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    Feed gas contaminant control in ion transport membrane systems
    13.
    发明授权
    Feed gas contaminant control in ion transport membrane systems 有权
    离子传输膜系统中的进料气体污染物控制

    公开(公告)号：US07556675B2

    公开(公告)日：2009-07-07

    申请号：US11247504

    申请日：2005-10-11

    申请人： Michael Francis Carolan ,  Eric Minford ,  William Emil Waldron

    发明人： Michael Francis Carolan ,  Eric Minford ,  William Emil Waldron

    IPC分类号： B01D53/22

    CPC分类号： B01J19/2475 ,  C01B3/36 ,  C01B13/0251 ,  C01B13/0255 ,  C01B2203/025

    摘要： Ion transport membrane oxidation system comprising an enclosure having an interior and an interior surface, inlet piping having an internal surface and adapted to introduce a heated feed gas into the interior of the enclosure, and outlet piping adapted to withdraw a product gas from the interior of the enclosure; one or more planar ion transport membrane modules disposed in the interior of the enclosure, each membrane module comprising mixed metal oxide material; and a preheater adapted to heat a feed gas to provide the heated feed gas to the inlet piping, wherein the preheater comprises an interior surface. Any of the interior surfaces of the enclosure, the inlet piping, and the preheater may be lined with a copper-containing metal lining. Alternatively, any of the interior surfaces of the inlet piping and the preheater may be lined with a copper-containing metal lining and the enclosure may comprise copper.

    摘要翻译： 离子传输膜氧化系统，其包括具有内部和内部表面的外壳，入口管道具有内表面并适于将加热的进料气体引入外壳的内部，以及出口管道，其适于将产物气体从内部和内部 外壳; 设置在外壳内部的一个或多个平面离子传递膜组件，每个膜组件包括混合金属氧化物材料; 以及预热器，其适于加热进料气体以将加热的进料气体提供给入口管道，其中预热器包括内表面。 外壳，入口管道和预热器的任何内表面可以衬有含铜金属衬里。 或者，入口管道和预热器的任何内表面可以衬有含铜金属衬里，并且外壳可以包括铜。

    Composite Seal
    14.
    发明申请
    Composite Seal 审中-公开
    复合密封

    公开(公告)号：US20080260455A1

    公开(公告)日：2008-10-23

    申请号：US11736020

    申请日：2007-04-17

    申请人： Michael Francis Carolan ,  Eric Minford ,  John Albert Cooke ,  Thomas John Calianno

    发明人： Michael Francis Carolan ,  Eric Minford ,  John Albert Cooke ,  Thomas John Calianno

    IPC分类号： F16L25/00

    CPC分类号： F16J15/128 ,  Y10T403/21

    摘要： A composite seal is disclosed having first and second metal layers overlying one another in spaced relation. A mineral layer is positioned between the metal layers. The metal and mineral layers have inner and outer perimeters, the inner perimeters overlapping to define an aperture. The metal layers are joined at a perimeter, preferably the outer perimeter, by welding. The metal layers are preferably precious metal or high temperature alloy foil and the mineral layer may be formed of mica, vermiculite, or modifications of vermiculite.

    摘要翻译： 公开了一种复合密封件，其具有以间隔的关系彼此叠置的第一和第二金属层。 矿物层位于金属层之间。 金属和矿物层具有内周和外周，内周重叠以限定孔。 金属层通过焊接在周边，优选外周边连接。 金属层优选为贵金属或高温合金箔，矿物层可以由云母，蛭石或蛭石的变型形成。

    Use of impure inert gases in the controlled heating and cooling of mixed conducting metal oxide materials
    16.
    发明授权
    Use of impure inert gases in the controlled heating and cooling of mixed conducting metal oxide materials 有权
    在混合导电金属氧化物材料的受控加热和冷却中使用不纯的惰性气体

    公开(公告)号：US08246719B2

    公开(公告)日：2012-08-21

    申请号：US12567167

    申请日：2009-09-25

    申请人： Michael Francis Carolan ,  John Charles Bernhart

    发明人： Michael Francis Carolan ,  John Charles Bernhart

    IPC分类号： B01D53/22

    CPC分类号： B01D71/024 ,  B01D53/228 ,  B01D67/0093 ,  C01B13/0255 ,  C01B2210/0046 ,  C01B2210/005 ,  C01B2210/0051 ,  C01B2210/0062 ,  C01B2210/0075

    摘要： Method for processing an article comprising mixed conducting metal oxide material. The method comprises contacting the article with an oxygen-containing gas and either reducing the temperature of the oxygen-containing gas during a cooling period or increasing the temperature of the oxygen-containing gas during a heating period; during the cooling period, reducing the oxygen activity in the oxygen-containing gas during at least a portion of the cooling period and increasing the rate at which the temperature of the oxygen-containing gas is reduced during at least a portion of the cooling period; and during the heating period, increasing the oxygen activity in the oxygen-containing gas during at least a portion of the heating period and decreasing the rate at which the temperature of the oxygen-containing gas is increased during at least a portion of the heating period.

    摘要翻译： 用于加工包含混合导电金属氧化物材料的制品的方法。 该方法包括使制品与含氧气体接触，并且在冷却期间降低含氧气体的温度或在加热期间增加含氧气体的温度; 在冷却期间，在冷却期间的至少一部分期间降低含氧气体中的氧活度，并且在冷却期间的至少一部分期间提高含氧气体的温度降低的速度; 并且在加热期间，在加热期间的至少一部分期间增加含氧气体中的氧活性，并且在加热期间的至少一部分期间降低含氧气体的温度升高的速率 。

    Liners For Ion Transport Membrane Systems
    17.
    发明申请
    Liners For Ion Transport Membrane Systems 有权
    离子传输膜系统衬垫

    公开(公告)号：US20080168901A1

    公开(公告)日：2008-07-17

    申请号：US11838477

    申请日：2007-08-14

    申请人： Michael Francis Carolan ,  Christopher Francis Miller

    发明人： Michael Francis Carolan ,  Christopher Francis Miller

    IPC分类号： B01J20/28 ,  B01J35/10

    CPC分类号： B01D53/22 ,  B01D53/228 ,  B01D63/06 ,  B01D63/08 ,  B01D2256/12 ,  B01D2313/14 ,  B01D2313/42 ,  B01D2317/02 ,  B01D2317/04 ,  C01B3/382 ,  C01B13/0251 ,  C01B13/0255 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/143 ,  C01B2210/0046 ,  Y02P20/52

    摘要： Ion transport membrane system comprising (a) a pressure vessel comprising an interior, an exterior, an inlet, an inlet conduit, an outlet, and an outlet conduit; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein the inlet and the outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; (c) a gas manifold having an interior surface wherein the gas manifold is in flow communication with the interior region of each of the planar ion transport membrane modules and with the exterior of the pressure vessel; and(d) a liner disposed within any of the inlet conduit, the outlet conduit, and the interior surface of the gas manifold.

    摘要翻译： 离子传输膜系统，包括（a）压力容器，其包括内部，外部，入口，入口导管，出口和出口导管; （b）多个平面离子传递膜组件，其设置在所述压力容器的内部并串联布置，每个膜组件包括混合的金属氧化物陶瓷材料并具有内部区域和外部区域，其中所述入口和出口 压力容器与膜组件的外部区域流动连通; （c）具有内表面的气体歧管，其中所述气体歧管与所述平面离子迁移膜模块的每个的内部区域以及所述压力容器的外部流动连通; 和（d）设置在任何入口导管，出口导管和气体歧管内表面内的衬垫。

    Module isolation devices
    18.
    发明授权
    Module isolation devices 失效
    模块隔离装置

    公开(公告)号：US07703472B2

    公开(公告)日：2010-04-27

    申请号：US11296633

    申请日：2005-12-07

    申请人： Michael Francis Carolan ,  John Albert Cooke ,  Michael David Buzinski

    发明人： Michael Francis Carolan ,  John Albert Cooke ,  Michael David Buzinski

    IPC分类号： F16K17/40 ,  B01D53/047

    CPC分类号： F16K17/16 ,  B01D53/22 ,  B01D63/00 ,  B01D2257/102 ,  B01D2313/18 ,  B01D2319/04 ,  Y10T137/1789

    摘要： A gas flow isolation device includes a gas flow isolation valve movable from an opened condition to a closed condition. The module isolation valve in one embodiment includes a rupture disk in flow communication with a flow of gas when the module isolation valve is in an opened condition. The rupture disk ruptures when a predetermined pressure differential occurs across it causing the isolation valve to close. In one embodiment the valve is mechanically linked to the rupture disk to maintain the valve in an opened condition when the rupture disk is intact, and which permits the valve to move into a closed condition when the rupture disk ruptures. In another embodiment a crushable member maintains the valve in an open condition, and the flow of gas passed the valve upon rupturing of the rupture disk compresses the crushable member to close the isolation valve.

    摘要翻译： 气体流隔离装置包括可从打开状态移动到关闭状态的气体流隔离阀。 在一个实施例中，模块隔离阀包括当模块隔离阀处于打开状态时与气流流动连通的破裂盘。 当在其上发生预定的压力差时，破裂盘破裂，导致隔离阀关闭。 在一个实施例中，当破裂盘完好时，阀与破裂盘机械连接以将阀保持在打开状态，并且当破裂盘破裂时允许阀移动到关闭状态。 在另一个实施例中，可压碎构件将阀保持在打开状态，并且在破裂盘破裂时气体流过阀的流动压缩可压碎构件以关闭隔离阀。

    Operation of mixed conducting metal oxide membrane systems under transient conditions
    19.
    发明授权
    Operation of mixed conducting metal oxide membrane systems under transient conditions 有权
    在瞬态条件下操作混合导电金属氧化物膜系统

    公开(公告)号：US07468092B2

    公开(公告)日：2008-12-23

    申请号：US11115778

    申请日：2005-04-27

    申请人： Michael Francis Carolan

    发明人： Michael Francis Carolan

    IPC分类号： B01D53/22

    CPC分类号： C01B13/0255 ,  B01D53/22 ,  B01D53/228 ,  B01D69/141 ,  B01D71/024 ,  B01D2323/12 ,  C01B2210/0046

    摘要： Method of operating an oxygen-permeable mixed conducting membrane having an oxidant feed side, an oxidant feed surface, a permeate side, and a permeate surface, which method comprises controlling the differential strain between the permeate surface and the oxidant feed surface at a value below a selected maximum value by varying the oxygen partial pressure on either or both of the oxidant feed side and the permeate side of the membrane.

    摘要翻译： 操作具有氧化剂进料侧，氧化剂进料表面，渗透侧和渗透表面的透氧性混合导电膜的方法，该方法包括将渗透物表面和氧化剂进料表面之间的微分应变控制在低于 通过改变膜的氧化剂进料侧和渗透侧中的任一个或两者的氧分压来选择最大值。