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11.发明申请Ethylene/dicyclopentadiene/norbornene terpolymer materials having desirable structural and thermal properties 审中-公开乙烯/二环戊二烯/降冰片烯三元共聚物材料具有理想的结构和热性能公开(公告)号：US20080221275A1
公开(公告)日：2008-09-11
申请号：US12074213
申请日：2008-02-29
申请人： Lisa S. Baugh , Enock Berluche , Abhimanyu O. Patil , Beverly J. Poole , Kevin D. Robinson , Kevin R. Squire
发明人： Lisa S. Baugh , Enock Berluche , Abhimanyu O. Patil , Beverly J. Poole , Kevin D. Robinson , Kevin R. Squire
CPC分类号： C08C19/06 , C08F8/04 , C08F8/08 , C08F210/02
摘要： Provided are selected types of terpolymer components comprising terpolymers having monomer units derived from ethylene (E), dicyclopentadiene (DCPD) and norbornene-based (NB) co-monomers. Such terpolymer components have certain specified amounts of each co-monomer as well as certain specified molecular weight and glass transition temperature characteristics. Terpolymer components which are derivatized by hydrogenation and/or by epoxidation and/or hydroxylation are also disclosed, as well as thermoplastic polyolefin compositions which contain the terpolymer components and which have especially desirable structural and thermal properties.Also provided are processes for preparing and derivatizing the terpolymer components herein. Such preparation processes comprise: a) contacting ethylene with a polymerization mixture comprising selected amounts of both DCPD and NB co-monomers, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst under specific polymerization conditions to thereby form the desired ethylene-dicyclopentadiene-norbornene terpolymer components within the polymerization mixture. These terpolymer components can then be subsequently derivatized by hydrogenation or functionalization of the residual double bonds therein.
摘要翻译： 提供了包含来自乙烯（E），二环戊二烯（DCPD）和降冰片烯基（NB））共聚单体的单体单元的三元共聚物的选择类型的三元共聚物组分。 这些三元共聚物组分具有特定量的每种共聚单体以及某些特定的分子量和玻璃化转变温度特性。 还公开了通过氢化和/或通过环氧化和/或羟基化衍生化的三元共聚物组分，以及含有三元共聚物组分并且具有特别期望的结构和热性质的热塑性聚烯烃组合物。 还提供了用于制备和衍生本文中三元共聚物组分的方法。 这样的制备方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在特定的聚合条件下，使乙烯与包含选定量的DCPD和NB共聚单体的聚合混合物接触，从而形成所需的乙烯 - 二环戊二烯 - 降冰片烯三元共聚物组分在聚合混合物内。 然后可以通过氢化或官能化其中的残余双键将这些三元共聚物组分衍生化。
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公开(公告)号：US07297805B2
公开(公告)日：2007-11-20
申请号：US11152802
申请日：2005-06-14
CPC分类号： C07F11/005 , B01J31/143 , B01J31/183 , C08F110/02 , C08F4/69034
摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.
摘要翻译： 具有式I的组合物，其中R 1和R 2独立地是氢，C 1至C 12直链 和支链烷基，C 3至C 12环烷基，芳基，C 1至C 12烷氧基，F， Cl，SO 3，C 1至C 12全氟烷基和N（CH 3 3）2 R 3，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 1〜 C 1 -C 4 - （CH 3） - ，其中C（R 4） - ， x（CH 2）2 - ， - （CH 2 CH 2）x NH 2（CH 2） ）其中R 4是烃基，卤代烃基，卤代烃基， 或1至12个碳原子的烷氧基，x是1至12的整数，Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，可用于聚合烯烃单体。
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公开(公告)号：US09028785B2
公开(公告)日：2015-05-12
申请号：US13228999
申请日：2011-09-09
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A CO2 amine scrubbing process uses an absorbent mixture combination of an amine containing a primary amino group CO2 sorbent in combination with a non-nucleophilic relatively stronger base. The weaker base(s) are nucleophilic and have the ability to react directly with the CO2 in the gas stream while the relatively stronger bases act as non-nucleophilic promoters for the reaction between the CO2 and the weaker base. Two moles of CO2 can be taken up by the primary amine groups in a dicarboxylation reaction, affording the potential for a highly efficient scrubbing process.
摘要翻译： CO 2胺洗涤方法使用含有伯氨基CO 2吸附剂的胺与非亲核相对较强的碱的组合的吸收混合物组合。 较弱的碱是亲核的，并且具有与气流中的CO 2直接反应的能力，而相对较强的碱作为CO 2和较弱碱之间的反应的非亲核促进剂。 在二羧酸化反应中，二元醇可以被伯胺基团吸收，提供高效洗涤过程的潜力。
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公开(公告)号：US20120063980A1
公开(公告)日：2012-03-15
申请号：US13229174
申请日：2011-09-09
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A CO2 amine scrubbing process uses an absorbent mixture consisting of an alkanolamine CO2 sorbent in combination with a non-nucleophilic base. The alkanolamine has oxygen and nitrogen sites capable of nucleophilic attack at the CO2 carbon atom. The nucleophilic addition is promoted in the presence of the non-nucleophilic, relatively stronger base, acting as a proton acceptor. The non-nucleophilic base promoter, which may also act as a solvent for the alkanolamine, can promote reaction with the CO2 at each of the reactive hydroxyl and nucleophilic amine group(s) of the alkanolamines. In the case of primary amino alkanolamines the CO2 may be taken up by a double carboxylation reaction in which two moles of CO2 are taken up by the reacting primary amine groups.
摘要翻译： CO 2胺洗涤方法使用由链烷醇胺CO 2吸附剂与非亲核基团组合组成的吸收混合物。 链烷醇胺具有能够在CO 2碳原子上亲核攻击的氧和氮位点。 在非亲核相对较强的碱存在下促进亲核加成，作为质子受体。 还可以作为烷醇胺溶剂的非亲核碱基启动子可以促进与链烷醇胺的各反应性羟基和亲核胺基团中的CO 2的反应。 在伯氨基链烷醇胺的情况下，CO 2可以被双羧化反应吸收，其中两摩尔CO 2被伯胺基团反应。
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15.发明申请Mixed Amine and Non-Nucleophilic Base CO2 Scrubbing Process for Improved Adsorption at Increased Temperatures 有权用于提高温度下改善吸附的混合胺和非亲核碱性CO2洗涤方法公开(公告)号：US20120060686A1
公开(公告)日：2012-03-15
申请号：US13228869
申请日：2011-09-09
申请人： Pavel Kortunov , Lisa S. Baugh , David C. Calabro , Michael Siskin , Preeti Kamakoti , Quanchang Li
发明人： Pavel Kortunov , Lisa S. Baugh , David C. Calabro , Michael Siskin , Preeti Kamakoti , Quanchang Li
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A CO2 amine scrubbing process uses an absorbent mixture combination of an amine CO2 sorbent in combination with a non-nucleophilic, relatively stronger, typically nitrogenous, base. The weaker base(s) are nucleophilic and have the ability to react directly with the CO2 in the gas stream while the relatively stronger bases act as non-nucleophilic promoters for the reaction between the CO2 and the weaker base. The sorption and desorption temperatures can be varied by selection of the amine/base combination, permitting effective sorption temperatures of 70 to 90° C., favorable to scrubbing flue gas.
摘要翻译： CO 2胺洗涤方法使用胺二氧化碳吸附剂与非亲核相对较强的通常含氮碱的组合的吸收混合物组合。 较弱的碱是亲核的，并且具有与气流中的CO 2直接反应的能力，而相对较强的碱作为CO 2和较弱碱之间的反应的非亲核促进剂。 吸附和解吸温度可以通过选择胺/碱组合来改变，允许有效吸附温度为70-90℃，有利于洗涤烟道气。
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16.发明授权公开(公告)号：US09186618B2
公开(公告)日：2015-11-17
申请号：US13228734
申请日：2011-09-09
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： Ionic liquids are capable of acting as solvents for amine CO2 absorbent compounds in CO2 separation processes and when so used enhance the sorption of the CO2 by the amine. A cyclic sorption process for separating CO2 from a gas stream, such as flue gas or natural gas, brings the gas stream into contact with an absorbent solution of an amine CO2 sorbent in an ionic liquid solvent followed by desorbing the CO2 to regenerate the amine.
摘要翻译： 离子液体能够作为二氧化碳分离过程中胺二氧化碳吸收剂化合物的溶剂，当这样使用时，胺可以增强二氧化碳的吸附。 用于从气流（例如废气或天然气）中分离CO 2的循环吸附方法使气流与胺CO 2吸附剂在离子液体溶剂中的吸收剂溶液接触，然后解吸CO 2以再生胺。
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17.发明申请公开(公告)号：US20120063978A1
公开(公告)日：2012-03-15
申请号：US13228734
申请日：2011-09-09
IPC分类号： B01D53/62
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： Ionic liquids are capable of acting as solvents for amine CO2 absorbent compounds in CO2 separation processes and when so used enhance the sorption of the CO2 by the amine. A cyclic sorption process for separating CO2 from a gas stream, such as flue gas or natural gas, brings the gas stream into contact with an absorbent solution of an amine CO2 sorbent in an ionic liquid solvent followed by desorbing the CO2 to regenerate the amine.
摘要翻译： 离子液体能够作为二氧化碳分离过程中胺二氧化碳吸收剂化合物的溶剂，当这样使用时，胺可以增强二氧化碳的吸附。 用于从气流（例如废气或天然气）中分离CO 2的循环吸附方法使气流与胺CO 2吸附剂在离子液体溶剂中的吸收剂溶液接触，然后解吸CO 2以再生胺。
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公开(公告)号：US09034288B2
公开(公告)日：2015-05-19
申请号：US13229174
申请日：2011-09-09
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A CO2 amine scrubbing process uses an absorbent mixture consisting of an alkanolamine CO2 sorbent in combination with a non-nucleophilic base. The alkanolamine has oxygen and nitrogen sites capable of nucleophilic attack at the CO2 carbon atom. The nucleophilic addition is promoted in the presence of the non-nucleophilic, relatively stronger base, acting as a proton acceptor. The non-nucleophilic base promoter, which may also act as a solvent for the alkanolamine, can promote reaction with the CO2 at each of the reactive hydroxyl and nucleophilic amine group(s) of the alkanolamines. In the case of primary amino alkanolamines the CO2 may be taken up by a double carboxylation reaction in which two moles of CO2 are taken up by the reacting primary amine groups.
摘要翻译： CO 2胺洗涤方法使用由链烷醇胺CO 2吸附剂与非亲核基团组合组成的吸收混合物。 链烷醇胺具有能够在CO 2碳原子上亲核攻击的氧和氮位点。 在非亲核相对较强的碱存在下促进亲核加成，作为质子受体。 还可以作为烷醇胺溶剂的非亲核碱基启动子可以促进与链烷醇胺的各反应性羟基和亲核胺基团中的CO 2的反应。 在伯氨基链烷醇胺的情况下，CO 2可以被双羧化反应吸收，其中两摩尔CO 2被伯胺基团反应。
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公开(公告)号：US09186616B2
公开(公告)日：2015-11-17
申请号：US13228556
申请日：2011-09-09
申请人： Lisa S. Baugh , Pavel Kortunov , Michael Siskin
发明人： Lisa S. Baugh , Pavel Kortunov , Michael Siskin
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： Ionic liquids containing a cation with a potentially nucleophilic carbon atom bearing a relatively acidic hydrogen atom bonded to a potentially nucleophilic carbon atom, typically in the conjugated —NC(H)N— structure or a —NC(H)S— structure of imidazolium, imidazolidinium or thiazolium salts, can be capable of acting as sorbents for CO2 in cyclic separation processes. The ionic liquid may be used on its own, mixed with a solvent, preferably an aprotic, polar, non-aqueous solvent such as toluene, DMSO, NMP or sulfolane, or in conjunction with a non-nucleophilic nitrogenous base promoter compound having a pKa of at least 10.0 such as a carboxamidine or a guanidine.
摘要翻译： 含有阳离子的离子液体具有与可能亲核性碳原子键合的相对酸性氢原子的潜在亲核性碳原子，通常在咪唑鎓的共轭-NC（H）N-结构或-NC（H）S-结构中， 咪唑鎓或噻唑鎓盐可以作为循环分离过程中的二氧化碳吸附剂。 离子液体可以单独使用，与溶剂，优选非质子极性的非水溶剂如甲苯，DMSO，NMP或环丁砜混合，或与具有pKa的非亲核含氮碱基启动子化合物混合使用 至少10.0，如甲脒或胍。
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公开(公告)号：US20140178278A1
公开(公告)日：2014-06-26
申请号：US14087377
申请日：2013-11-22
申请人： Michael Siskin , Patrick L. Hanks , Pavel Kortunov , Robert B. Fedich , Patrick P. McCall , Hans Thomann , Daniel Leta , Lisa S. Baugh , David C. Calabro , Harry W. Deckman
发明人： Michael Siskin , Patrick L. Hanks , Pavel Kortunov , Robert B. Fedich , Patrick P. McCall , Hans Thomann , Daniel Leta , Lisa S. Baugh , David C. Calabro , Harry W. Deckman
IPC分类号： B01D53/62
CPC分类号： B01D53/62 , B01D53/1425 , B01D53/1475 , B01D2252/20415 , B01D2252/20447 , B01D2252/20484 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： Systems and methods are provided for performing CO2 sorption and regeneration processes that can take advantage of phase changes between solutions of amine-CO2 reaction products and precipitate slurries, where the slurry particles can include solid precipitates formed based on the amine-CO2 reaction products. An amine solution can be used to capture CO2 from a gas phase stream. During this initial capture process, the amine-CO2 reaction product can remain in solution. The solution containing the amine-CO2 reaction product can then be exposed to a set of conditions which result in precipitation of a portion of the amine-CO2 reaction product to form a slurry. The precipitate slurry can be passed into one or more release stages where the conditions for the slurry are altered to allow for release of the CO2.
摘要翻译： 提供了系统和方法，用于执行CO2吸附和再生过程，可以利用胺-CO 2反应产物和沉淀物浆料的溶液之间的相变，其中浆料颗粒可以包括基于胺-CO 2反应产物形成的固体沉淀物。 胺溶液可用于从气相物流中捕获CO 2。 在该初始捕获过程中，胺-CO 2反应产物可以保留在溶液中。 然后可以将含有胺-CO 2反应产物的溶液暴露于导致部分胺-CO 2反应产物沉淀形成浆料的一组条件。 沉淀浆料可以进入一个或多个释放阶段，其中改变浆料的条件以允许CO 2的释放。
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