烃类产物的方法，具有以下步骤：（a）使用空气或富氧空气作为氧化剂，在升高的压力下将常规气态烃进料部分氧化，以获得 具有氢气，一氧化碳和氮气的合成气混合物; （b）将步骤（a）中获得的氢气和一氧化碳转化为通常为液体的烃产物和通常为气态烃产物; （c）与步骤（b）中获得的反应混合物分离出具有氮气，通常为气态烃产物和未转化氢气，一氧化碳和通常为气态烃进料的废气混合物，只要存在这种未转化的组分; （d）在蒸汽提升装置中燃烧至少一部分废气混合物，产生高压蒸汽; 和（e）扩大在步骤（d）中产生的用于压缩步骤（a）中使用的空气或富氧空气和/或常规气态烃进料的蒸汽; 以及具有适合于执行该过程的阵列中的设备的设备。
-
-
-
-
-
-
-
搜索结果
18 条记录 (耗时 0.022 秒)
