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公开(公告)号：US5591378A
公开(公告)日：1997-01-07
申请号：US271093
申请日：1994-07-06
CPC分类号： C11D3/3925
摘要： Substituted benzonitrile activators give excellent bleaching performance when combined with a peroxygen source and dissolved in solution. These substituted benzonitrile activators give best bleaching performance when the activators are multiply substituted with electron-withdrawing groups.
摘要翻译： 当与过氧源结合并溶解在溶液中时，取代的苄腈活化剂具有优异的漂白性能。 当活化剂被吸电子基团取代时，这些取代的苄腈活化剂具有最佳的漂白性能。
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公开(公告)号：US06235218B1
公开(公告)日：2001-05-22
申请号：US09444041
申请日：1999-11-19
申请人： Ulrich Annen , James E. Deline , Lafayette D. Foland , Kevin A. Klotter , Josef Müller , Michael Müller , Klaus Mundinger , Martin A. Phillippi , Alfred Ruland , Wolfgang Schäfer , Gregor Schürmann , Rudi Widder , Alfred G. Zielske
发明人： Ulrich Annen , James E. Deline , Lafayette D. Foland , Kevin A. Klotter , Josef Müller , Michael Müller , Klaus Mundinger , Martin A. Phillippi , Alfred Ruland , Wolfgang Schäfer , Gregor Schürmann , Rudi Widder , Alfred G. Zielske
IPC分类号： C07D26530
CPC分类号： C11D3/3925 , C07D295/15
摘要： A process is provided for the preparation of a compound having the structure of Formula I The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of pH control substantially prevents formation of an undesirable protonated reaction intermediate.
摘要翻译： 提供了一种制备具有式I结构的化合物的方法。该方法包括使杂环胺与约8至14的pH范围内的单醛或二醛反应，然后将如此反应的杂环胺与烷基化 在pH不低于约2的情况下，pH控制的使用基本上防止形成不期望的质子化反应中间体。
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公开(公告)号：US6017464A
公开(公告)日：2000-01-25
申请号：US207797
申请日：1998-12-09
申请人： James E. Deline
发明人： James E. Deline
IPC分类号： C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C09K3/00
CPC分类号： C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitrites for bleaching applications.
摘要翻译： 提供漂白组合物，其包含两个腈基团，其中每个腈通过亚甲基单元与季氮结合。 季氮是饱和环的一部分。 该饱和环除了季氮之外还含有2至8个原子。 活性氧源将与亚硝酸盐反应，用于漂白应用。
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公开(公告)号：US6010994A
公开(公告)日：2000-01-04
申请号：US758540
申请日：1996-11-29
申请人： Clement K. Choy , James E. Deline , Lafayette D. Foland , Aram Garabedian, Jr. , Kevin A. Klotter , Michael J. Petrin , Martin J. Phillippi , William L. Smith
发明人： Clement K. Choy , James E. Deline , Lafayette D. Foland , Aram Garabedian, Jr. , Kevin A. Klotter , Michael J. Petrin , Martin J. Phillippi , William L. Smith
IPC分类号： C07D295/14 , C07D295/15 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/04 , C11D17/08 , D06L3/02 , H04B7/06 , C09K3/00 , C11D1/62
CPC分类号： C07D295/15 , C11D17/041 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： The invention provides liquid cleaning or bleaching compositions containing compounds having the structure of Formula I ##STR1## wherein A is a saturated ring formed by five atoms in addition to the N.sub.1 atom, the five saturated ring atoms being four carbon atoms and a heteroatom, the substituent R.sub.1 bound to the N.sub.1 atom of the Formula I structure including either (a) a C.sub.1-24 alkyl or alkoxylated alkyl where the alkoxy is C.sub.2-4, (b) a C.sub.4-24 cycloalkyl, (c) a C.sub.7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C.sub.2-4, or (e) --CR.sub.2 R.sub.3 CN where R.sub.2 and R.sub.3 are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, the R.sub.2 and R.sub.3 substituents are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, and wherein Y is a generally anionic counterion and Z is in the range of 0 to 10. Additional, adjunct materials commonly found in liquid cleaning and bleaching compositions can be added.
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公开(公告)号：US5958289A
公开(公告)日：1999-09-28
申请号：US62878
申请日：1998-04-20
申请人： James W. Arbogast , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Kevin A. Klotter , Michael J. Petrin , William L. Smith , Alfred G. Zielske
发明人： James W. Arbogast , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Kevin A. Klotter , Michael J. Petrin , William L. Smith , Alfred G. Zielske
IPC分类号： C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C09K3/00 , C01B15/00 , C07D265/30
CPC分类号： C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： Bleaching compositions are provided that comprise a nitrile containing compound that has the nitrile bonded to a quaternary nitrogen through a methylene unit (where one or both of the normal hydrogens can be substituted), and two of the quaternary nitrogen bonds are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitrile for bleaching applications. Particularly preferred nitrile containing compounds are N-alkyl morpholinium acetonitrile salts.
摘要翻译： 提供漂白组合物，其包含含腈化合物，其腈通过亚甲基单元（其中一个或两个正常氢可被取代）与季氮结合，并且两个季氮键是饱和环的一部分 。 该饱和环除了季氮之外还含有2至8个原子。 活性氧源将与腈反应，用于漂白应用。 特别优选的含腈化合物是N-烷基吗啉鎓乙腈盐。
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公开(公告)号：US5877315A
公开(公告)日：1999-03-02
申请号：US59112
申请日：1998-04-13
申请人： James E. Deline , Kevin A. Klotter
发明人： James E. Deline , Kevin A. Klotter
IPC分类号： C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06
CPC分类号： C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.
摘要翻译： 提供漂白组合物，其包含两个腈基团，其中每个腈通过亚甲基单元与季氮结合。 季氮是饱和环的一部分。 该饱和环除了季氮之外还含有2至8个原子。 活性氧源将与腈类反应，用于漂白应用。
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公开(公告)号：US5814242A
公开(公告)日：1998-09-29
申请号：US758545
申请日：1996-11-29
申请人： Vincent E. Alvarez , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Michael J. Petrin , William L. Smith , Barry A. Sudbury , Alfred G. Zielske
发明人： Vincent E. Alvarez , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Michael J. Petrin , William L. Smith , Barry A. Sudbury , Alfred G. Zielske
IPC分类号： C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C09K3/00
CPC分类号： C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I ##STR1## wherein A is a saturated ring formed by a plurality of atoms in addition to the N.sub.1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R.sub.1 bound to the N.sub.1 atom of the Formula I structure including either (a) a C.sub.1-24 alkyl or alkoxylated alkyl where the alkoxy is C.sub.2-4, (b) a C.sub.4-24 cycloalkyl, (c) a C.sub.7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C.sub.2-4, or (e) --CR.sub.2 R.sub.3 C.tbd.N where R.sub.2 and R.sub.3 are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, the R.sub.2 and R.sub.3 substituents being each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.
摘要翻译： 本发明的优选实施方案是具有式I结构的杂环阳离子活化剂，其中A是除N1原子之外由多个原子形成的饱和环，饱和环原子包括至少一个碳原子和 O，S和N原子中的至少一个，取代基R 1与式I结构的N1原子结合，包括（a）C 1-4烷基或烷氧基烷基，其中烷氧基是C 2-4，（b）a C4-24环烷基，（c）C7-24烷芳基，（d）重复或非重复烷氧基或烷氧基化醇，其中烷氧基单元是C 2-4，或（e）-CR 2 R 3 C 3 N N，其中R 2和R 3各自为H ，C 1-4烷基，环烷基或烷芳基，或重复或非重复烷氧基或烷氧基化醇，其中烷氧基单元为C 2-4，R 2和R 3取代基各为H，C 1-4烷基，环烷基或烷芳基， 或重复或不重复的烷氧基或烷氧基化醇，其中烷氧基单元为C 2-4，Z在0至10的范围内，并且其中 Y是阴离子过酸活化剂。 当这些在活性氧源的存在下溶解在水溶液中时，将共同活化以改善漂白。
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公开(公告)号：US5707542A
公开(公告)日：1998-01-13
申请号：US720875
申请日：1996-10-03
CPC分类号： C11D3/3925
摘要： Substituted benzonitrile activators give excellent bleaching performance when combined with a peroxygen source and dissolved in solution. These substituted benzonitrile activators give best bleaching performance when the activators are multiply substituted with electron-withdrawing groups.
摘要翻译： 当与过氧源结合并溶解在溶液中时，取代的苄腈活化剂具有优异的漂白性能。 当活化剂被吸电子基团取代时，这些取代的苄腈活化剂具有最佳的漂白性能。
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