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11.发明授权公开(公告)号：US06249369B1
公开(公告)日：2001-06-19
申请号：US09350879
申请日：1999-07-09
IPC分类号： G02F115
CPC分类号： C09K9/02 , G02F1/1521 , G02F2001/1502 , G02F2001/1512
摘要： Coupling of anodic electrochromic compounds by a covalent bond or a bridge link which provides for electronic communication between the coupled electrochromic compounds results in coupled electrochromic compounds which exhibit greater stability as well as electrochromic activity that differs from the monomeric electrochromic compounds. Extension of the absorption spectrum into the near-infrared region of the spectrum is frequently observed. The coupled electrochromic compounds are highly suitable for use in electrochromic media used to produce electrochromic devices.
摘要翻译： 阳离子电致变色化合物通过共价键或桥连接偶联，其提供了耦合的电致变色化合物之间的电子连通，导致结合的电致变色化合物表现出更大的稳定性以及不同于单体电致变色化合物的电致变色活性。 经常观察到吸收光谱扩展到光谱的近红外区域。 偶联的电致变色化合物非常适用于用于制备电致变色装置的电致变色介质。
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公开(公告)号：US07031043B2
公开(公告)日：2006-04-18
申请号：US10753049
申请日：2004-01-07
IPC分类号： G02F1/15
CPC分类号： C09K9/00 , G02F1/1521 , G02F2001/1512
摘要： An electrochromic device comprising: a first substantially transparent substrate having an electrically conductive material associated therewith; a second substrate having an electrically conductive material associated therewith; and an electrochromic medium contained within a chamber positioned between the first and second substrates which comprises: at least one solvent; an anodic material; a cathodic material, wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic, and wherein at least one of the anodic and cathodic materials is slow-diffusing; and an electron shuttle, wherein the electron shuttle serves to decrease switching time of the electrochromic device relative to the same without the electron shuttle.
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13.发明授权Controlled diffusion coefficient electrochromic materials for use in electrochromic mediums and associated electrochromic devices 有权用于电致变色介质和相关电致变色器件的受控扩散系数电致变色材料公开(公告)号：US06710906B2
公开(公告)日：2004-03-23
申请号：US10054108
申请日：2001-11-13
申请人： Thomas F. Guarr , Kathy E. Roberts , Rongguang Lin , Kelvin L. Baumann , David A. Theiste , Punam Giri , Elizabeth M. Sanford
发明人： Thomas F. Guarr , Kathy E. Roberts , Rongguang Lin , Kelvin L. Baumann , David A. Theiste , Punam Giri , Elizabeth M. Sanford
IPC分类号： G02F115
CPC分类号： C09K9/00 , C09K9/02 , C09K2211/1007 , C09K2211/1029 , G02F1/1521 , G02F2001/1512
摘要： An electrochromic medium for use in an electrochromic device comprising: at least one solvent; an anodic electroactive material; a cathodic electroactive material; wherein at least one of the anodic and cathodic electroactive materials is electrochromic; and wherein at least one of the anodic and cathodic electroactive materials is associated with a diffusion coefficient controlling moiety which serves to lower the diffusion coefficient of the associated material relative to the same without the diffusion coefficient controlling moiety.
摘要翻译： 一种用于电致变色装置的电致变色介质，包括：至少一种溶剂; 阳极电活性材料; 阴极电活性材料; 其中所述阳极和阴极电活性材料中的至少一种是电致变色的; 并且其中所述阳极和阴极电活性材料中的至少一种与扩散系数控制部分相关联，所述扩散系数控制部分用于降低相关材料相对于相同材料的扩散系数而不具有扩散系数控制部分。
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14.发明授权公开(公告)号：US06362914B1
公开(公告)日：2002-03-26
申请号：US09794512
申请日：2001-02-27
IPC分类号： G02F115
摘要： Electrochromic devices and materials having enhanced daylight stability are described. The materials have a redox center linked to an energy receptor site that may serve to dissipate excited state energy from the redox center, alternatively the receptor site may absorb harmful radiation prior to the absorption by the redox center.
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公开(公告)号：US6037471A
公开(公告)日：2000-03-14
申请号：US140310
申请日：1998-08-26
申请人： Ramanujan Srinivasa , Darla J. French , Rongguang Lin , Thomas F. Guarr , Harlan J. Byker , Kelvin L. Baumann , David A. Theiste
发明人： Ramanujan Srinivasa , Darla J. French , Rongguang Lin , Thomas F. Guarr , Harlan J. Byker , Kelvin L. Baumann , David A. Theiste
IPC分类号： C07D213/22 , C07D241/36 , C07D241/46 , C09K9/02 , G02F1/15
CPC分类号： C07D213/22 , C07D241/36 , C07D241/46 , C09K9/02 , G02F1/1521
摘要： An improved electrochromic device, the device incorporating an electrochromic medium that comprises at least three electroactive materials having absorption spectra that add together such that the color of the electrochromic medium can be pre-selected by individually choosing the concentrations of the at least three electroactive materials. The electrochromic medium generally maintains the pre-selected perceived color throughout its normal range of voltages when used in an electrochromic device. The at least three electroactive materials include at least one electrochemically reducible material (cathodic material), at least one electrochemically oxidizable material (anodic material) and at least one additional electroactive material which may be either an anodic or cathodic material. Thus, there are always three electroactive materials present in the medium, with at least two either being anodic or cathodic materials. The pre-selected color may be chosen from a wide variety of colors and may be, for example, red, orange, yellow, green, blue, purple. For electrochromic mirrors for motor vehicles, a presently preferred color is gray.
摘要翻译： 一种改进的电致变色装置，该装置包含电致变色介质，其包含至少三种具有吸收光谱的电活性材料，所述电活性材料相加在一起，使得电致变色介质的颜色可以通过单独选择至少三种电活性材料的浓度来预先选择。 当电致变色装置中使用时，电致变色介质通常保持其预定的感知颜色在其正常的电压范围内。 至少三种电活性材料包括至少一种电化学可还原材料（阴极材料），至少一种电化学可氧化材料（阳极材料）和至少一种额外的电活性材料，其可以是阳极或阴极材料。 因此，介质中总是存在三种电活性材料，至少有两种是阳极或阴极材料。 预选颜色可以从各种颜色中选择，并且可以是例如红，橙，黄，绿，蓝，紫。 对于用于机动车辆的电致变色镜，目前优选的颜色是灰色。
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公开(公告)号：US6020987A
公开(公告)日：2000-02-01
申请号：US832596
申请日：1997-04-02
申请人： Kelvin L. Baumann , Harlan J. Byker , Thomas F. Guarr , Kathy E. Siegrist , David A. Theiste , Derick D. Winkle
发明人： Kelvin L. Baumann , Harlan J. Byker , Thomas F. Guarr , Kathy E. Siegrist , David A. Theiste , Derick D. Winkle
CPC分类号： G02F1/1521 , B32B17/10036 , B32B17/10174 , B32B17/10302 , B32B17/10513 , C09K9/02 , G02F1/15 , G02F1/1523 , G02F2001/1512
摘要： An improved electrochromic device, the device incorporating an electrochromic medium that comprises at least three electroactive materials having absorption spectra that add together such that the color of the electrochromic medium can be pre-selected by individually choosing the concentrations of the at least three electroactive materials. The electrochromic medium generally maintains the pre-selected perceived color throughout its normal range of voltages when used in an electrochromic device. The at least three electroactive materials include at least one electrochemically reducible material (cathodic material), at least one electrochemically oxidizable material (anodic material) and at least one additional electroactive material which may be either an anodic or cathodic material. Thus, there are always three electroactive materials present in the medium, with at least two either being anodic or cathodic materials. The pre-selected color may be chosen from a wide variety of colors and may be, for example, red, orange, yellow, green, blue, purple. For electrochromic mirrors for motor vehicles, a presently preferred color is gray.
摘要翻译： 一种改进的电致变色装置，该装置包含电致变色介质，其包含至少三种具有吸收光谱的电活性材料，所述电活性材料相加在一起，使得电致变色介质的颜色可以通过单独选择至少三种电活性材料的浓度来预先选择。 当电致变色装置中使用时，电致变色介质通常保持其预定的感知颜色在其正常的电压范围内。 至少三种电活性材料包括至少一种电化学可还原材料（阴极材料），至少一种电化学可氧化材料（阳极材料）和至少一种额外的电活性材料，其可以是阳极或阴极材料。 因此，介质中总是存在三种电活性材料，至少有两种是阳极或阴极材料。 预选颜色可以从各种颜色中选择，并且可以是例如红，橙，黄，绿，蓝，紫。 对于用于机动车辆的电致变色镜，目前优选的颜色是灰色。
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17.发明授权公开(公告)号：US06445486B1
公开(公告)日：2002-09-03
申请号：US09724118
申请日：2000-11-28
IPC分类号： G02F115
CPC分类号： C09K9/00 , G02F1/1521 , G02F2001/1512
摘要： An electrochromic medium for use in an electrochromic device comprising: at least one solvent; a cathodic electroactive material; an anodic electroactive material; an optional beneficial agent; wherein at least one of the cathodic and anodic electroactive materials is electrochromic; and wherein at least one of the cathodic electroactive material, anodic electroactive material, and/or optional beneficial agent is associated with a solubilizing moiety which serves to increase solubility of the associated material or agent relative to the same without the solubilizing moiety.
摘要翻译： 一种用于电致变色装置的电致变色介质，包括：至少一种溶剂; 阴极电活性材料; 阳极电活性材料; 一种可选的有益药剂; 其中阴极和阳极电活性材料中的至少一种是电致变色的; 并且其中所述阴极电活性材料，阳极电活性材料和/或任选的有益试剂中的至少一种与增溶部分相关联，所述增溶部分用于增加相关材料或试剂相对于没有增溶部分的溶解度。
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公开(公告)号：US07428091B2
公开(公告)日：2008-09-23
申请号：US11272552
申请日：2005-11-10
IPC分类号： G02F1/15
CPC分类号： C09K9/02 , C09K2211/1007 , C09K2211/1044 , G02F1/1521 , G02F2001/1512
摘要： An electrochromic device having an electrochromic medium comprising: a material represented by the following formula: wherein X comprises N—R10, O, or S; wherein R1-R10 are defined herein with the proviso that at least one of R5 and R10 comprises an alkyl, cycloalkyl, polycycloalkyl, heterocycloalkyl, aryl, alkaryl, aralkyl, alkoxy, alkenyl, and/or alkynyl group containing 4 to approximately 50 carbon atoms, wherein at least one of the carbon atoms may be a linking group to, or part of, a halogen, a N, O, and/or S containing moiety, and/or one or more functional groups comprising alcohols, esters, ammonium salts, phosphonium salts, and combinations thereof, and wherein at least one of R5 and R10 is void of any β hydrogen atoms.
摘要翻译： 一种具有电致变色介质的电致变色装置，包括：由下式表示的材料：其中X包括N-R 10，O或S; 其中R 1 -R 10在本文中定义，条件是R 5和R 10中的至少一个是 包括含有4至约50个碳原子的烷基，环烷基，多环烷基，杂环烷基，芳基，烷芳基，芳烷基，烷氧基，烯基和/或炔基，其中至少一个碳原子可以是连接基团或部分 的卤素，含有N，O和/或S的部分，和/或一种或多种包含醇，酯，铵盐，鏻盐及其组合的官能团，并且其中R 1， 5个和R 10个不含任何β氢原子。
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公开(公告)号：US06614578B2
公开(公告)日：2003-09-02
申请号：US10211485
申请日：2002-08-02
IPC分类号： G02F115
CPC分类号： C09K9/00 , G02F1/15 , G02F1/1521 , G02F2001/1512
摘要： The present invention is directed to an electrochromic medium for use in an electrochromic device comprising at least one solvent, an anodic material, a cathodic material, wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic, and an ultraviolet stabilizing material, wherein the ultraviolet stabilizing material includes a solublizing moiety which serves to increase solubility of the ultraviolet stabilizing material relative to the same without the solublizing moiety.
摘要翻译： 本发明涉及一种用于电致变色装置的电致变色介质，其包括至少一种溶剂，阳极材料，阴极材料，其中阳极和阴极材料都是电活性的，并且阳极和阴极材料中的至少一种是 电致变色和紫外线稳定材料，其中紫外线稳定材料包括溶解部分，其用于增加紫外线稳定材料在没有溶解部分的情况下相对于紫外线稳定材料的溶解度。
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公开(公告)号：US06433914B1
公开(公告)日：2002-08-13
申请号：US09650870
申请日：2000-08-30
IPC分类号： G02F115
CPC分类号： G02F1/1525 , C09K9/02 , G02F1/15 , G02F1/1521 , G02F2001/1502 , G02F2001/1512
摘要： An electrochromic device comprising: (a) at least one substantially transparent substrate having an electrically conductive material associated therewith; and (b) an electrochromic medium having a predetermined color while in a high transmission state, wherein the electrochromic medium comprises: (1) an anodic material and a cathodic material, wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic; (2) a redox buffer; and (3) means associated with the redox buffer for controllably maintaining the predetermined color of the electrochromic medium while in the high transmission state relative to an electrochromic medium without the redox buffer.
摘要翻译： 一种电致变色装置，包括：（a）至少一个基本上透明的基底，其具有与之相关联的导电材料; 和（b）在高透射状态下具有预定颜色的电致变色介质，其中所述电致变色介质包括：（1）阳极材料和阴极材料，其中阳极和阴极材料都是电活性的，并且至少一种 阳极和阴极材料是电致变色的; （2）氧化还原缓冲液; 和（3）与氧化还原缓冲液相关联的装置，用于相对于没有氧化还原缓冲液的电致变色介质，在高透射状态下可控地保持电致变色介质的预定颜色。
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