公开(公告)号：US20140357820A1

公开(公告)日：2014-12-04

申请号：US14192552

申请日：2014-02-27

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Michael A. GIARDELLO

IPC: C08F4/80

CPC classification number: C08F32/00 ,  B01J31/2278 ,  B01J2231/543 ,  C08F4/80 ,  C08F132/08 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418

Abstract: This invention relates to olefin metathesis catalysts and methods for controlling olefin metathesis reactions. More particularly, the present invention relates to methods and compositions for catalyzing and controlling ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. This invention also relates to olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a ROMP composition comprising a resin composition comprising at least one cyclic olefin, and an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a method of making an article comprising combining an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts with a resin composition comprising at least one cyclic olefin, thereby forming a ROMP composition, and subjecting the ROMP composition to conditions effective to polymerize the ROMP composition. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

Abstract translation: 本发明涉及烯烃复分解催化剂和控制烯烃复分解反应的方法。 更具体地说，本发明涉及用于催化和控制开环易位聚合（ROMP）反应和通过ROMP制备聚合物制品的方法和组合物。 本发明还涉及包含至少两种金属卡宾烯烃复分解催化剂的烯烃复分解催化剂组合物。 本发明还涉及包含至少一种环烯烃的树脂组合物和包含至少两种金属卡宾烯烃复分解催化剂的烯烃易位催化剂组合物的ROMP组合物。 本发明还涉及一种制备制品的方法，包括将包含至少两种金属卡宾烯烃复分解催化剂的烯烃复分解催化剂组合物与包含至少一种环烯烃的树脂组合物组合，从而形成ROMP组合物，并将ROMP组合物 有效聚合ROMP组合物的条件。 通过本发明的复分解反应产生的聚合物产物可用于广泛的材料和复合材料应用。 本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。

公开(公告)号：US20170166714A1

公开(公告)日：2017-06-15

申请号：US15120554

申请日：2015-02-25

Applicant: MATERIA, INC.

Inventor： Christopher J. CRUCE ,  Brian EDGECOMBE ,  Paul W. BOOTHE ,  Michael A. GIARDELLO

IPC: C08J5/10 ,  C08K5/29 ,  C08K5/101 ,  C08G61/08

CPC classification number: C08J5/10 ,  C08G18/6715 ,  C08G18/672 ,  C08G61/08 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08J5/24 ,  C08J2345/00 ,  C08K5/101 ,  C08K5/29 ,  C08L65/00

Abstract: This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the adhesion of ROMP compositions to substrate materials using an adhesion promoter composition, where the adhesion promoter composition comprises a pre-reacted mixture comprising at least one compound containing at least two isocyanate groups and at least one compound comprising a heteroatom-containing functional group and a metathesis active olefin, where the adhesion promoter composition is storage stable and/or possesses in-resin storage stability when added to a resin composition, particularly a cyclic olefin resin composition, such as a ROMP composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

公开(公告)号：US20170130089A1

公开(公告)日：2017-05-11

申请号：US15413703

申请日：2017-01-24

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

IPC: C09D143/00

CPC classification number: C09D143/00 ,  C09D143/04

Abstract: A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

公开(公告)号：US20170066869A1

公开(公告)日：2017-03-09

申请号：US15122860

申请日：2014-12-23

Applicant: MATERIA, INC.

Inventor： Christopher J. CRUCE ,  Michael A. GIARDELLO ,  Brian L. CONLEY ,  Anthony R. STEPHEN

IPC: C08G61/02 ,  F16L59/02 ,  F16L59/20 ,  C09D165/00

Abstract: The present invention is directed to addressing one or more of the aforementioned concerns and relates to thermal insulation materials and thermal insulation material compositions and methods for thermally insulating pipelines and associated equipment, structures, and objects used in offshore drilling. The present invention is directed to articles of manufacture comprising the thermal insulation materials and/or thermal insulation material compositions of the invention. More particularly the present invention relates to the use of ring opening metathesis polymerization polymers (ROMP polymers) and/or ROMP polymer composites for thermally insulating pipelines and associated equipment, structures, and objects used in offshore oil drilling.

Abstract translation: 本发明涉及解决上述问题中的一个或多个，并且涉及隔热材料和绝热材料组合物和用于隔热管道及相关设备，结构和用于海上钻井中的物体的方法。 本发明涉及包含本发明的隔热材料和/或绝热材料组合物的制品。 更具体地说，本发明涉及开环易位聚合聚合物（ROMP聚合物）和/或ROMP聚合物复合材料用于隔热管道和相关设备，结构和用于海上石油钻井中的物体的用途。

公开(公告)号：US20170233876A1

公开(公告)日：2017-08-17

申请号：US15374327

申请日：2016-12-09

Applicant: MATERIA, INC.

Inventor： Michael A. GIARDELLO ,  Mark S. TRIMMER ,  Christopher J. CRUCE ,  Anthony R. STEPHEN ,  Stuart A. M. TONER ,  Albert E. PAPPANO

IPC: C25B9/00 ,  C08G61/02 ,  B29C39/00 ,  C25B1/34 ,  B29C67/24

CPC classification number: C25B9/00 ,  B29C39/003 ,  B29C67/246 ,  B29K2023/00 ,  B29K2023/38 ,  B29K2105/0014 ,  B29K2995/0029 ,  B29L2031/7146 ,  C08G61/02 ,  C08G2120/00 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/58 ,  C25B1/34

Abstract: Articles of manufacture possessing corrosion resistance characteristics are described, in particular for use in the chlor-alkali and other industries. The articles are formed from a resin composition, e.g., a cyclic olefin composition, polymerized with a Group 8 olefin metathesis catalyst. In particular aspects, an electrolytic cell component, such as a cell cover for use in the electrolysis of brine, may be formed from the resin composition. Among other benefits, such articles provide improved corrosion resistance compared to articles molded from other resin compositions, such as fiberglass reinforced polyesters and vinyl esters, and two-component dicyclopentadiene (DCPD) resins comprising molybdenum or tungsten pre-catalysts.

公开(公告)号：US20160326304A1

公开(公告)日：2016-11-10

申请号：US15109703

申请日：2015-01-12

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

IPC: C08G61/02 ,  B29B15/12 ,  C09D165/00 ,  C03C25/30

CPC classification number: C08G61/02 ,  B29B15/122 ,  B29K2309/08 ,  C03C17/328 ,  C03C25/30 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/964 ,  C08J5/043 ,  C08J2323/20 ,  C08K3/36 ,  C08K3/40 ,  C08K5/14 ,  C08K5/5419 ,  C08K5/5425 ,  C08K7/14 ,  C08K7/28 ,  C08L65/00 ,  C09D165/00

Abstract: A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter.

Abstract translation: 公开了一种改善复分解组合物如开环易位聚合（ROMP）组合物对基材的粘合性的方法，其中向可聚合树脂组合物中加入粘合促进剂以改善聚合树脂的粘合性 涉及基材。 已经发现添加粘合促进剂对复分解素，特别是ROMP，组合物对基材，特别是玻璃表面的粘附性提供有益的改进，导致由其形成的ROMP材料的改进的特性。 粘合促进剂通常包含官能化的硅烷化合物和过氧化物。 还公开了一种ROMP组合物，其包含环烯烃，ROMP复分解催化剂和粘合促进剂。

公开(公告)号：US20160257779A1

公开(公告)日：2016-09-08

申请号：US14899165

申请日：2014-07-03

Applicant: MATERIA, INC.

Inventor： Christopher J. CRUCE ,  Michael A. GIARDELLO ,  Mark S. TRIMMER ,  Anthony R. STEPHEN ,  Paul W. BOOTHE ,  Brian EDGECOMBE ,  Jason L. MOORE

IPC: C08G61/08

CPC classification number: C08G61/08 ,  C07C13/38 ,  C07C13/61 ,  C08F4/80 ,  C08G2261/3325 ,  C08G2261/418 ,  C08J5/043 ,  C08J2323/20 ,  C08K7/14 ,  C08L65/00

Abstract: The present invention relates to methods and compositions for olefin metathesis. More particularly, the present invention relates to methods and compositions for ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles and/or polymer composite articles via ROMP Polymer products produced via the metathesis reactions of the invention may be utilized in a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

Abstract translation: 本发明涉及烯烃复分解的方法和组合物。 更具体地说，本发明涉及用于开环易位聚合（ROMP）反应的方法和组合物以及通过ROMP制备聚合物制品和/或聚合物复合制品通过本发明的复分解反应生产的聚合物产品可用于宽 材料和复合材料应用范围。 本发明在聚合物和材料化学和制造领域具有实用性。

公开(公告)号：US20180237581A1

公开(公告)日：2018-08-23

申请号：US15955876

申请日：2018-04-18

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

IPC: C08G61/02 ,  C03C17/32 ,  C09D165/00 ,  B29B15/12

CPC classification number: C08G61/02 ,  B29B15/122 ,  B29K2309/08 ,  C03C17/328 ,  C03C25/30 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/964 ,  C08J5/043 ,  C08J2323/20 ,  C08K3/36 ,  C08K3/40 ,  C08K5/14 ,  C08K5/5419 ,  C08K5/5425 ,  C08K7/14 ,  C08K7/28 ,  C08L65/00 ,  C09D165/00

Abstract: A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

公开(公告)号：US20160186022A1

公开(公告)日：2016-06-30

申请号：US14926830

申请日：2015-10-29

Applicant: MATERIA, INC.

Inventor： Michael A. GIARDELLO ,  Christopher M. HAAR ,  Brian EDGECOMBE ,  Anthony R. STEPHEN ,  Li-Sheng WANG ,  Diana STOIANOVA

IPC: C09J145/00 ,  C09J5/00

CPC classification number: C09J145/00 ,  C07C265/08 ,  C08F32/08 ,  C08F263/04 ,  C08G61/08 ,  C08G2261/142 ,  C08G2261/144 ,  C08G2261/3324 ,  C08G2261/418 ,  C09J4/00 ,  C09J5/00 ,  C09J165/00

Abstract: The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.

公开(公告)号：US20160185897A1

公开(公告)日：2016-06-30

申请号：US14843448

申请日：2015-09-02

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Michael A. GIARDELLO

IPC: C08G61/08

CPC classification number: C08G61/08 ,  B01J31/28 ,  B01J2231/14 ,  B01J2231/54 ,  B01J2531/821 ,  C08F4/80 ,  C08F32/00 ,  C08F132/08 ,  C08G2261/11 ,  C08G2261/135 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/76

Abstract: This invention relates to olefin metathesis catalysts and methods for controlling olefin metathesis reactions. More particularly, the present invention relates to methods and compositions for catalyzing and controlling ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. This invention also relates to olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts, wherein the at least two metal carbene olefin metathesis catalysts are structurally different, are chemically different, are distinct compounds, are not isomers, are not structural isomers, are not diastereoisomers, are not stereoisomers, are not enantiomers, or are not cis/trans isomers of each other, or any combinations thereof. This invention also relates to a ROMP composition comprising a resin composition comprising at least one cyclic olefin, and an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts, wherein the at least two metal carbene olefin metathesis catalysts are structurally different, are chemically different, are distinct compounds, are not isomers, are not structural isomers, are not diastereoisomers, are not stereoisomers, are not enantiomers, or are not cis/trans isomers of each other, or any combinations thereof. This invention also relates to a method of making an article comprising combining an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts with a resin composition comprising at least one cyclic olefin, thereby forming a ROMP composition, and subjecting the ROMP composition to conditions effective to polymerize the ROMP composition, wherein the at least two metal carbene olefin metathesis catalysts are structurally different, are chemically different, are distinct compounds, are not isomers, are not structural isomers, are not diastereoisomers, are not stereoisomers, are not enantiomers, or are not cis/trans isomers of each other, or any combinations thereof. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.