Process for the desulfurization of a crude gas containing H.sub.2 S
    11.
    发明授权
    Process for the desulfurization of a crude gas containing H.sub.2 S 失效
    含H2S的粗气体的脱硫方法

    公开(公告)号:US5628977A

    公开(公告)日:1997-05-13

    申请号:US436471

    申请日:1995-05-26

    Abstract: The invention relates to a process for the desulfurization of a crude gas stream containing at least H.sub.2 S in a Claus plant, afterburning of Claus waste gas, and gas washing of the waste gas from the afterburning to remove SO.sub.2, in which SO.sub.2 recovered by the gas washing is recycled to a point before the Claus plant. According to the invention, within the Claus plant, between 60% and 90%, preferably between 67% and 85%, and especially preferably between 67% and 80% of the sulfur contained in the crude gas is separated directly from the crude gas, and between 33% and 10%, preferably between 25% and 10%, and especially preferably between 20% and 15% of the sulfur originally contained in the crude gas is recycled as SO.sub.2. The gas washing to remove SO.sub.2 is advantageously carried out with an absorbing agent having a physical action. A partial stream of the crude gas can be conveyed directly into the afterburning, bypassing the Claus plant. In addition to a Claus reactor operated at a temperature of between 850.degree. and 1300.degree. C., preferably between 900.degree. and 1100.degree. C., the Claus plant can contain one or more catalytic and/or thermal reactors for sulfur production and condensers for sulfur recovery, use only thermal stages for sulfur production, or consist of a direct-oxidation Claus plant.

    Abstract translation: PCT No.PCT / EP93 / 03300 Sec。 371日期:1995年5月26日 102(e)日期1995年5月26日PCT提交1993年11月24日PCT公布。 公开号WO94 / 12430 日期:1994年7月9日本发明涉及在克劳斯装置中至少含有H 2 S的粗气流脱硫,Claus废气再燃烧和从后燃除去废气中去除SO2的方法,其中 通过气体洗涤回收的SO2再循环到克劳斯植物之前的一个点。 根据本发明,在克劳斯工厂内,粗气中所含的硫的60%至90%,优选67%至85%,特别优选67%至80%的硫直接从粗气中分离出来, 并且原始气体中原始含有的硫的33%至10%,优选25%至10%,特别优选20%至15%被再循环为SO 2。 用于除去SO 2的气体洗涤有利地用具有物理作用的吸收剂进行。 粗气体的一部分流可以直接进入后燃,绕过克劳斯工厂。 除了在850℃至1300℃之间,优选在900℃至1100℃之间操作的克劳斯反应器之外,克劳斯设备可以含有一个或多个用于硫生产的催化和/或热反应器以及用于 硫回收,仅使用硫化氢的阶段,或由直接氧化的克劳斯工厂组成。

    Removal of sulfur compounds from gases
    12.
    发明授权
    Removal of sulfur compounds from gases 失效
    从气体中除去硫化合物

    公开(公告)号:US4664903A

    公开(公告)日:1987-05-12

    申请号:US742447

    申请日:1985-06-07

    CPC classification number: C01B17/05 B01D53/1418 B01D53/1468 C07C7/11 C10K1/16

    Abstract: For the removal of sulfur compounds, especially H.sub.2 S, from gases that contain hydrocarbons, and/or CO.sub.2, the gases are scrubbed with a physical solvent, which is to be regenerated and reused. To obtain sulfur free of hydrocarbons, as well as a practically sulfur-free LPG fraction and optionally a C.sub.5+ fraction, an oxidizing agent is added to the solvent for reacting the sulfur compounds to elemental sulfur, and the sulfur is separated. The concomitantly absorbed hydrocarbons and/or CO.sub.2 can then be desorbed from the separated solvent by physical regeneration and can be recovered.

    Abstract translation: 为了从含有碳氢化合物和/或二氧化碳的气体中除去硫化合物,特别是硫化氢,气体被物理溶剂洗涤,物理溶剂将被再生和再利用。 为了获得无硫的烃,以及几乎无硫的LPG馏分和任选的C5 +馏分,将氧化剂加入到溶剂中以使硫化合物与元素硫反应,并且硫被分离。 然后伴随吸收的烃和/或CO 2可以通过物理再生从分离的溶剂中解吸并可以回收。

    METHOD FOR EXTINGUISHING A SMOULDERING FIRE IN A SILO
    13.
    发明申请
    METHOD FOR EXTINGUISHING A SMOULDERING FIRE IN A SILO 审中-公开
    一种用于在SILO中灭火的方法

    公开(公告)号:US20110024136A1

    公开(公告)日:2011-02-03

    申请号:US12900573

    申请日:2010-10-08

    CPC classification number: A62C3/04

    Abstract: The invention relates to a method for extinguishing a smouldering fire in a silo by introducing inert gas into the silo. The inert gas is introduced through a venturi-type nozzle above the stored content in the silo with a slow streaming velocity in such a way that mass ratio of the entrained surrounding gas to the incoming liquid inert gas is between 0.5 and 20. Thus a closed inert gas layer is formed above the smouldering fire.

    Abstract translation: 本发明涉及一种通过将惰性气体引入料仓来熄灭料仓中的闷烧火的方法。 惰性气体通过文丘里型喷嘴在筒仓内存储的物质上方以缓慢的流速引入,使得夹带的周围气体与进入的液体惰性气体的质量比在0.5和20之间。因此,封闭 惰性气体层形成在阴燃之上。

    ENHANCING THE RECOVERY OF CRUDE OIL WELLS
    14.
    发明申请
    ENHANCING THE RECOVERY OF CRUDE OIL WELLS 审中-公开
    增加原油油井的恢复

    公开(公告)号:US20100206556A1

    公开(公告)日:2010-08-19

    申请号:US12579865

    申请日:2009-10-15

    CPC classification number: E21B43/168

    Abstract: Described is a method for introducing at least one manufactured gas in the area of an oil reservoir for the purpose of enhancing the recovery of the oil reservoir. The gas is at least temporarily introduced in shock waves.

    Abstract translation: 描述了一种用于在储油器的区域中引入至少一种制造气体以提高储油器回收率的方法。 气体至少暂时引入冲击波。

    Process for thermal conversion of hydrogen sufide to elemental sulfur
    16.
    发明授权
    Process for thermal conversion of hydrogen sufide to elemental sulfur 失效
    氢化氢热转化为元素硫的工艺

    公开(公告)号:US5439664A

    公开(公告)日:1995-08-08

    申请号:US905567

    申请日:1992-06-29

    CPC classification number: C01B17/04 C01B17/0421 Y02P20/129

    Abstract: For the thermal conversion of hydrogen sulfide contained in a gaseous stream, the gaseous stream is introduced into a non-catalytic reactor together with sulfur dioxide obtained from a waste gas purification facility arranged downstream of the reactor. If necessary, the sulfur yield can be regulated by feeding additional fuel gas and/or reducing gas and/or process air into the reactor. The thus-produced vapor-phase sulfur is condensed out by cooling and is obtained as a product; the resultant gaseous stream extensively freed of sulfur compounds is discharged and fed into the aforesaid downstream waste gas purification facility.

    Abstract translation: 对于气流中所含的硫化氢的热转化,将气流与排放在反应器下游的废气净化装置获得的二氧化硫一起引入非催化反应器。 如果需要,可以通过向反应器中加入额外的燃料气体和/或还原气体和/或处理空气来调节硫产量。 由此产生的气相硫通过冷却冷凝,得到产物; 大量释放硫化合物的所得气流被排出并进料到上述下游废气净化设备中。

    Process for performing catalytic reactions
    17.
    发明授权
    Process for performing catalytic reactions 失效
    进行催化反应的方法

    公开(公告)号:US4988431A

    公开(公告)日:1991-01-29

    申请号:US097000

    申请日:1987-09-16

    Abstract: A process for performing catalytic reactions with intensive heat of reaction, in which a reaction mixture is conducted through a catalyst bed, from which the reaction heat is removed or to which it is fed by indirect heat exchange with a heat exchange medium. The catalyst bed adjoins at least one bed of a catalytically inert material, which also is in indirect heat exchange with the heat exchange medium.

    Abstract translation: 一种用强烈的反应热进行催化反应的方法,其中将反应混合物通过催化剂床进行,反应热从该催化剂床除去,或通过与热交换介质的间接热交换进料。 催化剂床邻近至少一个催化惰性材料床,其也与热交换介质进行间接热交换。

    Reactor for carrying out reactions having a high enthalpy change
    19.
    发明授权
    Reactor for carrying out reactions having a high enthalpy change 有权
    用于进行具有高焓变的反应的反应器

    公开(公告)号:US06676906B1

    公开(公告)日:2004-01-13

    申请号:US09435355

    申请日:1999-11-08

    Applicant: Michael Heisel

    Inventor: Michael Heisel

    Abstract: The invention relates to a reactor for carrying out reactions having a high enthalpy change containing catalyst particles between cooled dividing walls. According to the invention, the cooled dividing walls are formed by metal plates/metallic components in which hollow or intermediate spaces in the form of channels are provided in the metal plates/components for accommodating and conveying a cooling medium so as to cool the reactor. The reactor can be used for carrying out strongly exothermic catalytic reactions, for example for the selective hydrogenation of acetylene to ethylene.

    Abstract translation: 本发明涉及一种用于进行具有高焓变的反应的反应器,其中含有在冷却的分隔壁之间的催化剂颗粒。 根据本发明,冷却的分隔壁由金属板/金属部件形成,其中通道形式的中空或中间空间设置在金属板/部件中,用于容纳和输送冷却介质以冷却反应器。 该反应器可用于进行强烈的放热催化反应,例如用于将乙炔选择性氢化成乙烯。

    Method and reactor for producing ethylene oxide
    20.
    发明授权
    Method and reactor for producing ethylene oxide 失效
    生产环氧乙烷的方法和反应器

    公开(公告)号:US06172244B2

    公开(公告)日:2001-01-09

    申请号:US09423247

    申请日:2000-05-24

    Applicant: Michael Heisel

    Inventor: Michael Heisel

    Abstract: The invention relates to a process for the production of ethylene oxide from a gaseous feedstock—in a cooled exothermic catalytic reaction of ethylene and oxygen from this feed gas in parallel flow-through reaction zones. According to the invention, the reaction zones are limited by cooled dividing walls, and the cooling is achieved by a fluid that flows inside the dividing walls. In addition, the invention relates to a reactor for this purpose with catalyst particles between cooled dividing walls. According to the invention, the cooled dividing walls are formed with the aid of metal plates, and cavities in the form of channels for receiving and for passing through a coolant are arranged for cooling in the metal plates.

    Abstract translation: 本发明涉及一种用于从气态原料生产环氧乙烷的方法,该方法是在平行流通反应区中来自该进料气体的乙烯和氧气的冷却放热催化反应中。 根据本发明,反应区域受到冷却分隔壁的限制,并且冷却通过在分隔壁内流动的流体来实现。 此外,本发明涉及一种用于此目的的反应器,其具有在冷却的分隔壁之间的催化剂颗粒。 根据本发明,冷却的分隔壁借助于金属板形成,并且用于接收和通过冷却剂的通道形式的空腔被布置用于在金属板中冷却。

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