公开(公告)号：US09518182B2

公开(公告)日：2016-12-13

申请号：US14790457

申请日：2015-07-02

Applicant: Momentive Performance Materials Inc.

Inventor： Narayana Padmanabha Iyer ,  Indumathi Ramakrishnan ,  Anuj Mittal ,  Roy Rojas-Wahl ,  Samim Alam

IPC: C08L69/00 ,  C08G77/448 ,  C08G77/38 ,  C08G64/18 ,  C08G77/12

CPC classification number: C08G77/14 ,  C08G64/186 ,  C08G77/12 ,  C08G77/38 ,  C08G77/448 ,  C08L69/00 ,  C08L83/00

Abstract: There is described a polysiloxane having the structure: wherein R1, R2, and R3 are independently a hydrocarbon radical, an unsaturated radical, an alkoxy radical, an aryl radical or an alkenyloxy radical, R4 is independently a direct bond or hydrocarbon radical optionally substituted with oxygen and nitrogen, R5 is independently a hydrogen, a halogen, an aliphatic group having from 1 to 6 carbon atoms, an aromatic group having 6 to 8 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, or an aryloxy group, R6 is independently a hydroxyl group, an amine group, an acid chloride group, or a sulfonyl halide group, x is from 1 to 300; y is from 0 to 50; and z is from 0 to 50. The polysiloxane is used to make various copolymers and polymer blends. A variety of articles can be made using the polysiloxane described as a polymer blend or copolymer.

Abstract translation: 其中R1，R2和R3独立地是烃基，不饱和基团，烷氧基，芳基或烯氧基，R4独立地是直接键或任选被氧和氮取代的烃基，R 5独立地是氢 卤素，具有1-6个碳原子的脂族基团，具有6-8个碳原子的芳族基团，具有1-6个碳原子的烷氧基或芳氧基，R6独立地是羟基，胺 基团，酰氯基或磺酰卤基，x为1至300; y为0〜50; 并且z为0至50.聚硅氧烷用于制备各种共聚物和聚合物共混物。 可以使用描述为聚合物共混物或共聚物的聚硅氧烷制备各种制品。

公开(公告)号：US09428617B2

公开(公告)日：2016-08-30

申请号：US14858169

申请日：2015-09-18

Applicant: Momentive Performance Materials Inc.

Inventor： Anuj Mittal ,  Laxmi Samantara ,  Samim Alam ,  Anubhav Saxena ,  Indumathi Ramakrishnan ,  Roy U. Rojas-Wahl

IPC: C08G77/46 ,  C08G77/448 ,  C08L69/00 ,  C08G77/14 ,  C08L83/10 ,  C08L83/12 ,  C08G77/00

CPC classification number: C08G77/46 ,  C08G77/14 ,  C08G77/448 ,  C08G77/70 ,  C08L69/00 ,  C08L83/10 ,  C08L83/12

Abstract: An α,ω-functionalized polyoxyalkylene-siloxane polymer having the general structural Formula (I): provides improved hydrophilicity and hemocompatibility. The α,ω-functionalized polyoxyalkylene-siloxane polymer may be used to make various polycarbonate/α,ω-functionalized polyoxyalkylene-siloxane copolymers and polymer blends, as well as articles including such copolymers and blends.

Abstract translation: 具有通式结构式（I）的α，ω官能化聚氧化烯 - 硅氧烷聚合物：提供改善的亲水性和血液相容性。 α，ω官能化的聚氧化烯 - 硅氧烷聚合物可用于制备各种聚碳酸酯/α，ω-官能化的聚氧化烯 - 硅氧烷共聚物和聚合物共混物，以及包括这种共聚物和共混物的制品。

公开(公告)号：US20160002412A1

公开(公告)日：2016-01-07

申请号：US14790464

申请日：2015-07-02

Applicant: Momentive Performance Materials Inc.

Inventor： Narayana Padmanabha Iyer ,  Indumathi Ramakrishnan ,  Roy Rojas-Wahl ,  Samim Alam

IPC: C08G77/00 ,  C08G77/448

CPC classification number: C08L83/10 ,  C08G77/12 ,  C08G77/14 ,  C08G77/448 ,  C08G77/80 ,  C08G2261/594 ,  C08L69/00

Abstract: Disclosed herein is a polyorganosiloxane having the structure of Formula I: wherein, R1 and R2 are independently a hydrocarbon radical, an unsaturated radical, an alkoxy radical, an aryl radical or an alkenyloxy radical. R3 is an organic UV absorbing group, R4 independently is a direct bond, hydrocarbon radical optionally substituted with oxygen and nitrogen, or a group of Formula II(a) or Formula II(b) wherein A and B are a hydrocarbon radical, R5 is independently a hydrogen, a halogen, an aliphatic group having from 1 to 6 carbon atoms, an aromatic group having 6 to 8 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, or an aryloxy group, R6 is independently a hydroxyl group, an amine group, an acid chloride group, or a sulfonyl halide group, x is from 1 to 300, y is from 0 to 50 and z is from 1 to 50. The polyorganosiloxane is used to make various copolymers or polymer blends. A variety of articles can be made using the polysiloxane described as a polymer blend or copolymer.

Abstract translation: 本文公开了具有式I结构的聚有机硅氧烷：其中，R 1和R 2独立地为烃基，不饱和基，烷氧基，芳基或烯氧基。 R3是有机UV吸收基团，R4独立地是直接键，任选被氧和氮取代的烃基，或式II（a）或式II（b）的基团，其中A和B是烃基，R5是 独立地是氢，卤素，具有1至6个碳原子的脂族基团，具有6至8个碳原子的芳族基团，具有1至6个碳原子的烷氧基或芳氧基，R6独立地是羟基 ，胺基，酰氯基或磺酰卤基，x为1至300，y为0至50，z为1至50.聚有机硅氧烷用于制备各种共聚物或聚合物共混物。 可以使用描述为聚合物共混物或共聚物的聚硅氧烷制备各种制品。

公开(公告)号：US20150166708A1

公开(公告)日：2015-06-18

申请号：US14569057

申请日：2014-12-12

Applicant: Momentive Performance Materials Inc.

Inventor： Samim Alam ,  Roy U. Rojas Wahl

IPC: C08F255/02

CPC classification number: C08F255/02 ,  C08F230/08 ,  C08J3/24

Abstract: A process for producing a silane-crosslinked polyolefin which comprises exposing a polyolefin containing at least one [1,3,2]-dioxasilinane ring structure to moisture in the presence of an organic carboxylic acid, which is used as a hydrolysis and condensation catalyst and does not contain tin, thereby producing the silane-crosslinked polyolefin, wherein the polyolefin containing at least one [1,3,2]-dioxasilinane ring structure is made by the process of grafting an olefinically unsaturated [1,3,2]-dioxasilinane to a polyolefin in the presence of a free radical initiator. There is also provided the resulting silane-crosslinked polyolefin and the graftable silane composition used in the process.

Abstract translation: 一种制备硅烷交联聚烯烃的方法，其包括在有机羧酸存在下将含有至少一个[1,3,2] - 二氧杂环己烷环结构的聚烯烃暴露于水分中，所述有机羧酸用作水解和缩合催化剂， 不含锡，由此生产硅烷交联的聚烯烃，其中含有至少一种[1,3,2] - 二氧杂环己烷环结构的聚烯烃是通过接枝烯属不饱和[1,3,2] - 二氧杂环己烷 在自由基引发剂的存在下进行聚烯烃。 还提供了所得到的硅烷交联聚烯烃和在该方法中使用的可接枝硅烷组合物。