公开(公告)号：US20240294450A1

公开(公告)日：2024-09-05

申请号：US18423216

申请日：2024-01-25

Applicant: Massachusetts Institute of Technology

Inventor： Mircea Dinca ,  Constanze Nicole Neumann

IPC: C07C29/44 ,  B01J23/46 ,  B01J31/16 ,  C07C29/16 ,  C07C31/12 ,  C07C31/125 ,  C07F15/00 ,  C07F15/04 ,  C07F15/06

CPC classification number: C07C29/44 ,  B01J23/46 ,  B01J31/1691 ,  C07C31/12 ,  C07C31/125 ,  C07F15/0046 ,  C07F15/04 ,  C07F15/06 ,  B01J2231/46 ,  B01J2531/0208 ,  B01J2531/821 ,  B01J2531/845 ,  B01J2531/847 ,  C07C29/16

Abstract: Compositions and methods of use related to metal organic frameworks (MOFs) and/or nanoparticles are generally described. In some embodiments, methods and compositions for the catalytic upgrading of alcohols using MOFs and/or nanoparticles associated with MOFs are generally described. In some embodiments, a catalytic MOF composition is provided, wherein the MOF composition comprises a MOF compound and a plurality of metal catalytic compounds. In some embodiments, an alcohol may be exposed to the MOF composition and/or a plurality of nanoparticles associated with the MOF composition such that the alcohol is converted to a higher order alcohol. Advantageously, in some embodiments, the alcohol conversion occurs at a relatively high turnover frequency and/or with a relatively high selectivity as compared to traditional methods for converting alcohols.

公开(公告)号：US20180297972A1

公开(公告)日：2018-10-18

申请号：US15766381

申请日：2016-09-06

Applicant: UBE INDUSTRIES, LTD.

Inventor： Atsushi YAMADA ,  Yasushi YAMAMOTO

IPC: C07D307/33 ,  B01J23/46

CPC classification number: C07D307/33 ,  B01J23/46 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  C07B61/00

Abstract: Provided is a method for producing γ-valerolactone that is hard to elute metallic components and has high productivity. γ-Valerolactone is synthesized by bringing a levulinic acid compound represented by the formula (1) (where R represents a hydrogen atom, a linear alkyl group of 1 to 6 carbon atoms or a branched alkyl group of 3 to 6 carbon atoms) into contact with hydrogen in the presence of a catalyst in which two or more different kinds of metals of Group VIII to Group X metals in the periodic table are supported on a support.

公开(公告)号：US20180147565A1

公开(公告)日：2018-05-31

申请号：US15881170

申请日：2018-01-26

Applicant: Korea Research Institute of Chemical Technology

Inventor： Jong Wook BAE ,  Tae Sun CHANG ,  Beom Sik KIM ,  Jae Hyun PARK ,  Ji Soo NAM

IPC: B01J23/46 ,  B01J27/24 ,  B01J35/00 ,  B01J35/10 ,  B01J37/08 ,  C07C51/12

CPC classification number: B01J23/464 ,  B01J23/46 ,  B01J27/24 ,  B01J32/00 ,  B01J35/0006 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/08 ,  B01J37/084 ,  B01J37/086 ,  C07C51/12 ,  C07C67/36 ,  C07C53/08 ,  C07C69/14

Abstract: A carbon nitride heterogeneous catalyst containing rhodium, a method for preparing the catalyst, and a method for preparing acetic acid using the catalyst is disclosed. The heterogeneous catalyst is characterized in that the rhodium metal is contained in carbon nitride which is a support insoluble in a liquid solvent, such as water or alcohol. Thus, the catalyst can easily be separated from a resulting product even by a simple process such as filtration. Accordingly, the carbon nitride heterogeneous catalyst exhibits excellent long-term stability and activity by being capable of overcoming the disadvantages of the method using a conventional homogeneous catalyst and minimizing the phenomenon of rhodium leaching, compared to the results of the conventional homogeneous catalytic reactions. The catalyst can thus be effectively used for the preparation of acetic acid by a carbonylation reaction between methanol and carbon monoxide.

公开(公告)号：US20170368545A1

公开(公告)日：2017-12-28

申请号：US15539074

申请日：2015-12-21

Applicant: Click Materials Corp.

Inventor： Curtis BERLINGUETTE ,  Danielle SALVATORE ,  Kevan DETTLEBACH ,  Jesse HUDKINS

IPC: B01J35/00 ,  C25B11/04 ,  C25B1/04 ,  B01J37/34 ,  B01J23/75 ,  B01J23/08 ,  B01J23/745 ,  B01J23/34 ,  B01J23/24 ,  B01J23/14 ,  H01M4/90 ,  B01J37/02

CPC classification number: B01J35/0033 ,  B01J23/08 ,  B01J23/14 ,  B01J23/24 ,  B01J23/34 ,  B01J23/46 ,  B01J23/70 ,  B01J23/745 ,  B01J23/75 ,  B01J27/135 ,  B01J37/0215 ,  B01J37/0219 ,  B01J37/12 ,  B01J37/344 ,  C25B1/04 ,  C25B9/10 ,  C25B11/0442 ,  C25B11/0447 ,  H01M4/9016 ,  Y02E60/366

Abstract: The present invention provides a method for making materials and electrocatalytic materials comprising amorphous metals or metal oxides. This method provides a scalable preparative approach for accessing state-of-the-art electrocatalyst films, as demonstrated herein for the electrolysis of water, and extends the scope of usable substrates to include those that are non-conducting and/or three-dimensional electrodes.

公开(公告)号：US20170259247A1

公开(公告)日：2017-09-14

申请号：US15510095

申请日：2015-09-09

Applicant: Kyoto University ,  OITA UNIVERSITY ,  KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

Inventor： Hiroshi KITAGAWA ,  Kohei KUSADA ,  Hirokazu KOBAYASHI ,  Katsutoshi NAGAOKA ,  Katsutoshi SATO ,  Syo MATSUMURA ,  Tomokazu YAMAMOTO

IPC: B01J23/46 ,  F01N3/28 ,  C22C1/04 ,  C22C5/04 ,  B01J37/16 ,  B22F9/24

CPC classification number: B01J23/462 ,  B01J23/46 ,  B01J37/16 ,  B22F1/00 ,  B22F9/24 ,  B22F2009/245 ,  B22F2301/25 ,  B22F2998/10 ,  C22C1/0466 ,  C22C5/02 ,  C22C5/04 ,  C22C5/06 ,  F01N3/10 ,  F01N3/28

Abstract: The present invention provides an alloy fine particle including palladium and ruthenium, the alloy fine particle including at least one first phase in which the palladium is more abundant than the ruthenium and at least one second phase in which the ruthenium is more abundant than the palladium, the at least one first phase and the at least one second phase being separated by a phase boundary, the palladium and the ruthenium being distributed in the phase boundary in such a manner that the molar ratio of the palladium and the ruthenium continually changes, a plurality of crystalline structures being present together in the phase boundary.

公开(公告)号：US20170216820A1

公开(公告)日：2017-08-03

申请号：US15500714

申请日：2015-03-27

Applicant: Sinocat Environmental Technology Co., Ltd.

Inventor： Dacheng LI ,  Yun LI ,  Yun WANG ,  Qin WANG ,  Yongxiang CHENG ,  Yaoqiang CHEN

IPC: B01J23/46 ,  B01J23/42 ,  B01J23/44

CPC classification number: B01J23/46 ,  B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2063 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2258/018 ,  B01J21/04 ,  B01J23/42 ,  B01J23/44 ,  B01J23/63 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/038 ,  B01J37/08

Abstract: The present invention discloses a method for preparing a catalyst, comprising the following steps: (1) taking a noble metal salt solution A, adding a modified alumina support material, stirring until uniform and standing; (2) drying the material obtained in step (1) in a vacuum, and calcining at 500° C.-600° C. for 1-4 hours to obtain a powder material containing the noble metal; (3) mixing the noble metal powder material, an adhesive and other components to be added, and ball-milling to obtain a uniform slurry; (4) preparing a noble metal solution B and adjusting pH to 0.5-1; and (5) mixing the slurry of the step (3) with the noble metal solution B, coating the mixture on a support, drying, and calcining at 500° C.-600° C. for 1-2 hours to obtain the target product. The method for preparing the catalyst of the present invention is simple, the conditions of the preparation process are easy to control and the preparation method has strong practicality. The prepared catalyst has a good quality, a low ignition temperature and a high catalytic conversion rate for methane at a relatively low temperature.

公开(公告)号：US09499402B2

公开(公告)日：2016-11-22

申请号：US14118301

申请日：2012-05-15

Applicant: Debasish Chakraborty

Inventor： Debasish Chakraborty

IPC: C01B3/08 ,  H01M8/06 ,  B01J21/04 ,  B01J23/46 ,  B01J23/58 ,  B01J23/63 ,  B01J23/644 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  C01B3/04

CPC classification number: C01B3/08 ,  B01J21/04 ,  B01J23/46 ,  B01J23/462 ,  B01J23/58 ,  B01J23/63 ,  B01J23/644 ,  B01J23/6447 ,  B01J35/00 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/02 ,  B01J37/0203 ,  B01J37/0211 ,  B01J37/0221 ,  B01J37/08 ,  C01B3/047 ,  H01M8/0606 ,  Y02E60/324 ,  Y02E60/364 ,  Y02E60/50

Abstract: In a method of preparing a ruthenium-containing catalyst on a non-conductive metal oxide support comprises dissolving one or more ruthenium precursor compounds in an liquid organic polyol, combining the thus obtained solution with (a) nano-powder(s) of one or more metal oxides in a ratio of moles metal oxide(s) to moles ruthenium atoms in the one or more ruthenium precursor compounds of about 0:1 to about 6:1, the metal oxide nano-powder(s) having a surface area of from about 5 to about 300 m2/g and a point of zero charge (PZC) of pH 5.5 or higher, agitating the thus obtained mixture, adding pre-shaped alumina support pellets to the agitated mixture, which is than heated at a temperature of about 50° C. to the boiling point of the organic polyol, until the reaction is finished, cooling the mixture and combining it with an aqueous solution of NaNO3 and/or KNO3, agitating the resultant mixture, separating the solvent and the solids, and drying the thus obtained solid pellets of alumina, or alumina and the metal oxide(s) of the nano-powder(s) coated with ruthenium and an additional amount Na and/or K ions. Also disclosed is the supported ruthenium-containing catalyst obtainable by the method and the use thereof in decomposing ammonia into nitrogen and oxygen.

Abstract translation: 在非导电性金属氧化物载体上制备含钌催化剂的方法包括将一种或多种钌前体化合物溶解在液体有机多元醇中，将由此获得的溶液与（a）一种或多种纳米粉末组合， 一种或多种钌前体化合物中的金属氧化物与一种或多种钌前体化合物中钌原子摩尔数的摩尔比为大约0:1至大约6:1的金属氧化物，所述金属氧化物纳米粉末的表面积为 约5至约300m 2 / g和pH 5.5或更高的零电荷点（PZC），搅拌由此获得的混合物，将预形状的氧化铝载体颗粒加入到搅拌的混合物中，该混合物在温度为 约50℃至有机多元醇的沸点，直到反应完成，冷却混合物并将其与NaNO 3和/或KNO 3的水溶液混合，搅拌所得混合物，分离溶剂和固体，和 干燥由此获得的氧化铝固体颗粒， 或氧化铝和涂覆有钌的纳米粉末和额外量的Na和/或K离子的金属氧化物。 还公开了通过该方法获得的负载的含钌催化剂及其在将氨分解成氮和氧的用途。

公开(公告)号：US09314776B2

公开(公告)日：2016-04-19

申请号：US14440096

申请日：2013-10-10

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC

Inventor： Shudong Zhang ,  Yingjie Jin ,  Xiangqian Ni ,  Jie Li ,  Xiwen Zhang ,  Xinwei Zhang

IPC: C07C45/33 ,  B01J23/00 ,  B01J21/00 ,  B01J37/00 ,  B01J23/89 ,  B01J23/652 ,  B01J23/02 ,  B01J21/04 ,  B01J35/00 ,  B01J35/02 ,  B01J37/04 ,  B01J37/16 ,  B01J37/03 ,  B01J37/08 ,  C07C29/50 ,  B01J23/46 ,  B01J23/887

CPC classification number: B01J23/8993 ,  B01J21/04 ,  B01J23/00 ,  B01J23/002 ,  B01J23/02 ,  B01J23/46 ,  B01J23/6525 ,  B01J23/887 ,  B01J23/89 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/035 ,  B01J37/04 ,  B01J37/08 ,  B01J37/088 ,  B01J37/16 ,  B01J37/18 ,  B01J2523/00 ,  C07C29/50 ,  C07C45/33 ,  C07C47/06 ,  C07C31/08 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/822 ,  B01J2523/845 ,  B01J2523/847

Abstract: This invention relates to a composite oxide, production and use thereof as a methane selective oxidizing catalyst. The composite oxide has a composition as illustrated by the formula RhRxMoyVzOδ-α, wherein the symbols are as defined in the specification. When used as a methane selective oxidizing catalyst, the present composite oxide provides a high methane conversion and a high selectivity to the aimed products.

Abstract translation: 本发明涉及复合氧化物，其作为甲烷选择氧化催化剂的生产和应用。 复合氧化物具有式RhRxMoyVzOδ-α所示的组成，其中符号如说明书中所定义。 当用作甲烷选择性氧化催化剂时，本发明复合氧化物提供高甲烷转化率和对目标产物的高选择性。

公开(公告)号：US09295983B2

公开(公告)日：2016-03-29

申请号：US14582019

申请日：2014-12-23

Applicant: The Regents of the University of California ,  Chevron U.S.A. Inc.

Inventor： Alexander Katz ,  Namal De Silva ,  Andrew Solovyov ,  Alexander Kuperman ,  Cong-Yan Chen ,  Partha Nandi ,  Alexander Okrut ,  Igor Busygin

IPC: B01J31/24 ,  C07F15/00 ,  C07C5/03 ,  B01J23/46 ,  B01J31/16 ,  B01J31/06 ,  B01J35/00

CPC classification number: B01J31/24 ,  B01J23/46 ,  B01J23/468 ,  B01J31/066 ,  B01J31/16 ,  B01J31/20 ,  B01J31/2273 ,  B01J31/2404 ,  B01J31/2447 ,  B01J31/2457 ,  B01J35/0013 ,  B01J37/086 ,  B01J2231/641 ,  B01J2231/645 ,  B01J2231/70 ,  B01J2531/0211 ,  B01J2531/827 ,  B01J2540/10 ,  B01J2540/50 ,  C07C5/03 ,  C07C2531/24 ,  C07F15/0033

Abstract: The invention provides complexes in which a calixarene-related compound is coordinated to an iridium-containing metal colloid. The complexes can be immobilized on a substrate. The complexes of the invention are useful as tunable and highly robust isolated metal colloids that find use in binding of molecules and catalysis of chemical reactions.

公开(公告)号：US20150321179A1

公开(公告)日：2015-11-12

申请号：US14440096

申请日：2013-10-10

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC

Inventor： Shudong ZHANG ,  Yingjie JIN ,  Xiangqian NI ,  Jie LI ,  Xiwen ZHANG ,  Xinwei ZHANG

IPC: B01J23/89 ,  B01J23/02 ,  B01J21/04 ,  B01J35/00 ,  C07C45/33 ,  B01J37/04 ,  B01J37/16 ,  B01J37/03 ,  B01J37/08 ,  C07C29/50 ,  B01J23/652 ,  B01J35/02

CPC classification number: B01J23/8993 ,  B01J21/04 ,  B01J23/00 ,  B01J23/002 ,  B01J23/02 ,  B01J23/46 ,  B01J23/6525 ,  B01J23/887 ,  B01J23/89 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/035 ,  B01J37/04 ,  B01J37/08 ,  B01J37/088 ,  B01J37/16 ,  B01J37/18 ,  B01J2523/00 ,  C07C29/50 ,  C07C45/33 ,  C07C47/06 ,  C07C31/08 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/822 ,  B01J2523/845 ,  B01J2523/847

Abstract: This invention relates to a composite oxide, production and use thereof as a methane selective oxidizing catalyst. The composite oxide has a composition as illustrated by the formula RhRxMoyVzOδ-α, wherein the symbols are as defined in the specification. When used as a methane selective oxidizing catalyst, the present composite oxide provides a high methane conversion and a high selectivity to the aimed products.

Abstract translation: 本发明涉及复合氧化物，其作为甲烷选择氧化催化剂的生产和应用。 复合氧化物具有式RhRxMoyVzOδ-α所示的组成，其中符号如说明书中所定义。 当用作甲烷选择性氧化催化剂时，本发明复合氧化物提供高甲烷转化率和对目标产物的高选择性。