公开(公告)号：US20160185885A1

公开(公告)日：2016-06-30

申请号：US14959233

申请日：2015-12-04

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Michael A. GIARDELLO

IPC: C08F32/00

CPC classification number: C08F32/00 ,  B01J31/2278 ,  B01J2231/543 ,  C08F4/80 ,  C08F132/08 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418

Abstract: This invention relates to olefin metathesis catalysts and methods for controlling olefin metathesis reactions. More particularly, the present invention relates to methods and compositions for catalyzing and controlling ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. This invention also relates to olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a ROMP composition comprising a resin composition comprising at least one cyclic olefin, and an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a method of making an article comprising combining an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts with a resin composition comprising at least one cyclic olefin, thereby forming a ROMP composition, and subjecting the ROMP composition to conditions effective to polymerize the ROMP composition. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

Abstract translation: 本发明涉及烯烃复分解催化剂和控制烯烃复分解反应的方法。 更具体地说，本发明涉及用于催化和控制开环易位聚合（ROMP）反应和通过ROMP制备聚合物制品的方法和组合物。 本发明还涉及包含至少两种金属卡宾烯烃复分解催化剂的烯烃复分解催化剂组合物。 本发明还涉及包含至少一种环烯烃的树脂组合物和包含至少两种金属卡宾烯烃复分解催化剂的烯烃易位催化剂组合物的ROMP组合物。 本发明还涉及一种制备制品的方法，包括将包含至少两种金属卡宾烯烃复分解催化剂的烯烃复分解催化剂组合物与包含至少一种环烯烃的树脂组合物组合，从而形成ROMP组合物，并将ROMP组合物 有效聚合ROMP组合物的条件。 通过本发明的复分解反应产生的聚合物产物可用于广泛的材料和复合材料应用。 本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。

公开(公告)号：US20150166767A1

公开(公告)日：2015-06-18

申请号：US14133793

申请日：2013-12-19

Applicant: MATERIA, INC.

Inventor： Christopher J. CRUCE ,  Brian EDGECOMBE ,  Paul W. BOOTHE ,  Michael A. GIARDELLO

IPC: C08K5/29

CPC classification number: C08K5/29 ,  C08G61/06 ,  C08G61/08 ,  C08G2261/418 ,  C08G2261/76 ,  C08L75/04

Abstract: This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the adhesion of ROMP compositions to substrate materials using an adhesion promoter composition, where the adhesion promoter composition comprises a pre-reacted mixture comprising at least one compound containing at least two isocyanate groups and at least one compound comprising a heteroatom-containing functional group and a metathesis active olefin, where the adhesion promoter composition possesses in-resin storage stability when added to a resin composition, particularly a cyclic olefin resin composition, such as a ROMP composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

Abstract translation: 本发明涉及用于改善树脂组合物与基材的粘合性的组合物和方法。 更具体地说，本发明涉及使用粘合促进剂组合物改进ROMP组合物与基材的粘合性的组合物和方法，其中粘合促进剂组合物包含预反应的混合物，其包含至少一种含有至少两个异氰酸酯基团的化合物和 至少一种包含含杂原子的官能团和易位活性烯烃的化合物，其中当加入到树脂组合物中时，粘合促进剂组合物具有树脂存储稳定性，特别是环状烯烃树脂组合物，例如ROMP组合物。 通过本发明的ROMP反应生产的聚合物产品可用于广泛的材料和复合材料应用。 本发明在聚合物和材料化学和制造领域具有实用性。

公开(公告)号：US20210403654A1

公开(公告)日：2021-12-30

申请号：US17164095

申请日：2021-02-01

Applicant: MATERIA, INC.

Inventor： Christopher J. CRUCE ,  Brian EDGECOMBE ,  Paul W. BOOTHE ,  Michael A. GIARDELLO

IPC: C08J5/10 ,  C08L65/00 ,  C08G18/67 ,  C08J5/24 ,  C08G61/08 ,  C08K5/101 ,  C08K5/29

Abstract: This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the adhesion of ROMP compositions to substrate materials using an adhesion promoter composition, where the adhesion promoter composition comprises a pre-reacted mixture comprising at least one compound containing at least two isocyanate groups and at least one compound comprising a heteroatom-containing functional group and a metathesis active olefin, where the adhesion promoter composition is storage stable and/or possesses in-resin storage stability when added to a resin composition, particularly a cyclic olefin resin composition, such as a ROMP composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

公开(公告)号：US20160017089A1

公开(公告)日：2016-01-21

申请号：US14774347

申请日：2014-03-14

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

IPC: C08G61/08 ,  C08L65/00

CPC classification number: C08G61/08 ,  B29C37/0032 ,  B29C41/00 ,  B29C41/22 ,  B29K2075/00 ,  C08G2261/3325 ,  C08G2261/418 ,  C08K5/05 ,  C08K5/053 ,  C08K5/101 ,  C08L65/00 ,  Y10T428/31938

Abstract: The present invention relates to in-mold coating of a cyclic olefin polymer. More particularly, the present invention relates to methods and compositions for in-mold coating cyclic olefin polymers prepared by ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and material chemistry and manufacture.

Abstract translation: 本发明涉及环状烯烃聚合物的模内涂覆。 更具体地，本发明涉及通过开环易位聚合（ROMP）反应制备的环烯烃聚合物的模内涂布方法和组合物，以及通过ROMP制备聚合物制品。 通过本发明的复分解反应产生的聚合物产物可用于广泛的材料和复合材料应用。 本发明在聚合物和材料化学和制造领域具有实用性。

公开(公告)号：US20150152283A1

公开(公告)日：2015-06-04

申请号：US13914919

申请日：2013-06-11

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

IPC: C09D145/00

CPC classification number: C09D143/00 ,  C09D143/04

Abstract: A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

Abstract translation: 公开了一种改善复分解组合物如开环易位聚合（ROMP）组合物对基材的粘合性的方法，其中向可聚合树脂组合物中加入粘合促进剂以改善聚合树脂的粘合性 涉及基材。 已经发现添加粘合促进剂对复分解素，特别是ROMP，组合物对基材，特别是玻璃表面的粘附性提供有益的改进，导致由其形成的ROMP材料的改进的特性。 粘合促进剂通常包含官能化的硅烷化合物和过氧化物。 还公开了一种ROMP组合物，其包含环烯烃，ROMP复分解催化剂和粘合促进剂。 通过本发明的复分解（ROMP）反应制备的聚合物产物可用于提供广泛的材料和各种复合应用。 本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。

公开(公告)号：US20140370318A1

公开(公告)日：2014-12-18

申请号：US14213701

申请日：2014-03-14

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

IPC: C08K5/05 ,  C08K5/053 ,  B29C41/22 ,  C08K5/101

CPC classification number: C08G61/08 ,  B29C37/0032 ,  B29C41/00 ,  B29C41/22 ,  B29K2075/00 ,  C08G2261/3325 ,  C08G2261/418 ,  C08K5/05 ,  C08K5/053 ,  C08K5/101 ,  C08L65/00 ,  Y10T428/31938

Abstract: The present invention relates to in-mold coating of a cyclic olefin polymer. More particularly, the present invention relates to methods and compositions for in-mold coating cyclic olefin polymers prepared by ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and material chemistry and manufacture.

Abstract translation: 本发明涉及环状烯烃聚合物的模内涂覆。 更具体地，本发明涉及通过开环易位聚合（ROMP）反应制备的环烯烃聚合物的模内涂布方法和组合物，以及通过ROMP制备聚合物制品。 通过本发明的复分解反应产生的聚合物产物可用于广泛的材料和复合材料应用。 本发明在聚合物和材料化学和制造领域具有实用性。

公开(公告)号：US20140088260A1

公开(公告)日：2014-03-27

申请号：US13838459

申请日：2013-03-15

Applicant: MATERIA, INC.

Inventor： Michael A. GIARDELLO ,  Christopher M. HAAR ,  Brian EDGECOMBE ,  Anthony R. STEPHEN ,  Li-Sheng WANG ,  Diana STOIANOVA

IPC: C07C265/08 ,  C08F32/08

CPC classification number: C09J145/00 ,  C07C265/08 ,  C08F32/08 ,  C08F263/04 ,  C08G61/08 ,  C08G2261/142 ,  C08G2261/144 ,  C08G2261/3324 ,  C08G2261/418 ,  C09J4/00 ,  C09J5/00 ,  C09J165/00

Abstract: The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.

Abstract translation: 本发明公开了一种粘合剂组合物，其包含至少一种具有至少一个复分解活性双键的C 3 -C 20烯烃化合物，其中所述烯烃是取代或未取代的; 以及用于与衬底表面相互作用的至少一种相容性功能。 衬底表面可以是任何表面，例如硅酸盐玻璃，硅酸盐矿物，金属，金属合金，陶瓷，天然石，塑料，碳，硅和半导体。 本发明还公开了利用这些粘合剂的制品以及将聚烯烃粘附到基材表面的方法。