摘要:
A cell structure includes a cathode, an anode, and a protonically conductive solid electrolyte layer between the cathode and the anode. The solid electrolyte layer contains a compound having a perovskite structure and containing zirconium, cerium, and a rare-earth element other than cerium. If the solid electrolyte layer has a thickness of T, the elemental ratio of zirconium to cerium at a position 0.25 T from a surface of the solid electrolyte layer opposite the cathode, ZrC/CeC, and the elemental ratio of zirconium to cerium at a position 0.25 T from a surface of the solid electrolyte layer opposite the anode, ZrA/CeA, satisfy ZrC/CeC>ZrA/CeA, and ZrC/CeC>1.
摘要:
Provided is an electrode catalyst material that has an increased reduction rate of a nickel catalyst and thus an improved catalytic function in a fuel cell. The electrode catalyst material for fuel cells contains nickel oxide and cobalt oxide. The electrode catalyst material contains a cobalt metal component in an amount of 2 to 15 mass % with respect to the total mass of a nickel metal component and the cobalt metal component.
摘要:
A electrochemical cell device includes: a cell having a first main surface and a second main surface opposite to the first main surface; a first current collector having a third main surface facing the first main surface; and a second current collector having a fourth main surface facing the second main surface. The cell is warped to protrude from the second main surface toward the first main surface. The third main surface is provided with a recess at a position facing a central portion of the first main surface. The fourth main surface includes a protrusion at a position facing a central portion of the second main surface. Each of the first current collector and the second current collector is constituted of one or more metal porous body sheets each composed of a metal porous body having a framework with a three-dimensional network structure.
摘要:
A porous body includes a framework having a three-dimensional network structure, the framework having a body including crystal grains including nickel and cobalt as constituent elements, the cobalt having a proportion in mass of 0.2 or more and 0.8 or less with respect to a total mass of the nickel and the cobalt, the crystal grains having a shorter grain diameter of 2 μm or more, as determined in a first observed image obtained by observing the body of the framework in cross section at a magnification of 200 times.
摘要:
A fuel cell includes a MEA that includes a cathode, an anode, and a solid electrolyte layer disposed between the cathode and the anode, the solid electrolyte layer containing an ion-conducting solid oxide; at least one first porous metal body arranged to oppose at least one of the cathode and the anode; and an interconnector arranged to oppose the first porous metal body and having a gas supply port and a gas discharge port formed therein. The first porous metal body includes a porous metal body S that opposes the gas supply port and has a three-dimensional mesh-like skeleton, and a porous metal body H that has a three-dimensional mesh-like skeleton and is other than the porous metal body S. A porosity Ps of the porous metal body S and a porosity Ph of the porous metal body H satisfy a relationship: Ps
摘要:
Provided is a porous current collector which is used for a fuel electrode and has a high gas reforming function and high durability. A porous current collector 9 is provided adjacent to a fuel electrode 4 of a fuel cell 101 that includes a solid electrolyte layer 2, the fuel electrode 4 disposed on one side of the solid electrolyte layer, and an air electrode 3 disposed on the other side. The porous current collector includes a porous metal body 1 and a first catalyst 20. The porous metal body has an alloy layer 12a at least on a surface thereof, the alloy layer containing nickel (Ni) and tin (Sn). The first catalyst, which is in the form of particles, is supported on a surface of the alloy layer, the surface facing pores of the porous metal body, and is capable of processing a carbon component contained in a fuel gas that flows inside the pores.
摘要:
The present invention inexpensively provides an electrode material for a fuel electrode, the electrode material having CO2 resistance and being capable of forming a fuel cell having high electricity generation performance. An electrode material for a fuel electrode, the electrode material constituting a fuel electrode of a fuel cell including a proton-conductive solid electrolyte layer, includes a perovskite-type solid electrolyte component and a nickel (Ni) catalyst component, in which the solid electrolyte component includes a barium component, a zirconium component, a cerium component, and a yttrium component, and the mixture ratio of the zirconium component to the cerium component in the solid electrolyte component is set to be 1:7 to 7:1 in terms of molar ratio.
摘要:
There is provided a composite material for a fuel cell, in which in the case where an electrolyte-anode laminate is co-fired, the composite material is capable of inhibiting a decrease in the ion conduction performance of a solid electrolyte layer to enhance the power generation performance of the fuel cell. A composite material 1 for a fuel cell includes a solid electrolyte layer 3 and an anode layer 2 stacked on the solid electrolyte layer, in which the solid electrolyte layer is composed of an ionic conductor in which the A-site of a perovskite structure is occupied by at least one of barium (Ba) and strontium (Sr) and tetravalent cations in the B-sites are partially replaced with a trivalent rare-earth element, the anode layer contains an electrolyte component having the same composition as the solid electrolyte layer, a nickel (Ni) catalyst, and an additive containing a rare-earth element, the additive being located at least at an interfacial portion with the solid electrolyte layer.
摘要:
A proton-conductive cell structure includes an air electrode, a hydrogen electrode, and a solid electrolyte layer disposed between the air electrode and the hydrogen electrode, wherein the solid electrolyte layer includes at least a first solid electrolyte layer formed of a compact material. The first solid electrolyte layer includes a metal oxide having a perovskite structure and represented by Formula 1 below, a ratio of Sr to a total amount of Ba and Sr in an air-electrode-side near-surface region of the first solid electrolyte layer is 0.4 or more, and a ratio of Sr to a total amount of Ba and Sr in a hydrogen-electrode-side near-surface region of the first solid electrolyte layer is 0.003 to 0.3.
摘要:
A metal porous body has a skeleton of a three-dimensional network structure, an outer layer portion of the skeleton having a second pore smaller in size than a first pore formed by the skeleton, wherein the outer layer portion is a metal layer, and a water vapor reforming catalyst is supported in the outer layer portion.