摘要:
A color photographic material, the cyan coupler of which is of the formula ##STR1## in which R.sub.11 means an alkyl, aryl, acylamino, alkylcarbamoyl, arylcarbamoyl or a heterocyclic group,R.sub.12 means a group having electron-attracting characteristics,R.sub.13 means a group having electron-attracting characteristics,R.sub.14 means an alkyl or aryl group,R.sub.15 means a divalent linking member having 2 to 4 linking atoms,X means .dbd.O or .dbd.N--SO.sub.2 R.sub.21 andY means a group eliminable by hydrolytic or intramolecular (nucleophilic) attack,is distinguished by improved processing stability.
摘要:
The present invention relates to a new compound of formula (I) with the proviso that Y represents N, and also relates to a colour photographic silver halide material comprising at least one red-sensitive silver halide layer with which according to the invention a compound of formula (I) is associated, and also relates to a photographic colour development process in which couplers of formula (I) are reacted with colour developers of the phenylenediamine and/or diaminotoluene type to form coupling products which exhibit a strong absorption, particularly in the infrared region. The present invention further relates to the use of compounds of formula (I) as cyan and/or infrared couplers in colour photographic silver halide materials.
摘要:
A photosensitive silver halide emulsion which is ripened with at least one compound of the formula (I)R.sub.1 --X--R.sub.2 (I)in whichR.sub.1 and R.sub.2 mutually independently mean groups which are linked to X via an element from periods 3 to 6 of main group 4 or 5 or via an element from sub-groups 4 to 8 of the periodic system of elements, wherein R.sub.1 and R.sub.2 may be attached together via a linking member and wherein the bonds R.sub.1 --X and R.sub.2 --X may mutually independently be single or double bonds, andX means Se or Te,is distinguished by elevated sensitivity, low grain and low fog.
摘要:
A color photographic silver halide material having at least one silver halide emulsion layer, which is stabilized with a compound of formula (I) or (II) ##STR1## where X represents O or NR.sub.2 Y represents halogen, Z.sup..crclbar. represents an anion, R.sub.1 represents hydrogen or a substituent, or jointly with X represents the remaining members of a condensed ring R.sub.2 represents hydrogen or a substituent, and Q represents the atoms required for the completion of a 5- or 6-membered ring, is characterized by enhanced stability.
摘要:
Highly active silver halide development inhibitors are released from DIR couplers corresponding to formula I during color development. Where DIR couplers are used in color photographic silver halide materials, high edge effects and high inter-image effects are obtained.A--(TIME).sub.n --Z IIn formula I,A is the residue of a coupler which couples with the oxidation product of a silver halide developing agent under the conditions of photographic development and, in doing so, releases a group corresponding to the following formula--(TIME).sub.n --ZTIME is a binding link which together with the group Z (a triazole ring) attached thereto is releases on reaction of the coupler with the oxidation product of a silver halide developing agent and which, in turn, releases the group Z with delay under the development conditions;n is 0 or 1;Z is a triazole ring corresponding to one of the following formulae ##STR1## R.sup.1 is alkylthio; R.sup.2 is H, alkyl, alkythio, aryl or a heterocyclic group; at least one of the substituents R.sup.1 and R.sup.2 contains at a distance of 2 to 4 atoms from the triazole ring a group --CO--OR.sup.3, --O--CO--OR.sup.3 or --O--CO--R.sup.3 hydrolyzable in aqueous alkali;R.sup.3 is alkyl, cycloalkyl or aryl.
摘要:
Precursor compounds from which photographically-active compounds are released with a time delay correspond to the following general formula ##STR1## wherein A represents the residue of a compound which undergoes oxidative coupling;X represents --O--, --S-- or --NR.sup.1 --;Y represents a releasable group which may consist of or contain the residue of a photographically-active compound; andR represents a group for controlling the kinetics of release.Advantageous pictorial properties (inter-image effect, edge effect, modulation transfer function) are obtained with compounds according to the present invention if the photographically-active residue is the residue of a development inhibitor.
摘要:
Polymers, containing polymerized units of at least one compound of the formula ##STR1## and at least one compound of the formula ##STR2## are useful for the preparation of silver halide emulsions.
摘要:
The light-fastness of an inkjet recording material having a support and an image-receiving layer containing a binder is improved if the image-receiving layer contains a water soluble inorganic thiosulphate, trithionate or tetrathionate or an organic thiosulphate in a quantity of 2 to 200 wt. %, relative to the quantity of binder in the image-receiving layer.
摘要:
In the case of color materials with the usual processing times, bleaching and bleaching/fixing baths containing an iron(III) ion complex salt as bleach and, in addition, a 5- to 7-membered heterocyclic compound containing at least one N-atom and at least one other hetero atom from the group consisting of O,S,N which is substituted by --S.sup..crclbar. and, at a quaternary ring nitrogen atom, carries a positive charge arranged in such a way that no tautomeric charge compensation to a neutral thione form is possible, provide for good bleaching, i.e. for black areas free from residual silver in the case of color negative materials and for low minimum densities in the case of color reversal materials, by virtue of their excellent bleaching rate and, at the same time, their high stability.
摘要:
Metal complexes, particularly copper and nickel complexes of azo dyes corresponding to general formula (I) are suitable as color dyes for the production of color images by the dye diffusion transfer process. The dyes are (in non-metallized form), in the form of so-called "dye-releasers", bound to a redox-active carrier radical provided with a ballast group, which dye-releasers are associated to a light-sensitive silver halide emulsion layer. During development, the metallizable dyes are image-wise released and are converted, after diffusion into a light-receiving layer, into the corresponding metal complexes ##STR1## wherein E represents an electron acceptor radical; andK represents the radical of an azo coupler component, derived from an open-chain or closed ring ketomethylene compound, a cyclic enamine compound or a phenolic compound.