公开(公告)号：US20070176165A1

公开(公告)日：2007-08-02

申请号：US11219573

申请日：2005-09-01

申请人： Stephen Forrest ,  Barry Rand ,  Michael Lange

发明人： Stephen Forrest ,  Barry Rand ,  Michael Lange

IPC分类号： H01L29/08 ,  H01L27/14 ,  H01L31/0232

CPC分类号： H01L51/4246 ,  G01S7/4816 ,  H01L27/305 ,  H01L31/101 ,  H01L51/0037 ,  H01L51/0053 ,  H01L51/0062 ,  H01L51/0078 ,  H01L2251/308 ,  Y02E10/549

摘要： The present invention is directed to organic photosensitive optoelectronic devices and methods of use for determining the position of a light source. Provided is an organic position sensitive detector (OPSD) comprising: a first electrode, which is resistive and may be either an anode or a cathode; a first contact in electrical contact with the first electrode; a second contact in electrical contact with the first electrode; a second electrode disposed near the first electrode; a donor semiconductive organic layer disposed between the first electrode and the second electrode; and an acceptor semiconductive organic layer disposed between the first electrode and the second electrode and adjacent to the donor semiconductive organic layer. A hetero-junction is located between the donor layer and the acceptor layer, and at least one of the donor layer and the acceptor layer is light absorbing. The OPSD has an optical beam spatial resolution of 20 μm and measurements are insensitive to fluctuations in incident light beam intensity and background illumination. The response of the OPSD shows high linearity, low positional error, high spatial resolution, and good beam tracking velocity. The OPSDs exhibited linearities and positional uncertainties of

摘要翻译： 本发明涉及有机光敏光电器件和用于确定光源位置的方法。 提供了一种有机位置敏感检测器（OPSD），其包括：第一电极，其是电阻性的并且可以是阳极或阴极; 与所述第一电极电接触的第一接触; 与所述第一电极电接触的第二触点; 设置在第一电极附近的第二电极; 设置在所述第一电极和所述第二电极之间的供体半导体有机层; 以及设置在第一电极和第二电极之间并且与施主半导体有机层相邻的受主半导体有机层。 异质结位于供体层和受主层之间，供体层和受体层中的至少一个是光吸收的。 OPSD的光束空间分辨率为20um，测量对入射光束强度和背景照明的波动不敏感。 OPSD的响应显示出高线性度，低位置误差，高空间分辨率和良好的光束跟踪速度。 OPSD显示线性和位置不确定度<1％。

公开(公告)号：US20070096085A1

公开(公告)日：2007-05-03

申请号：US11263865

申请日：2005-11-02

申请人： Barry Rand ,  Stephen Forrest

发明人： Barry Rand ,  Stephen Forrest

IPC分类号： H01L35/24 ,  H01L29/08 ,  H01L51/00

CPC分类号： H01L51/4246 ,  B82Y10/00 ,  H01L51/0046 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0078 ,  H01L51/4253 ,  Y02E10/549

摘要： A photosensitive device includes a series of organic photoactive layers disposed between two electrodes. Each layer in the series is in direct contact with a next layer in the series. The series is arranged to form at least one donor-acceptor heterojunction, and includes a first organic photoactive layer comprising a first host material serving as a donor, a thin second organic photoactive layer comprising a second host material disposed between the first and a third organic photoactive layer, and the third organic photoactive layer comprising a third host material serving as an acceptor. The first, second, and third host materials are different. The thin second layer serves as an acceptor relative to the first layer or as a donor relative to the third layer.

摘要翻译： 感光装置包括一系列设置在两个电极之间的有机光活性层。 该系列中的每个层与该系列中的下一层直接接触。 该系列被布置成形成至少一个供体 - 受体异质结，并且包括第一有机光活性层，其包含用作供体的第一主体材料，薄的第二有机光活性层，其包含设置在第一和第三有机 光活性层，第三有机光活性层包含用作受体的第三主体材料。 第一，第二和第三主机材料是不同的。 相对于第三层，薄的第二层用作相对于第一层或作为供体的受体。

公开(公告)号：US20080001144A1

公开(公告)日：2008-01-03

申请号：US11810782

申请日：2007-06-06

申请人： Barry Rand ,  Stephen Forrest ,  Mark Thompson

发明人： Barry Rand ,  Stephen Forrest ,  Mark Thompson

IPC分类号： H01L51/44

CPC分类号： B82Y10/00 ,  H01L51/0046 ,  H01L51/0062 ,  H01L51/0078 ,  H01L51/0086 ,  H01L51/4246 ,  H01L2251/308 ,  Y02E10/549

摘要： A photosensitive cell includes an anode and a cathode; a donor-type organic material and an acceptor-type organic material forming a donor-acceptor junction connected between the anode and the cathode; and an exciton blocking layer connected between the acceptor-type organic material of the donor-acceptor junction and the cathode, the blocking layer consisting essentially of a material that has a hole mobility of at least 10−7 cm2/V-sec or higher, where a HOMO of the blocking layer is higher than or equal to a HOMO of the acceptor-type material.

摘要翻译： 光敏电池包括阳极和阴极; 供体型有机材料和形成连接在阳极和阴极之间的供体 - 受体结的受主型有机材料; 以及连接在供体 - 受体结的受主型有机材料和阴极之间的激子阻挡层，该阻挡层基本上由具有至少10 -7 cm的空穴迁移率的材料组成 2秒/ V秒以上，其中阻挡层的HOMO高于或等于受主型材料的HOMO。

公开(公告)号：US20060278944A1

公开(公告)日：2006-12-14

申请号：US11150143

申请日：2005-06-13

申请人： Barry Rand ,  Stephen Forrest ,  Mark Thompson

发明人： Barry Rand ,  Stephen Forrest ,  Mark Thompson

IPC分类号： H01L27/14

CPC分类号： B82Y10/00 ,  H01L51/0046 ,  H01L51/0062 ,  H01L51/0078 ,  H01L51/0086 ,  H01L51/4246 ,  H01L2251/308 ,  Y02E10/549

摘要： A photosensitive cell includes an anode and a cathode; a donor-type organic material and an acceptor-type organic material forming a donor-acceptor junction connected between the anode and the cathode; and an exciton blocking layer connected between the acceptor-type organic material of the donor-acceptor junction and the cathode, the blocking layer consisting essentially of a material that has a hole mobility of at least 10−7 cm2NV-sec or higher, where a HOMO of the blocking layer is higher than or equal to a HOMO of the acceptor-type material.

摘要翻译： 光敏电池包括阳极和阴极; 供体型有机材料和形成连接在阳极和阴极之间的供体 - 受体结的受主型有机材料; 以及连接在供体 - 受体结的受主型有机材料和阴极之间的激子阻挡层，该阻挡层基本上由具有至少10 -7 cm的空穴迁移率的材料组成 其中阻挡层的HOMO高于或等于受体型材料的HOMO。

公开(公告)号：US20100301320A1

公开(公告)日：2010-12-02

申请号：US12789202

申请日：2010-05-27

申请人： Barry Rand ,  David Cheyns ,  Benjamin Kam

发明人： Barry Rand ,  David Cheyns ,  Benjamin Kam

IPC分类号： H01L51/46 ,  H01L51/48 ,  H01L51/54 ,  H01L51/56

CPC分类号： H01L51/4246 ,  B82Y10/00 ,  H01L51/0046 ,  H01L51/442 ,  Y02E10/549

摘要： An organic optoelectronic device and a method for manufacturing the same are disclosed. In one aspect, the device has a stack of layers. The stack includes a buffer layer and a first organic semiconductor layer adjacent to the buffer layer at a first side of the buffer layer. The buffer layer includes at least one transition metal oxide doped with a metal.

摘要翻译： 公开了一种有机光电子器件及其制造方法。 在一个方面，该装置具有一叠层。 堆叠包括缓冲层和在缓冲层的第一侧与缓冲层相邻的第一有机半导体层。 缓冲层包括掺杂有金属的至少一种过渡金属氧化物。

公开(公告)号：US08987589B2

公开(公告)日：2015-03-24

申请号：US11486163

申请日：2006-07-14

申请人： Barry Rand ,  Stephen R. Forrest ,  Diana Pendergrast Burk

发明人： Barry Rand ,  Stephen R. Forrest ,  Diana Pendergrast Burk

IPC分类号： H01L31/0256 ,  H01L51/42 ,  B82Y10/00 ,  H01L27/30 ,  H01L51/00

CPC分类号： H01L51/4246 ,  B82Y10/00 ,  H01L27/302 ,  H01L51/0046 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0078 ,  H01L51/4253 ,  Y02E10/549

摘要： An organic photovoltaic cell includes an anode and a cathode, and a plurality of organic semiconductor layers between the anode and the cathode. At least one of the anode and the cathode is transparent. Each two adjacent layers of the plurality of organic semiconductor layers are in direct contact. The plurality of organic semiconductor layers includes an intermediate layer consisting essentially of a photoconductive material, and two sets of at least three layers. A first set of at least three layers is between the intermediate layer and the anode. Each layer of the first set consists essentially of a different organic semiconductor material having a higher LUMO and a higher HOMO, relative to the material of an adjacent layer of the plurality of organic semiconductor layers closer to the cathode. A second set of at least three layers is between the intermediate layer and the cathode. Each layer of the second set consists essentially of a different organic semiconductor material having a lower LUMO and a lower HOMO, relative to the material of an adjacent layer of the plurality of organic semiconductor layers closer to the anode.

摘要翻译： 有机光伏电池包括阳极和阴极，以及在阳极和阴极之间的多个有机半导体层。 阳极和阴极中的至少一个是透明的。 多个有机半导体层中的每两相邻层直接接触。 多个有机半导体层包括基本上由光电导材料组成的中间层和两组至少三层。 中间层和阳极之间至少有三层的第一组。 相对于更靠近阴极的多个有机半导体层的相邻层的材料，第一组的每个层基本上由具有较高LUMO和较高HOMO的不同有机半导体材料组成。 第二组至少三层在中间层和阴极之间。 相对于更靠近阳极的多个有机半导体层的相邻层的材料，第二组的每个层基本上由具有较低LUMO和较低HOMO的不同有机半导体材料组成。

公开(公告)号：US08242493B2

公开(公告)日：2012-08-14

申请号：US13150594

申请日：2011-06-01

申请人： Barry Rand ,  Stephen R. Forrest ,  Kristin L. Mutolo ,  Elizabeth Mayo ,  Mark E. Thompson

发明人： Barry Rand ,  Stephen R. Forrest ,  Kristin L. Mutolo ,  Elizabeth Mayo ,  Mark E. Thompson

IPC分类号： H01L51/46

CPC分类号： H01L51/0078 ,  C09B47/00 ,  C09B47/04 ,  H01L51/008 ,  H01L51/424 ,  H01L51/4246 ,  Y02E10/52 ,  Y02E10/549

摘要： An organic photosensitive optoelectronic device includes an anode, a cathode, and a donor-acceptor heterojunction between the anode and the cathode, the heterojunction including a donor-like material and an acceptor-like material, wherein at least one of the donor-like material and the acceptor-like material includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound, wherein the subporphyrin or subporphyrazine compound includes boron.

摘要翻译： 有机光敏光电子器件包括在阳极和阴极之间的阳极，阴极和供体 - 受体异质结，异质结包括施主样材料和受体样材料，其中至少一个供体样材料 并且受体样材料包括亚酞菁，卟啉和/或子卟吩化合物，其中卟啉或子卟吩化合物包括硼。

公开(公告)号：US08592804B2

公开(公告)日：2013-11-26

申请号：US12789202

申请日：2010-05-27

申请人： Barry Rand ,  David Cheyns ,  Benjamin Kam

发明人： Barry Rand ,  David Cheyns ,  Benjamin Kam

IPC分类号： H01L51/46

CPC分类号： H01L51/4246 ,  B82Y10/00 ,  H01L51/0046 ,  H01L51/442 ,  Y02E10/549

摘要： An organic optoelectronic device and a method for manufacturing the same are disclosed. In one aspect, the device has a stack of layers. The stack includes a buffer layer and a first organic semiconductor layer adjacent to the buffer layer at a first side of the buffer layer. The buffer layer includes at least one transition metal oxide doped with a metal.

摘要翻译： 公开了一种有机光电子器件及其制造方法。 在一个方面，该装置具有一叠层。 堆叠包括缓冲层和在缓冲层的第一侧与缓冲层相邻的第一有机半导体层。 缓冲层包括掺杂有金属的至少一种过渡金属氧化物。

公开(公告)号：US20130255758A1

公开(公告)日：2013-10-03

申请号：US11486163

申请日：2006-07-14

申请人： Barry Rand ,  Stephen R. Forrest ,  Diana Pendergrast Burk

发明人： Barry Rand ,  Stephen R. Forrest ,  Diana Pendergrast Burk

IPC分类号： H01L51/42

CPC分类号： H01L51/4246 ,  B82Y10/00 ,  H01L27/302 ,  H01L51/0046 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0078 ,  H01L51/4253 ,  Y02E10/549

摘要： An organic photovoltaic cell includes an anode and a cathode, and a plurality of organic semiconductor layers between the anode and the cathode. At least one of the anode and the cathode is transparent. Each two adjacent layers of the plurality of organic semiconductor layers are in direct contact. The plurality of organic semiconductor layers includes an intermediate layer consisting essentially of a photoconductive material, and two sets of at least three layers. A first set of at least three layers is between the intermediate layer and the anode. Each layer of the first set consists essentially of a different organic semiconductor material having a higher LUMO and a higher HOMO, relative to the material of an adjacent layer of the plurality of organic semiconductor layers closer to the cathode. A second set of at least three layers is between the intermediate layer and the cathode. Each layer of the second set consists essentially of a different organic semiconductor material having a lower LUMO and a lower HOMO, relative to the material of an adjacent layer of the plurality of organic semiconductor layers closer to the anode.

摘要翻译： 有机光伏电池包括阳极和阴极，以及在阳极和阴极之间的多个有机半导体层。 阳极和阴极中的至少一个是透明的。 多个有机半导体层中的每两相邻层直接接触。 多个有机半导体层包括基本上由光电导材料组成的中间层和两组至少三层。 中间层和阳极之间至少有三层的第一组。 相对于更靠近阴极的多个有机半导体层的相邻层的材料，第一组的每个层基本上由具有较高LUMO和较高HOMO的不同有机半导体材料组成。 第二组至少三层在中间层和阴极之间。 相对于更靠近阳极的多个有机半导体层的相邻层的材料，第二组的每个层基本上由具有较低LUMO和较低HOMO的不同有机半导体材料组成。

公开(公告)号：US20110253992A1

公开(公告)日：2011-10-20

申请号：US13150594

申请日：2011-06-01

申请人： Barry Rand ,  Stephen R. Forrest ,  Kristin L. Mutolo ,  Elizabeth Mayo ,  Mark E. Thompson

发明人： Barry Rand ,  Stephen R. Forrest ,  Kristin L. Mutolo ,  Elizabeth Mayo ,  Mark E. Thompson

IPC分类号： H01L51/46

CPC分类号： H01L51/0078 ,  C09B47/00 ,  C09B47/04 ,  H01L51/008 ,  H01L51/424 ,  H01L51/4246 ,  Y02E10/52 ,  Y02E10/549

摘要： An organic photosensitive optoelectronic device includes an anode, a cathode, and a donor-acceptor heterojunction between the anode and the cathode, the heterojunction including a donor-like material and an acceptor-like material, wherein at least one of the donor-like material and the acceptor-like material includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound, wherein the subporphyrin or subporphyrazine compound includes boron.

摘要翻译： 有机光敏光电子器件包括在阳极和阴极之间的阳极，阴极和供体 - 受体异质结，异质结包括施主样材料和受体样材料，其中至少一个供体样材料 并且受体样材料包括亚酞菁，卟啉和/或子卟吩化合物，其中卟啉或子卟吩化合物包括硼。