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公开(公告)号:US6051055A
公开(公告)日:2000-04-18
申请号:US117566
申请日:1998-07-28
申请人: Naohiko Ukawa , Toru Takashina , Susumu Okino , Kazuaki Kimura , Koichiro Iwashita , Kouji Ikeda , Heiji Tanaka
发明人: Naohiko Ukawa , Toru Takashina , Susumu Okino , Kazuaki Kimura , Koichiro Iwashita , Kouji Ikeda , Heiji Tanaka
CPC分类号: B01D53/18 , B01D53/504 , B01D53/80 , B01J19/26 , B05B1/205
摘要: An exhaust gas desulfurization system includes a spray pipe which is provided with a plurality of nozzles in the lengthwise direction and whose one end is closed and arranged horizontally in an absorption tower through which the exhaust gas passes vertically. Absorbent slurry is fed from the other end of the spray pipe and is injected upward from the nozzles, by which absorbent slurry is brought into contact with the exhaust gas to perform treatment in the absorption tower. The flow passage on the closed end side of the pipe is present in a shape such that the flow passage cross-sectional area decreases toward the closed end.
摘要翻译: PCT No.PCT / JP97 / 00152 Sec。 371日期1998年7月28日第 102(e)1998年7月28日PCT 1997年1月24日PCT PCT。 第WO97 / 27931号公报 日期1997年8月7日废气脱硫系统包括喷管,该喷管在长度方向上设置有多个喷嘴,其一端封闭并且水平地布置在废气垂直通过的吸收塔中。 吸收剂浆料从喷射管的另一端进料,并从喷嘴向上注入,使吸收剂浆料与废气接触,以在吸收塔中进行处理。 管的封闭端侧的流路的形状为使流路截面积向封闭端减少的形状。
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公开(公告)号:US06511636B1
公开(公告)日:2003-01-28
申请号:US09407042
申请日:1999-09-27
申请人: Taku Shimizu , Kazuaki Kimura , Kiyoshi Okazoe , Atsushi Tatani , Naohiko Ukawa , Masao Hino , Susumu Okino , Takashi Haruki , Toru Takashina , Eiji Ochi
发明人: Taku Shimizu , Kazuaki Kimura , Kiyoshi Okazoe , Atsushi Tatani , Naohiko Ukawa , Masao Hino , Susumu Okino , Takashi Haruki , Toru Takashina , Eiji Ochi
IPC分类号: B01D5000
CPC分类号: C10M173/02 , B01D53/46 , B01D53/501 , C10M2215/042 , C10M2229/045 , C10M2229/046 , C10N2220/13 , C10N2240/58 , F23J15/003 , F23J15/022 , F23J2215/20 , F23J2219/50
摘要: Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.
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公开(公告)号:US06203598B1
公开(公告)日:2001-03-20
申请号:US09246130
申请日:1999-02-08
申请人: Shigeo Hasegawa , Naohiko Ukawa , Susumu Okino , Koichiro Iwashita , Kazuaki Kimura , Atsushi Yoshioka , Yoshimitsu Kawanishi , Shoichi Onishi , Toru Takashina , Toyoshi Nakagawa
发明人: Shigeo Hasegawa , Naohiko Ukawa , Susumu Okino , Koichiro Iwashita , Kazuaki Kimura , Atsushi Yoshioka , Yoshimitsu Kawanishi , Shoichi Onishi , Toru Takashina , Toyoshi Nakagawa
IPC分类号: B01D5310
CPC分类号: B01D53/75 , B01D53/501 , B01D53/502 , B01D53/508 , B01D2251/404 , B01D2257/302
摘要: This invention relates to a flue gas treating process including a heat recovery step for recovering heat from flue gas by means of a heat exchanger (4) and thereby cooling the flue gas, and a subsequent absorption step for bringing the flue gas into gas-liquid contact with an absorbing fluid (D) in absorption towers (12, 13) so as to remove at least SO2 present in the flue gas by absorption into the absorbing fluid (D), which is characterized, for example, in that a powder addition step for spraying a powder collectable in the absorption step into the flue gas is provided prior to the heat recovery step. This invention makes it possible to provide a flue gas treating process in which a countermeasure against SO3 present in flue gas can be easily achieved without resorting to ammonia injection and the flue gas can further be purified without the disadvantage of causing the injected substance to remain in the treated flue gas.
摘要翻译: 烟气处理方法技术领域本发明涉及一种烟道气处理方法,其包括通过热交换器(4)从烟道气中回收热量并由此冷却烟道气的热回收步骤,以及随后的吸收步骤,用于将烟道气引入气液 与吸收塔(12,13)中的吸收流体(D)接触,以便通过吸收到吸收流体(D)中来除去烟道气中存在的至少SO 2,其特征在于:粉末添加 在热回收步骤之前提供将在吸收步骤中可收集的粉末喷射到烟道气中的步骤。 本发明使得可以提供一种烟道气处理方法,其中可以容易地实现对烟气中存在的SO 3的对策,而不需要采用氨注射,并且可以进一步净化烟道气,而不会导致注入物质残留 经处理的烟气。
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公开(公告)号:US6113863A
公开(公告)日:2000-09-05
申请号:US592116
申请日:1996-01-26
申请人: Taku Shimizu , Kazuaki Kimura , Kiyoshi Okazoe , Atsushi Tatani , Naohiko Ukawa , Masao Hino , Susumu Okino , Takashi Haruki , Toru Takashina , Eiji Ochi
发明人: Taku Shimizu , Kazuaki Kimura , Kiyoshi Okazoe , Atsushi Tatani , Naohiko Ukawa , Masao Hino , Susumu Okino , Takashi Haruki , Toru Takashina , Eiji Ochi
CPC分类号: C10M173/02 , B01D53/46 , B01D53/501 , F23J15/003 , F23J15/022 , C10M2215/042 , C10M2229/045 , C10M2229/046 , C10N2220/13 , C10N2240/58 , F23J2215/20 , F23J2219/50
摘要: Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350.degree. C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350.degree. C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.
摘要翻译: 提出了能够除去燃烧废气中的灰尘和硒(Se),无害化的五种燃烧废气处理系统:(1)燃烧废气冷却至350℃以下,灰尘分解, 化合物,Se分离; (2)燃烧废气冷却至350℃以下,粉尘分离,加入Se洗脱剂,灰尘形成规模; (3)燃烧废气中的灰尘由集尘器收集,利用脱硫装置中循环液的一部分形成粉尘,并将粉尘浆中的四价硒转化为不溶性化合物,分离成固体和液体 ; (4)灰尘通过集尘器与燃烧废气分离,并被加热气化Se,并被引入脱硫装置等,形成浆料,Se成不溶性化合物; (5)在脱硫装置的一部分循环液中加入四价Se不溶性的处理剂,喷入燃烧废气中使Se不溶。
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公开(公告)号:US6138378A
公开(公告)日:2000-10-31
申请号:US341433
申请日:1999-09-08
申请人: Toru Takashina , Naoyuki Kamiyama , Takeo Shinoda , Hiromitsu Nagayasu , Susumu Okino , Masakazu Onizuka , Koichiro Iwashita , Satoshi Nakamura , Kenji Inoue
发明人: Toru Takashina , Naoyuki Kamiyama , Takeo Shinoda , Hiromitsu Nagayasu , Susumu Okino , Masakazu Onizuka , Koichiro Iwashita , Satoshi Nakamura , Kenji Inoue
IPC分类号: B01D53/50 , B01D47/06 , B01D53/14 , B01D53/18 , B01D53/34 , B01D53/77 , B01D53/78 , B01D53/80 , F26B7/00
CPC分类号: B01D53/80 , B01D53/1412 , B01D53/18 , B01D53/504 , B01D53/78 , F23J2215/20 , F23J2219/40
摘要: This invention is related to a wet gas process which would not require a spray pump, and which would allow the absorption liquid to be recovered smoothly even if the flow velocity of the gases entrained to the liquid should decrease. A wet gas processing apparatus in which the absorption liquid collected in the first liquid storage tank is sprayed in a specified direction (which may be upward, horizontal or downward) by a discharge unit consisting of spray nozzles (14) or the like in the absorption tower. The sprayed liquid is brought into contact with the exhaust gases which are conducted into the tower, and the targeted components of the gases are absorbed and removed. This processing apparatus is distinguished by the following. The first liquid storage tank for the absorption liquid comprises a pressure tank (11) which generates a pressurized gas in the space above the surface of the collected liquid (11a). The increased pressure of the pressurized gas is employed to spray the liquid collected in the pressurized tank from the spray nozzle unit in the absorption tower. This apparatus is further distinguished as the following. This invention has overflow ports which generate a virtually horizontal overflow or source flow. The absorption liquid propelled by the overflow ports makes orthogonal contact with the flow of exhaust gases, which results in both atomization of the liquid and liquid-vapor contact.
摘要翻译: PCT No.PCT / JP98 / 05062 Sec。 371 1999年9月8日第 102(e)日期1999年9月8日PCT提交1998年11月10日PCT公布。 出版物WO99 / 24148 日期1999年5月20日本发明涉及不需要喷雾泵的湿法气体处理,即使吸入液体的气体的流速降低也能使吸收液体顺利地回收。 一种湿气处理装置,其中收集在第一液体储罐中的吸收液体通过在吸收中由喷嘴(14)等组成的排出单元在特定方向(可以是向上,水平或向下)喷射) 塔。 喷射的液体与被引导到塔中的废气接触,并且气体的目标成分被吸收和去除。 该处理装置的区别在于以下。 用于吸收液体的第一液体储存罐包括在收集液体(11a)的表面上方的空间中产生加压气体的压力罐(11)。 加压气体的增加的压力用于将从加压罐中收集的液体从吸收塔中的喷嘴单元喷射。 该装置进一步区别如下。 本发明具有产生实质上水平的溢流或源流的溢流口。 由溢流口推动的吸收液体与废气流正交接触,导致液体雾化和液 - 气接触。
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公开(公告)号:US6096279A
公开(公告)日:2000-08-01
申请号:US033894
申请日:1998-03-03
申请人: Koichiro Iwashita , Kazuaki Kimura , Toyoshi Nakagawa , Naohiko Ukawa , Susumu Okino , Kiyoshi Okazoe
发明人: Koichiro Iwashita , Kazuaki Kimura , Toyoshi Nakagawa , Naohiko Ukawa , Susumu Okino , Kiyoshi Okazoe
CPC分类号: B01D53/508 , B01D53/1481
摘要: Flue gas is treated for the presence of SO.sub.3, without resorting to ammonia injection, by adding a powder into the flue gas and subsequently bringing the flue gas into gas-liquid contact with an absorbing fluid, whereby the SO.sub.2 present in the flue gas is removed by absorption into the absorbing fluid. The treatment process may also include introducing the flue gas into a dust collector, whereby dust, including the powder present in the flue gas, is collected, and/or recovering heat from the flue gas by means of a heat exchanger, whereby the flue gas is cooled. A system for treating flue gas is also provided.
摘要翻译: 对烟气进行处理,不用借助氨注入,通过向烟道气中加入粉末,随后使烟道气与吸收液体气液接触,由此除去烟道气中存在的SO2 通过吸收到吸收液中。 处理过程还可以包括将烟道气引入集尘器,由此收集包括烟道气中存在的粉末的粉尘,和/或通过热交换器从烟道气中回收热量,从而烟道气 被冷却。 还提供了一种处理烟气的系统。
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公开(公告)号:US5266286A
公开(公告)日:1993-11-30
申请号:US895546
申请日:1992-06-08
申请人: Naohiko Ukawa , Susumu Okino , Kenji Inoue , Toshiaki Kinomoto , Taku Shimizu
发明人: Naohiko Ukawa , Susumu Okino , Kenji Inoue , Toshiaki Kinomoto , Taku Shimizu
IPC分类号: B01D53/50 , B01D53/60 , B01D53/68 , B01D53/70 , B01D53/73 , B01D53/77 , C01B17/00 , C01B17/22
CPC分类号: B01D53/501 , B01D53/73
摘要: A flue gas desulfurization process for treating flue gases containing SO.sub.2, NO.sub.x, and halogen gases by the wet lime method, in which part of the absorbent liquid is extracted, freed from iodine, and recycled as makeup water to the absorption column.
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公开(公告)号:US4420465A
公开(公告)日:1983-12-13
申请号:US390835
申请日:1982-06-22
申请人: Naoharu Shinoda , Atsushi Tatani , Naohiko Ukawa , Michio Oshima , Susumu Okino , Sadaichi Shigeta
发明人: Naoharu Shinoda , Atsushi Tatani , Naohiko Ukawa , Michio Oshima , Susumu Okino , Sadaichi Shigeta
CPC分类号: C01F11/464 , B01D53/501
摘要: A process for desulfurizing an exhaust gas which comprises desulfurizing an exhaust gas containing SO.sub.2 by bringing it into contact with a slurry containing calcium compounds and aluminum compounds, characterized in that the concentration of the dissolved aluminum ion in said slurry is detected and a manganese compound is supplied into said slurry in such a manner that the ratio of the concentration of manganese (including both solid and liquid) to said concentration of the dissolved aluminum ion may be maintained in a molar ratio of less than 1 in said slurry.
摘要翻译: 一种废气脱硫方法,其特征在于,将含有二氧化硫的废气与含有钙化合物和铝化合物的浆料接触,其特征在于检测所述浆料中溶解的铝离子的浓度,锰化合物为 供给到所述浆料中,使得所述浆料中锰(包括固体和液体两者)的浓度与所述溶解的铝离子的浓度之比可保持小于1的摩尔比。
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公开(公告)号:US5976376A
公开(公告)日:1999-11-02
申请号:US745302
申请日:1996-11-08
申请人: Yasuyuki Ogushi , Masato Kaneko , Naohiko Ukawa , Susumu Okino , Masao Hino , Takashi Haruki , Taku Shimizu , Kiyoshi Okazoe , Masaharu Yoshimi
发明人: Yasuyuki Ogushi , Masato Kaneko , Naohiko Ukawa , Susumu Okino , Masao Hino , Takashi Haruki , Taku Shimizu , Kiyoshi Okazoe , Masaharu Yoshimi
IPC分类号: C12N1/20 , B01D53/34 , B01D53/50 , B01D53/77 , C02F1/52 , C02F1/56 , C02F1/70 , C02F3/12 , C02F3/30 , C02F3/34 , C02F9/00 , C12P3/00 , C12R1/38
CPC分类号: C02F9/00 , C02F1/5236 , C02F1/56 , C02F1/58 , C02F1/70 , C02F3/12 , C02F3/302 , C02F3/34 , C12P3/00 , C02F2101/106 , C02F2101/20 , C02F2103/18 , Y02W10/15 , Y10S210/912 , Y10S435/874
摘要: A process for the treatment of sewage to provide effective removal of selenium (especially the 6-valent selenium) to meet required standards for the dissolved amount of selenium, and the like, at a low cost are developed. The process and apparatus reduces selenium from the 6-valent selenium using microbiological treatment to obtain 4-valent selenium and/or simple selenium, and then provide a solid-liquid separation.
摘要翻译: 开发了以低成本处理污水以有效去除硒(特别是6价硒)以满足硒等溶解量的要求标准的方法。 该方法和装置使用微生物处理从6价硒还原硒,得到4价硒和/或简单硒,然后提供固液分离。
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公开(公告)号:US5246678A
公开(公告)日:1993-09-21
申请号:US821706
申请日:1992-01-16
申请人: Eiji Ochi , Kiyoshi Okazoe , Naohiko Ukawa , Susumu Okino
发明人: Eiji Ochi , Kiyoshi Okazoe , Naohiko Ukawa , Susumu Okino
CPC分类号: C01F11/464 , B01D53/501 , B01D53/504
摘要: A desulfurization process which comprises the steps of bringing a combustion exhaust gas into contact with a gypsum slurry containing 1% or less of calcium carbonate in a first absorption tower, and then bringing the combustion exhaust gas into contact with a gypsum slurry containing 1% or more of calcium carbonate in a second absorption tower. SO.sub.x can be removed from a combustion exhaust gas with a high efficiency in accordance with a wet lime/gypsum method.
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