摘要:
A polythioether comprising: wherein R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6; R2 is C1-6 alkyloxy or C5-12 cycloalkyloxy, R4 is H, C1-6 alkyl, C1-6 alkyl alcohol and C0-6 alkyl substituted with where X is a halogen, m is an integer between 1 and 4, and n is an integer selected to yield a molecular weight for said polythioether of between 1000 and 10,000 Daltons.
摘要:
Sealant and potting formulations are provided which are prepared from components including ungelled mercapto-terminated polymer(s) prepared by reacting reactants comprising polyvinyl ether monomer(s) and polythiol material(s); curing agent(s) reactive with a mercapto group of the mercapto-terminated polymer; and additive(s) selected from the group consisting of fillers, adhesion promoters, plasticizers and catalysts.
摘要:
Sealant and potting formulations are provided which are prepared from components including ungelled mercapto-terminated polymer(s) prepared by reacting reactants comprising polyvinyl ether monomer(s) and polythiol material(s); curing agent(s) reactive with a mercapto group of the mercapto-terminated polymer; and additive(s) selected from the group consisting of fillers, adhesion promoters, plasticizers and catalysts.
摘要:
A polythioether comprising: R4—S&Brketopenst;R1—S—CH2CH2—(R2)m—S&Brketclosest;nR1SR4 wherein R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6; R2 is C1-6 alkyloxy or C5-12 cycloalkyloxy, R4 is H, C1-6 alkyl, C1-6 alkyl alcohol and C0-6 alkyl substituted with &Brketopenst;CH2CH2(R2)m&Brketclosest;X, where X is a halogen, m is an integer between 1 and 4, and n is an integer selected to yield a molecular weight for said polythioether of between 1000 and 10,000 Daltons.
摘要:
A blend of multimodal average molecular weight sulfur or ether linkage containing organic polymers provides sealants, potting compounds and moldable compositions with good physical properties. In the case of S-containing polythioether or polysulfide, these properties are well suited to the formulation of aerospace sealants even using standard lightweight filler technology. Sealants based upon this multimodal blend concept exhibit improved strength and toughness even when relatively large amounts of lightweight fillers are used. Multimodal polyurethanes and other ether linkage containing polymers also show enhanced physical properties.