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11.发明申请CATALYST COMPOSITION AND PROCESS FOR PRODUCING CROSS-COUPLED COMPOUND USING SAME 审中-公开催化剂组合物和使用其制备交联偶联剂的方法公开(公告)号：US20100185019A1
公开(公告)日：2010-07-22
申请号：US12668338
申请日：2008-07-09
IPC分类号： C07C43/205 , B01J31/02 , B01J23/755 , C07C1/00
CPC分类号： B01J31/2273 , B01J31/0244 , B01J31/24 , B01J31/2404 , B01J31/30 , B01J2231/4233 , B01J2231/4238 , B01J2531/847 , C07B37/04 , C07C1/325 , C07C1/326 , C07C43/30 , C07C67/343 , C07C253/30 , C07C2521/02 , C07C2521/18 , C07C2527/128 , C07C2527/138 , C07C2531/24 , C07C15/14 , C07C69/76 , C07C255/50
摘要： A catalyst composition for a cross-coupling reaction comprising a nickel metal source, a fluorine source, and a nitrogen-containing heterocyclic compound having a specific structure, or a phosphine compound. Using this catalyst composition, a cross-coupled compound R5—R6 (wherein R5 and R6 are an aryl or heteroaryl group, or a linear, branched or cyclic alkyl group or a linear, branched or cyclic alkenyl group) is produced with a high selectivity by allowing an organometallic compound of the formula (2) R5-MY1 or the formula (3) R5-M-R5 (wherein R5 is the same as defined above, M is a Mg or Zn atom, and Y1 is a halogen atom) to react with a compound of the formula (4) R6—Y2 (wherein R6 is the same as defined above, and Y2 is a halogen atom, a methanesulfonate group, a toluenesulfonate group or a trifluoromethanesulfonate group).
摘要翻译： 包含镍金属源，氟源和具有特定结构的含氮杂环化合物的交联反应催化剂组合物或膦化合物。 使用该催化剂组合物，以高选择性制备交联体化合物R5-R6（其中R5和R6为芳基或杂芳基，或直链，支链或环状烷基或直链，支链或环状烯基） 通过使式（2）R5-MY1或式（3）R5-M-R5（其中R5与上述定义相同，M为Mg或Zn原子，Y1为卤素原子）的有机金属化合物， 与式（4）R6-Y2（其中R6与上述定义相同，Y2是卤素原子，甲磺酸酯基，甲苯磺酸酯基或三氟甲磺酸酯基）的化合物反应。
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12.发明授权Aminoalkoxystyrene, process for preparation thereof, polymer thereof, process for producing the polymer and use thereof 失效氨基烷氧基苯乙烯，其制备方法，其聚合物，聚合物的制备方法及其用途公开(公告)号：US07816475B2
公开(公告)日：2010-10-19
申请号：US11713087
申请日：2007-03-02
CPC分类号： C07C217/18 , B01J41/14 , C08F8/44 , C08F212/14 , C08F212/08 , C08F212/36
摘要： An aminoalkoxystyrene represented by the formula (1) wherein R1 and R2 are C1-4 alkyl and n is 3-6. The aminoalkoxystyrene is prepared by reacting an aminoalkoxyphenylmagnesium halide with vinyl halide in the presence of a catalyst. A quaternized amino group-containing polymer made by quaternizing the amino groups of a polymer prepared from the aminoalkoxystyrene is useful as an anion exchanger.
摘要翻译： 由式（1）表示的氨基烷氧基苯乙烯，其中R 1和R 2是C 1-4烷基，n是3-6。 氨基烷氧基苯乙烯通过在催化剂存在下使氨基烷氧基苯基卤化镁与乙烯基卤化物反应来制备。 通过季铵化由氨基烷氧基苯乙烯制备的聚合物的氨基制备的含季铵化的含氨基聚合物可用作阴离子交换剂。
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13.发明申请Aminoalkoxystyrene, process for preparation thereof, polymer thereof, process for producing the polymer and use thereof 失效氨基烷氧基苯乙烯，其制备方法，其聚合物，聚合物的制备方法及其用途公开(公告)号：US20070213490A1
公开(公告)日：2007-09-13
申请号：US11713087
申请日：2007-03-02
IPC分类号： C08F26/00
CPC分类号： C07C217/18 , B01J41/14 , C08F8/44 , C08F212/14 , C08F212/08 , C08F212/36
摘要： An aminoalkoxystyrene represented by the formula (1) wherein R1 and R2 are C1-4 alkyl and n is 3-6. The aminoalkoxystyrene is prepared by reacting an aminoalkoxyphenylmagnesium halide with vinyl halide in the presence of a catalyst. A quaternized amino group-containing polymer made by quaternizing the amino groups of a polymer prepared from the aminoalkoxystyrene is useful as an anion exchanger.
摘要翻译： 由式（1）表示的氨基烷氧基苯乙烯，其中R 1和R 2是C 1-4烷基，n是3-6。 氨基烷氧基苯乙烯通过在催化剂存在下使氨基烷氧基苯基卤化镁与乙烯基卤化物反应来制备。 通过季铵化由氨基烷氧基苯乙烯制备的聚合物的氨基制备的含季铵化的含氨基聚合物可用作阴离子交换剂。
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公开(公告)号：US07148363B2
公开(公告)日：2006-12-12
申请号：US10986885
申请日：2004-11-15
申请人： Shinichi Ishikawa , Hisao Eguchi
发明人： Shinichi Ishikawa , Hisao Eguchi
IPC分类号： C07D315/00 , C07D307/02 , C07C69/52 , C07C69/62
CPC分类号： C07C67/04 , C07C2601/14 , C07C2603/74 , C07C69/653 , C07C69/54
摘要： An acrylate compound of formula (4): is produced by allowing an acrylic acid compound of formula (1): to react with an unsaturated compound of formula (2) or (3): In formulae (1) through (4), R1 and R2 are H or F, R3 is H, F, or an alkyl, alkenyl, fluoroalkyl or fluoroalkenyl group, R4 and R5 are H, halogen, or an alkyl, alkenyl, halogenated alkyl or halogenated alkenyl group; and X and Y are an unsubstituted or substituted hydrocarbon group, and dashed line - - - means that X and Y may be bonded together to form a cyclic structure.
摘要翻译： 通过使式（1）的丙烯酸化合物与式（2）或（3）的不饱和化合物反应制备式（4）的丙烯酸酯化合物：在式（1）至（4）中，R R 1是H或F，R 3是H，F或烷基，烯基，氟代烷基或氟代烯基， O 4，R 5和R 5是H，卤素或烷基，烯基，卤代烷基或卤代烯基; X和Y是未取代或取代的烃基，虚线 - 表示X和Y可以键合在一起形成环状结构。
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公开(公告)号：US06479709B1
公开(公告)日：2002-11-12
申请号：US09238585
申请日：1999-01-28
申请人： Shin-ichi Ishikawa , Hisao Eguchi
发明人： Shin-ichi Ishikawa , Hisao Eguchi
IPC分类号： C07C4106
CPC分类号： C07C41/30 , C07C15/44 , C07C17/2632 , C07C25/28 , C07C43/215
摘要： A process for the production of a styrene derivative is provided. The process comprises reacting a Grignard reagent prepared from an aromatic halogen compound with a vinyl halide in the presence of a catalyst, wherein the catalyst is at least one member selected from the group consisting of manganese catlyst, iron catalyst, cobalt catalyst and rhodium catalyst.
摘要翻译： 提供了生产苯乙烯衍生物的方法。 该方法包括使由芳族卤素化合物制备的格氏试剂与乙烯基卤化物在催化剂存在下反应，其中该催化剂是选自锰催化剂，铁催化剂，钴催化剂和铑催化剂中的至少一种。
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公开(公告)号：US5138103A
公开(公告)日：1992-08-11
申请号：US745888
申请日：1991-08-16
申请人： Hisao Eguchi , Masashige Kubo , Noritaka Nagasaki , Koji Kunimoto
发明人： Hisao Eguchi , Masashige Kubo , Noritaka Nagasaki , Koji Kunimoto
IPC分类号： C07C37/62
CPC分类号： C07C37/62
摘要： A process for producing tetrabromobisphenol A of high quality, which comprises brominating bisphenol A with bromine, wherein a solvent mixture comprising a hydrohalogenic acid and an alcohol, is used as the solvent for reaction. Also disclosed is a process for producing tetrabromobisphenol A of high quality, which comprises brominating bisphenol A with bromine in an alcohol, wherein the reaction temperature is set at a level of from -10.degree. to +20.degree. C., and water is added in an aging step.
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公开(公告)号：US5059726A
公开(公告)日：1991-10-22
申请号：US600817
申请日：1990-10-22
申请人： Hisao Eguchi , Masashige Kubo , Koji Kunimoto , Sadami Shimizu , Masakatsu Sato , Hanzo Tamabayashi
发明人： Hisao Eguchi , Masashige Kubo , Koji Kunimoto , Sadami Shimizu , Masakatsu Sato , Hanzo Tamabayashi
IPC分类号： C07C37/62
CPC分类号： C07C37/62
摘要： A process for producing tetrabromobisphenol A, which comprises brominating bisphenol A in methanol, wherein the substrate concentration of bisphenol A to methanol is at most 20 wt/vol %.
摘要翻译： 一种生产四溴双酚A的方法，其包括在甲醇中溴化双酚A，其中双酚A至甲醇的底物浓度为至多20重量/体积％。
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公开(公告)号：US06833462B2
公开(公告)日：2004-12-21
申请号：US10303905
申请日：2002-11-26
申请人： Shinichi Ishikawa , Hisao Eguchi
发明人： Shinichi Ishikawa , Hisao Eguchi
IPC分类号： C07D31500
CPC分类号： C07C67/04 , C07C2601/14 , C07C2603/74 , C07C69/653 , C07C69/54
摘要： An acrylate compound of formula (4): is produced by allowing an acrylic acid compound of formula (1): to react with an unsaturated compound of formula (2) or (3): In formulae (1) through (4), R1 and R2 are H or F, R3 is H, F, or an alkyl, alkenyl, fluoroalkyl or fluoroalkenyl group, R4 and R5 are H, halogen, or an alkyl, alkenyl, halogenated alkyl or halogenated alkenyl group; and X and Y are an unsubstituted or substituted hydrocarbon group, and dashed line - - - means that X and Y may be bonded together to form a cyclic structure.
摘要翻译： 通过使式（1）的丙烯酸化合物与式（2）或（3）的不饱和化合物反应制备式（4）的丙烯酸酯化合物：在式（1）至（4）中，R R 1和R 2均为H或F，R 3为H，F或烷基，烯基，氟烷基或氟烯基，R 4和R 5为H，卤素或烷基 ，烯基，卤代烷基或卤代烯基; X和Y是未取代或取代的烃基，虚线 - 表示X和Y可以键合在一起形成环状结构。
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公开(公告)号：US06472567B2
公开(公告)日：2002-10-29
申请号：US09923347
申请日：2001-08-08
申请人： Shin-ichi Ishikawa , Hisao Eguchi
发明人： Shin-ichi Ishikawa , Hisao Eguchi
IPC分类号： C07C4106
CPC分类号： C07C41/30 , C07C15/44 , C07C17/2632 , C07C25/28 , C07C43/215
摘要： A process for the production of a styrene compound is provided. The process comprises reacting a Grignard reagent prepared from a tertiary butoxyphenyl halide with a vinyl halide in the presence of a catalyst, wherein the catalyst is at least one member selected from the group consisting of manganese catalyst, iron catalyst, cobalt catalyst and rhodium catalyst. The process overcomes the problems involved in the prior art, and is economical and safe. The styrene compound by the process is free from biphenyl.
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