摘要:
The invention provides a process for the manufacture of carbon disulphide comprising supplying a molecular oxygen-containing gas and a feedstock comprising a hydrocarbonaceous compound to a reaction zone containing a liquid elemental sulphur phase and reacting, in the liquid sulphur phase, at a temperature in the range of from 300 to 750° C., the hydrocarbonaceous compound with elemental sulphur to form carbon disulphide and hydrogen sulphide and oxidizing at least part of the hydrogen sulphide formed to elemental sulphur and water. The invention further provides the use of a liquid stream comprising carbon disulphide, hydrogen sulphide and carbonyl sulphide obtainable such process for enhanced oil recovery.
摘要:
A method for producing oil and/or gas comprising injecting a miscible enhanced oil recovery formulation into fractures, karsts, and/or vugs of a formation for a first time period from a first well; producing oil and/or gas from the fractures, karsts, and/or vugs from a second well for the first time period; injecting a miscible enhanced oil recovery formulation into the fractures, karsts, and/or vugs for a second time period from the second well; and producing oil and/or gas from the fractures, karsts, and/or vugs from the first well for the second time period.
摘要:
A process for improving the smell of a stream of elemental sulphur comprising an organic polysulphide and/or a thiol, the process comprising the following step: (a) heating the stream of liquid elemental sulphur comprising an organic polysulphide and/or a thiol at a heating temperature in the range of from 360 to 700° C., at a pressure that is sufficient to maintain a liquid elemental sulphur phase to obtain heat-treated elemental sulphur.
摘要:
The invention relates to a process for the catalytic partial oxidation of a hydrocarbonaceous feedstock, wherein a feed mixture having the hydrocarbonaceous feedstock and a molecular-oxygen containing gas is contacted with a catalyst system having an upstream part and a downstream part, the downstream part being in the form of a porous catalyst bed, wherein the catalyst system is retained in a reactor, the reactor having an upstream part that contains the upstream part of the catalyst system and a downstream part that contains the downstream part of the catalyst system, wherein the upstream part of the catalyst system only partly fills the cross-sectional area of the fluid flow path of the upstream part of the reactor and the downstream part of the catalyst system completely fills the cross-sectional area of the fluid flow path of the downstream part of the reactor. The invention further relates to a reactor having such a catalyst system and a catalytic reaction zone for the water-gas shift conversion of the effluent of the catalyst system, to a fuel cell system having such a reactor and a fuel cell, and to a vehicle provided with such a fuel cell system.
摘要:
The present invention is a method for extracting bitumen from an oil sand feed stream including at least the steps of: (a) providing an oil sand feed stream; (b) contacting the oil sand feed stream with a liquid comprising an aliphatic hydrocarbon solvent thereby obtaining a solvent-diluted oil sand slurry; (c) depositing the solvent-diluted oil sand slurry as a filter cake on a filter medium and filtering the solvent-diluted oil sand slurry, thereby obtaining a solids-enriched stream and a filtrate, wherein during the filtering the pressure above the filter cake is at least 1.7 bara; and (d) lowering the pressure of the solids-enriched stream to below 1.2 bara.
摘要:
The invention provides a process for the manufacture of carbon disulphide by reacting carbon monoxide with elemental sulphur to form carbonyl sulphide and disproportionating the carbonyl sulphide formed into carbon disulphide and carbon dioxide, the process comprising contacting a gaseous stream comprising carbon monoxide with a liquid elemental sulphur phase containing a solid catalyst at a temperature in the range of from 250 to 700° C. to obtain a gaseous phase comprising carbonyl sulphide, carbon disulphide and carbon dioxide. The invention further provides the use of a liquid stream comprising carbon disulphide, carbonyl sulphide and carbon dioxide obtainable by such process for enhanced oil recovery.
摘要:
The present invention provides a process for the selective oxidation of hydrogen sulphide contained in a hydrogen sulphide-containing hydrocarbon feed gas to elemental sulphur. The hydrogen sulphide-containing hydrocarbon feed gas and a sulphur dioxide-containing gas are supplied to a reaction zone containing a TiO2-comprising catalyst, wherein elemental sulphur and a gaseous stream depleted in hydrogen sulphide are formed. The gas feeds are contacted with the TiO2 containing catalyst at elevated pressure and at a temperature in the range of from 120 and below 160° C., under such conditions that the elemental sulphur formed is essentially in liquid form. At least part of the sulphur dioxide-containing gas is obtained by combusting elemental sulphur to obtain a gaseous mixture of sulphur dioxide and nitrogen and then concentrating the gaseous mixture to provide the sulphur dioxide-containing gas.
摘要:
The present invention provides a process for purifying natural gas, comprising removing mercaptans from a natural gas stream by a combination of an amine-based separation unit and a selective oxidation unit to obtain a purified natural gas stream, wherein at least part of the mercaptans are converted into at least elemental sulphur in the selective oxidation unit by selective catalytic oxidation.
摘要:
The invention provides an auxiliary power unit (APU) and process for electricity generation in combination with an internal combustion engine in which the APU includes a solid oxide fuel cell (SOFC) having an inlet for fuel, an inlet for air and/or engine exhaust gas, and an outlet for off-gas; anda catalytic partial oxidation reformer (CPOx) having an outlet which is connected to the inlet for fuel of the SOFC and an inlet for reactants, wherein the inlet for reactants is connected to an outlet for engine exhaust gas of the internal combustion engine through an evaporator having an inlet for fuel and an inlet for engine exhaust gas and an outlet which is connected to the inlet of the CPOx.
摘要:
The invention provides a process for the manufacture of carbon disulphide comprising supplying a molecular oxygen-containing gas and a feedstock comprising a hydrocarbonaceous compound to a reaction zone containing a liquid elemental sulphur phase and reacting, in the liquid sulphur phase, at a temperature in the range of from 300 to 750° C., the hydrocarbonaceous compound with elemental sulphur to form carbon disulphide and hydrogen sulphide and oxidising at least part of the hydrogen sulphide formed to elemental sulphur and water. The invention further provides the use of a liquid stream comprising carbon disulphide, hydrogen sulphide and carbonyl sulphide obtainable such process for enhanced oil recovery.