公开(公告)号：US20050245410A1

公开(公告)日：2005-11-03

申请号：US11061893

申请日：2005-02-18

申请人： Masaki Tezuka ,  Hiroshi Tanaka ,  Takao Yokohashi ,  Takao Nishihata ,  Manabu Kikuta ,  Michiyuki Kono ,  Tetsuya Higashizaki ,  Kazuo Takei ,  Taketo Toba ,  Toshiaki Kuriyama ,  Izuho Okada ,  Fumihide Tamura ,  Ritsuo Kitada ,  Shigetaka Takamiya ,  Jun Iwamura ,  Takanori Murakami ,  Hiromoto Katsuyama ,  Teruki Matsushita

发明人： Masaki Tezuka ,  Hiroshi Tanaka ,  Takao Yokohashi ,  Takao Nishihata ,  Manabu Kikuta ,  Michiyuki Kono ,  Tetsuya Higashizaki ,  Kazuo Takei ,  Taketo Toba ,  Toshiaki Kuriyama ,  Izuho Okada ,  Fumihide Tamura ,  Ritsuo Kitada ,  Shigetaka Takamiya ,  Jun Iwamura ,  Takanori Murakami ,  Hiromoto Katsuyama ,  Teruki Matsushita

IPC分类号： B29B9/04 ,  C08G65/30 ,  C08G65/46 ,  C08J3/12 ,  C08L71/02 ,  C11D17/00

CPC分类号： C08J3/12 ,  B29B9/04 ,  C08G65/30 ,  C08J2371/00 ,  C08L71/02

摘要： The residual amount of a solvent in a water soluble nonionic alkylene oxide resin is decreased in an apparatus including an evaporation vessel and a stirring blade which scrapes-up and coats resin solution onto the inner wall surface of the evaporation vessel. A water soluble nonionic alkylene oxide resin having a crystallization temperature of 10 to 60° C. is extruded to a predetermined thickness in a molten state, the extruded molten resin is brought into contact with a metal surface which is at the crystallization temperature (Tc) or lower, and the thereby solidified resin may be cut into pellets. The resin pellets preferably are of rectangular shape and prescribed dimensions. The resin may be pulverized in a pulverizer by shearing force between a rotary blade and a fixed blade. In the pulverizer, grains smaller than a predetermined size pass through the screen, while larger grains are again pulverized.

摘要翻译： 在包括蒸发容器和搅拌叶片的装置中，水溶性非离子环氧烷烃树脂中的溶剂的残留量减少，所述搅拌叶片刮擦并将树脂溶液涂覆在蒸发容器的内壁表面上。 将结晶温度为10〜60℃的水溶性非离子性环氧烷树脂在熔融状态下挤出至规定厚度，使熔融树脂与结晶化温度（Tc）的金属表面接触， 或更低，并且由此固化的树脂可以切成颗粒。 树脂颗粒优选为矩形形状和规定尺寸。 树脂可以通过旋转叶片和固定叶片之间的剪切力在粉碎机中粉碎。 在粉碎机中，小于预定尺寸的颗粒通过筛网，而较大的颗粒再次被粉碎。

公开(公告)号：US20050211956A1

公开(公告)日：2005-09-29

申请号：US11062151

申请日：2005-02-18

申请人： Michiyuki Kono ,  Manabu Kikuta ,  Masaki Tezuka ,  Hiroshi Tanaka ,  Takao Yokohashi ,  Takao Nishihata ,  Kazuhiko Murata ,  Taketo Toba ,  Fumihide Tamura ,  Ritsuo Kitada

发明人： Michiyuki Kono ,  Manabu Kikuta ,  Masaki Tezuka ,  Hiroshi Tanaka ,  Takao Yokohashi ,  Takao Nishihata ,  Kazuhiko Murata ,  Taketo Toba ,  Fumihide Tamura ,  Ritsuo Kitada

IPC分类号： C08G65/02 ,  C08G65/30 ,  C08G65/34 ,  C08G65/46 ,  C11D17/00

CPC分类号： C08G65/30 ,  Y10T428/1348

摘要： To efficiently dry it, a nonionic alkylene oxide-type water-soluble resin is put into a container, then the container is degassed to a prescribed vacuum degree which is maintained while a dry gas having a dew point not higher than prescribed is introduced into the container at a rate not lower than prescribed. Minor volatiles are efficiently removed from the resin in an evaporation tank having a stirring blade. For protecting the dried resin from water, a dry gas is introduced into and air is purged from an empty packaging container whereafter the resin is charged into the container is sealed. By controlling solvent content and visocity of the resin and loading it into a temperature-controlled transportation container and/or unloading it out of the transportation container by the use of a pump, good subsquent processability of the resin and prevention of deterioration thereof are ensured.

摘要翻译： 为了有效地将其干燥，将非离子型环氧烷烃型水溶性树脂放入容器中，然后将容器脱气到规定的真空度，将具有不高于露点的干燥气体导入到 容器以不低于规定的速度。 在具有搅拌叶片的蒸发罐中有效地从树脂中除去少量挥发物。 为了将干燥的树脂从水中保护，将干燥的气体引入空气中并从空的包装容器中清除空气，然后将树脂装入容器中进行密封。 通过控制树脂的溶剂含量和粘度，并将其装载到温度控制的运输容器中和/或通过使用泵将其卸载出运输容器，确保树脂的良好的加工性和防止其变质。

公开(公告)号：US06765084B2

公开(公告)日：2004-07-20

申请号：US10335807

申请日：2003-01-02

申请人： Michiyuki Kono ,  Manabu Kikuta ,  Masahito Nishiura ,  Fumihide Tamura ,  Shigetaka Takamiya ,  Taketo Toba

发明人： Michiyuki Kono ,  Manabu Kikuta ,  Masahito Nishiura ,  Fumihide Tamura ,  Shigetaka Takamiya ,  Taketo Toba

IPC分类号： C08G600

CPC分类号： B01D3/06 ,  B01D1/225 ,  C08G65/30

摘要： The present invention provides a novel production process for an ethylene oxide resin, in which, when the ethylene oxide resin is obtained, it is arranged that the resin should contain no antistatic agent, and further its water content is also easily controlled in not more than a definite amount, and the thermal damage of the above resin is prevented, and besides, the reduction of the cost can also be actualized. The production process for an ethylene oxide resin, according to the present invention, comprises the step of carrying out devolatilization of a solvent from a polymerization reaction liquid containing the solvent, thereby obtaining the ethylene oxide resin; with the production process being characterized by arranging that: after the devolatilization, the resin should have a solvent concentration of 0.01 to 30 weight % and a water content of not more than 200 ppm, and the resin should contain no antistatic agent.

摘要翻译： 本发明提供一种新型的环氧乙烷树脂的制造方法，其中，当得到环氧乙烷树脂时，树脂不含抗静电剂，其含水量也容易控制在不超过 一定量，并且防止了上述树脂的热损伤，并且还可以实现成本的降低。 根据本发明的环氧乙烷树脂的制备方法包括从含有溶剂的聚合反应液中进行溶剂脱挥发分的步骤，得到环氧乙烷树脂; 其制造方法的特征在于：在脱挥发分后，树脂的溶剂浓度为0.01〜30重量％，水含量不大于200ppm，树脂不含抗静电剂。

公开(公告)号：US20060223995A1

公开(公告)日：2006-10-05

申请号：US11356799

申请日：2006-02-17

申请人： Hirofumi Uchimura ,  Manabu Kikuta

发明人： Hirofumi Uchimura ,  Manabu Kikuta

IPC分类号： C07F9/02 ,  C07D279/12 ,  C07D265/28 ,  C07D213/20 ,  C07D239/02

CPC分类号： C07D233/54 ,  B01J35/12 ,  H01G11/20 ,  H01G11/60 ,  H01G11/62

摘要： An ionic liquid with an extremely low content of an impurity such as halogen ions which can be obtained easily at a relatively reduced cost, the ionic liquid comprising a pair of a cation K+ and an anion A− represented by the general formula (1) in which the content of an alkali metal as an impurity is 5 ppm or less and the content of a halogen ion is 1 ppm or less, the cation being preferably selected from the group represented by the following general formula (2) obtained by quarternizing a tertiary amine compound or a tertiary phosphine compound by using an acid ester represented by the following general formula (3) and then conducting salt exchange: in which R1 to R4 in the formula (2) each independently represents a linear or branched alkyl group of 1 to 8 carbon atoms, X represents a hetero atom and R in the formula (3) represents a linear or branched alkyl group of 1 to 8 carbon atoms.

摘要翻译： 具有极低含量杂质如离子的离子液体，其可以以相对降低的成本容易地获得，离子液体包含一对阳离子K +和阴离子A SUP 作为杂质的碱金属的含量为5ppm以下，卤素离子的含量为1ppm以下的通式（1）表示的化合物，优选选自 通过使用由以下通式（3）表示的酸酯季铵化叔胺化合物或叔膦化合物，然后进行盐交换而获得的由以下通式（2）表示的基团：其中R 1， 式（2）中的R 4〜R 4各自独立地表示1〜8个碳原子的直链或支链烷基，X表示杂原子，式（3）中的R表示 具有1至8个碳原子的直链或支链烷基。

公开(公告)号：US20060020093A1

公开(公告)日：2006-01-26

申请号：US11184263

申请日：2005-07-18

申请人： Manabu Kikuta ,  Akiyoshi Hatakeyama

发明人： Manabu Kikuta ,  Akiyoshi Hatakeyama

IPC分类号： C08F12/28

CPC分类号： H01M10/0565 ,  H01B1/122 ,  H01G11/56 ,  H01M6/181 ,  H01M8/103 ,  H01M8/1072 ,  H01M10/052 ,  H01M2300/0085 ,  Y02E60/13 ,  Y02P70/56

摘要： A precursor composition capable to form a solid-state electrolyte having good ion conductivity and high heat-resistance, by simple curing procedure, comprising; (A) a polymerizable ion pair compound represented by formula I, (B) a cross-linker having two or more unsaturated groups co-polymerizable with the polymerizable ion pair compound (A), and (C) non-polymerizable ion pair compound. Each of R1, R2, R3, R4, R5 and R6 represents hydrogen atom, alkyl or aryl group having 1-12 carbon atoms; and each of R7 and R8 represents alkyl or aryl group having 1-12 carbon atoms. X designates either of halogen atom, AlCl4−, PF6−, BF4−, bis (oxalato) borate anion, Rf1SO3−, (NC)2N−, (Rf2Y)2N−, (Rf2Y)3C−, and (Rf2Y)2C−Q, where Rf1 designates perfluoro alkyl or aryl group having 1-8 carbon atoms; each Rf2 designates fluorine atom, perfluoro alkyl or aryl group having 1-8 carbon atoms; Y designates —SO2—or —PO—Rf2; and Q designates —H or —CO—Rf2.

摘要翻译： 通过简单的固化方法能够形成具有良好离子传导性和高耐热性的固态电解质的前体组合物，其包含： （A）由式I表示的可聚合离子对化合物，（B）具有两个或多个与可聚合离子对化合物（A）可共聚的不饱和基团的交联剂，和（C）不可聚合离子对化合物。 R1，R2，R3，R4，R5和R6各自表示氢原子，具有1-12个碳原子的烷基或芳基; 并且R 7和R 8各自表示具有1-12个碳原子的烷基或芳基。 X表示卤素原子，AlCl 4，SO 4，SO 4，SO 4， 双（草酸）硼酸盐阴离子，R 1，SO 3，SO 3， - （NC） （R＆lt; 2＆gt; 2）＆lt; / SUP＆gt;，（R＆lt; SUB＆gt; （R 2，Y 2）2 C 2 O 3，其中R 1，R 2， Q，其中R f1表示具有1-8个碳原子的全氟烷基或芳基; 每个R f2表示氟原子，具有1-8个碳原子的全氟烷基或芳基; Y表示-SO 2 - 或-PO-R 1/2; 并且Q表示-H或-CO-R <！ - SIPO <

公开(公告)号：US5332780A

公开(公告)日：1994-07-26

申请号：US44591

申请日：1993-04-08

申请人： Naoki Kitazawa ,  Manabu Kikuta ,  Hiroshi Hotta ,  Yutaka Nakayama ,  Hideyuki Sumi

发明人： Naoki Kitazawa ,  Manabu Kikuta ,  Hiroshi Hotta ,  Yutaka Nakayama ,  Hideyuki Sumi

IPC分类号： C08L67/02 ,  C08L69/00 ,  C08L77/00 ,  C08L101/02 ,  C08L33/24

CPC分类号： C08L69/00 ,  C08L101/02 ,  C08L67/02 ,  C08L77/00 ,  C08L2205/08

摘要： Thermoplastic resin compositions having the following component A-1 or A-2, component B and component C:(A-1): a polymer component having a functional group capable of reacting with an amino group, or(A-2): a composition of component (A-1) and a resin that is non-reactive with an amino group and is different from the resin used in the following component B(B) a thermoplastic resin component that is non-reactive with an amino group under the conditions required to mold the entire resin composition; and(C) a graft copolymer obtained by a graft reaction of a thermoplastic polymer, with a compound (I), or a copolymer having the repeating unit (II) and the repeating unit of an ethylenic unsaturated monomer, ##STR1## wherein R.sup.1 -R.sup.4, the same or different represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group.

摘要翻译： 具有以下组分A-1或A-2，组分B和组分C的热塑性树脂组合物：（A-1）：具有能够与氨基反应的官能团的聚合物组分，或（A-2）： 组分（A-1）的组成和与氨基不反应并且与以下组分B（B）中使用的树脂不同的树脂，与下述氨基不具有反应性的热塑性树脂组分 模制整个树脂组合物所需的条件; （C）通过热塑性聚合物与化合物（I）或具有重复单元（II）的共聚物和烯属不饱和单体的重复单元的接枝反应获得的接枝共聚物， （II）其中R 1 -R 4相同或不同表示氢原子，烷基，环烷基，芳基或芳烷基。

公开(公告)号：US07605271B2

公开(公告)日：2009-10-20

申请号：US11356799

申请日：2006-02-17

申请人： Hirofumi Uchimura ,  Manabu Kikuta

发明人： Hirofumi Uchimura ,  Manabu Kikuta

IPC分类号： C07D233/02

CPC分类号： C07D233/54 ,  B01J35/12 ,  H01G11/20 ,  H01G11/60 ,  H01G11/62

摘要： Provided is an ionic liquid, represented by the formula K+A−, having a very low content of impurities, especially a low content of halogen ions and/or a low content of alkali metal, wherein K+is a quaternary ammonium ion, for example an imidazolium ion. Also provided is a quaternarization process for making the ionic liquid in reacted with an acid ester such as a sulfate or phosphate.

摘要翻译： 提供一种离子液体，其由式K + A-表示，具有非常低的杂质含量，特别是低含量的卤素离子和/或低含量的碱金属，其中K +是季铵离子，用于 例如咪唑鎓离子。 还提供了使离子液体与酸酯如硫酸盐或磷酸盐反应的季铵化方法。

公开(公告)号：US07279540B2

公开(公告)日：2007-10-09

申请号：US11184263

申请日：2005-07-18

申请人： Manabu Kikuta ,  Akiyoshi Hatakeyama

发明人： Manabu Kikuta ,  Akiyoshi Hatakeyama

IPC分类号： C08F12/28

CPC分类号： H01M10/0565 ,  H01B1/122 ,  H01G11/56 ,  H01M6/181 ,  H01M8/103 ,  H01M8/1072 ,  H01M10/052 ,  H01M2300/0085 ,  Y02E60/13 ,  Y02P70/56

摘要： A precursor composition capable to form a solid-state electrolyte having good ion conductivity and high heat-resistance, by simple curing procedure, comprising; (A) a polymerizable ion pair compound represented by formula I, (B) a cross-linker having two or more unsaturated groups co-polymerizable with the polymerizable ion pair compound (A), and (C) non-polymerizable ion pair compound. Each of R1, R2, R3, R4, R5 and R6 represents hydrogen atom, alkyl or aryl group having 1-12 carbon atoms; and each of R7 and R8 represents alkyl or aryl group having 1-12 carbon atoms. X designates either of halogen atom, AlCl4−, PF6−, BF4−, bis (oxalato) borate anion, Rf1SO3−, (NC)2N−, (Rf2Y)2N−, (Rf2Y)3C−, and (Rf2Y) 2C−Q, where Rf1 designates perfluoro alkyl or aryl group having 1-8 carbon atoms; each Rf2 designates fluorine atom, perfluoro alkyl or aryl group having 1-8 carbon atoms; Y designates —SO2—or —PO—Rf2; and Q designates —H or —CO—Rf2

摘要翻译： 通过简单的固化方法能够形成具有良好离子传导性和高耐热性的固态电解质的前体组合物，其包含： （A）由式I表示的可聚合离子对化合物，（B）具有两个或多个与可聚合离子对化合物（A）可共聚的不饱和基团的交联剂，和（C）不可聚合离子对化合物。 R1，R2，R3，R4，R5和R6各自表示氢原子，具有1-12个碳原子的烷基或芳基; 并且R 7和R 8各自表示具有1-12个碳原子的烷基或芳基。 X表示卤素原子，AlCl 4，SO 4，SO 4，SO 4， 双（草酸）硼酸盐阴离子，R 1，SO 3，SO 3， - （NC） （R＆lt; 2＆gt; 2）＆lt; / SUP＆gt;，（R＆lt; SUB＆gt; （R 2，Y 2）2 C 2 O 3，其中R 1，R 2， Q，其中R f1表示具有1-8个碳原子的全氟烷基或芳基; 每个R f2表示氟原子，具有1-8个碳原子的全氟烷基或芳基; Y表示-SO 2 - 或-PO-R 1/2; 并且Q表示-H或-CO-R <！ - SIPO <

公开(公告)号：US5420210A

公开(公告)日：1995-05-30

申请号：US921343

申请日：1992-07-29

申请人： Naoki Kitazawa ,  Hiroshi Hotta ,  Hideyuki Sumi ,  Manabu Kikuta

发明人： Naoki Kitazawa ,  Hiroshi Hotta ,  Hideyuki Sumi ,  Manabu Kikuta

IPC分类号： C08F8/32 ,  C08F214/00 ,  C08F216/36 ,  C08F220/54 ,  C08F222/40

CPC分类号： C08F8/32 ,  C08F2800/10

摘要： A novel formamide group-containing copolymer, or a salt thereof, which can be used as a high-molecular weight amino reagent, a starting material for functional high-molecular weight compounds, a starting material for adhesives, a polymer compatibilizer, a resin modifier, etc., and can undergo hydrolysis to give a copolymer containing a primary amino group, and a novel copolymer containing a primary amino group obtained by hydrolysis.

摘要翻译： 可用作高分子量氨基试剂的新型含甲酰胺基团的共聚物或其盐，功能性高分子化合物的起始原料，粘合剂原料，聚合物相容剂，树脂改性剂 等，并且可以进行水解，得到含有伯氨基的共聚物，以及含有通过水解获得的伯氨基的新型共聚物。

公开(公告)号：US5202193A

公开(公告)日：1993-04-13

申请号：US797868

申请日：1991-11-26

申请人： Hideyuki Sumi ,  Hiroshi Hotta ,  Manabu Kikuta ,  Nario Uejyukkoku ,  Masashi Takeda ,  Osamu Wada ,  Tomomi Ueda ,  Toshiaki Doyama ,  Shoichi Wakatake ,  Kanji Tanaka

发明人： Hideyuki Sumi ,  Hiroshi Hotta ,  Manabu Kikuta ,  Nario Uejyukkoku ,  Masashi Takeda ,  Osamu Wada ,  Tomomi Ueda ,  Toshiaki Doyama ,  Shoichi Wakatake ,  Kanji Tanaka

IPC分类号： C08F8/44 ,  C08F210/02

CPC分类号： C08F210/02 ,  C08F8/44 ,  Y10T428/249953 ,  Y10T428/249981 ,  Y10T428/31725 ,  Y10T428/31783

摘要： A linear random N-substituted acrylamide copolymer comprising 65 to 99% by mole of ethylene units, 1 to 15% by mole of acrylate units and 1 to 35% by mole of acrylamide units, the copolymer having a weight average molecular weight of 1000 to 50000, and an aqueous composition, a resin film, a laminate, recording paper and a foamed article comprising the N-substituted acrylamide copolymer, respectively. The N-substituted acrylamide copolymer is excellent in antistatic ability for thermoplastic resins and does not lower physical properties such as transparency and elongation of films and articles which are formed from a thermoplastic resin. Moreover, the N-substituted acrylamide copolymer is excellent in anti-blocking ability so that the copolymer can be suitably used for various uses.