Method of preparing co-precipitated microcrystalline dye dispersions and layers coated therewith in materials

    公开(公告)号:US07026108B2

    公开(公告)日:2006-04-11

    申请号:US10625021

    申请日:2003-07-23

    摘要: A method has been disclosed for preparing a co-precipitated microcrystalline dye dispersion, the absorption spectrum of which exceeds the summoned spectra of individually dispersed dyes, which comprises, as consecutive preparation steps: adding to one vessel, an amount of at least one pentamethine oxonol-type barbituric acid filter dye having ionizable sites in its molecular structure; adding thereto an aqueous alkaline solution in an amount sufficient to completely dissolve the said filter dye while stirring the solution thus formed; adding in another vessel, to an amount of at least one pyrrole type filter dye, an amount of water, followed by adding of an aqueous alkaline solution and a surfactant; followed, after having completely dissolved (under stirring conditions) the said pyrrole type filter dye, by adding to the solution thus formed in the other vessel, the solution formed in the one vessel; adding an aqueous acidic solution up to a pH of less than 3.0; adding an aqueous alkaline solution up to a pH in the range from 4.0 up to 5.5; followed by adding a binder in order to make the dispersion thus obtained ready-for-coating in a filter dye layer on a support, suitable for use as antihalation undercoat layer between said support and a light-sensitive layer or as a backing layer of said material, or as layer covering the light-sensitive layer, thus providing safelight protection.

    Industrial radiographic silver halide material suitable for rapid processing applications
    2.
    发明授权
    Industrial radiographic silver halide material suitable for rapid processing applications 失效
    适用于快速加工应用的工业射线卤化银材料

    公开(公告)号:US06936411B2

    公开(公告)日:2005-08-30

    申请号:US10758577

    申请日:2004-01-15

    摘要: A silver halide industrial radiographic material comprising on at least one side of a support a hydrophilic gelatinous non-spectrally sensitized radiation-sensitive emulsion layer, having grains, coated in a total amount in the range from 6 to 20 g, expressed as an equivalent amount of silver nitrate per square meter, and at least one non-radiation sensitive protective gelatinous antistress overcoat layer thereupon, wherein a ratio of gelatin to silver, expressed as silver nitrate in the said layer arrangement is at least 0.70, wherein said gelatinous layers are hardened by a gelatin cross-linking agent in an amount in order to have a dissolving time of at least 40 minutes, said time being defined as the period of time from the moment when the silver halide photographic material, dipped into 50 ml of an aqueous solution of 1.5% by weight of sodium hydroxide at 50° C., until the moment that the base becomes visible due to dissolving of the layers coated thereupon, is characterized by a hydrophilic gelatinous layer arrangement wherein a hydrophilic polymer is present in an amount of at least 1 g per m2.

    摘要翻译: 一种卤化银工业射线照相材料,其在载体的至少一侧上包含亲水性凝胶状非光谱敏化型辐射敏感乳剂层,其具有以6至20g的总量涂覆的颗粒,其表示为当量 每平方米的硝酸银和至少一种非辐射敏感性的防静电胶质抗静电外涂层,其中所述层布置中以硝酸银表示的明胶与银的比例至少为0.70,其中所述凝胶状层被硬化 通过明胶交联剂以使溶解时间至少为40分钟,所述时间定义为从卤化银照相材料浸入50ml水溶液中的时间 在50℃下为1.5重量%的氢氧化钠,直到由于其上涂覆的层的溶解使基体变得可见的时刻,其特征在于 亲水凝胶层布置,其中亲水性聚合物以每平方米至少1克的量存在。

    Method of preparing co-precipitated microcrystalline dye dispersions and layers coated therewith in materials
    3.
    发明申请
    Method of preparing co-precipitated microcrystalline dye dispersions and layers coated therewith in materials 失效
    在材料中制备共沉淀的微晶染料分散体和涂层的层的方法

    公开(公告)号:US20040074020A1

    公开(公告)日:2004-04-22

    申请号:US10625021

    申请日:2003-07-23

    IPC分类号: C09B001/00

    摘要: A method has been disclosed for preparing a co-precipitated microcrystalline dye dispersion, the absorption spectrum of which exceeds the summoned spectra of individually dispersed dyes, which comprises, as consecutive preparation steps: adding to one vessel, an amount of at least one pentamethine oxonol-type barbituric acid filter dye having ionizable sites in its molecular structure; adding thereto an aqueous alkaline solution in an amount sufficient to completely dissolve the said filter dye while stirring the solution thus formed; adding in another vessel, to an amount of at least one pyrrole type filter dye, an amount of water, followed by adding of an aqueous alkaline solution and a surfactant; followed, after having completely dissolved (under stirring conditions) the said pyrrole type filter dye, by adding to the solution thus formed in the other vessel, the solution formed in the one vessel; adding an aqueous acidic solution up to a pH of less than 3.0; adding an aqueous alkaline solution up to a pH in the range from 4.0 up to 5.5; followed by adding a binder in order to make the dispersion thus obtained ready-for-coating in a filter dye layer on a support, suitable for use as antihalation undercoat layer between said support and a light-sensitive layer or as a backing layer of said material, or as layer covering the light-sensitive layer, thus providing safelight protection.

    摘要翻译: 已经公开了一种制备共沉淀的微晶染料分散体的方法,其吸收光谱超过单独分散的染料的召唤光谱,其包括作为连续制备步骤:向一个容器中加入一定量的至少一种五甲氧基oxonol 型巴比妥酸过滤染料,其分子结构中具有电离位点; 向其中加入足以完全溶解所述过滤染料同时搅拌形成的溶液的碱性水溶液; 在另一个容器中加入一定量的至少一种吡咯型过滤染料,一定量的水,然后加入碱性水溶液和表面活性剂; 然后在完全溶解(在搅拌条件下)所述吡咯型过滤染料,通过向在其他容器中形成的溶液加入在一个容器中形成的溶液; 加入酸性水溶液至pH小于3.0; 加入碱性水溶液至4.0至5.5范围内的pH; 然后加入粘合剂以使得如此获得的分散体在支撑体上的过滤染料层中即可涂覆,适合用作所述载体和感光层之间的防晕晕底涂层或作为所述支持体的背衬层 材料或覆盖光敏层的层,从而提供安全保护。

    Photothermo-or thermo-graphic material
    5.
    发明授权
    Photothermo-or thermo-graphic material 有权
    光热或热图形材料

    公开(公告)号:US06312885B1

    公开(公告)日:2001-11-06

    申请号:US09531421

    申请日:2000-03-20

    IPC分类号: G03C1498

    摘要: A photothermographic or thermographic material comprising a support having provided thereon or thereabove at least one image forming layer having its thermal expansion coefficient in the range of 1.0 to 1.5 and having provided on or above said at least one image forming layer a layer which has its thermal expansion coefficient of at least 0.9 and lower than 1.0 and comprises at least one kind of polymer latex having a glass transition temperature of not higher than a heat development temperature, said layer which has its thermal expansion coefficient of at least 0.9 and lower than 1.0 being farther from the support than the at least one image forming layer.

    摘要翻译: 一种光热照相或热成像材料,其包括在其上或其上设置有至少一个其热膨胀系数在1.0至1.5范围内的图像形成层的支撑件,并且在所述至少一个图像形成层上或上方提供具有其热 膨胀系数至少为0.9且低于1.0,并且包括玻璃化转变温度不高于显影温度的至少一种聚合物胶乳,所述热膨胀系数至少为0.9且低于1.0的所述层是 比支撑件远离至少一个图像形成层。

    Method of preparing (100) tabular grains rich in silver bromide
    9.
    发明授权
    Method of preparing (100) tabular grains rich in silver bromide 失效
    制备(100)富含溴化银的片状晶粒的方法

    公开(公告)号:US6080536A

    公开(公告)日:2000-06-27

    申请号:US267635

    申请日:1999-03-15

    摘要: A method has been described of preparing a photosensitive emulsion comprising tabular silver halide grains rich in silver bromide, having {100} major faces and an aspect ratio more than 1.5, wherein at least 50% of the projected area of all grains is provided by said {100} tabular grains, said method comprising the step of running in a reaction vessel an aqueous silver salt solution and an aqueous alkali halide solution rich in alkali bromide, characterized in that before starting running said reaction vessel comprises in an aqueous solution of gelatin an amount of amino-modified polyvinyl alcohol as an aqueous soluble polymer.

    摘要翻译: 已经描述了一种制备感光乳剂的方法,其包含富含溴化银的片状卤化银颗粒,其具有{100}主面和大于1.5的纵横比,其中所有颗粒的投影面积的至少50%由所述 所述方法包括在反应容器中运行富含碱金属溴化物的银盐溶液和碱金属卤化物水溶液的步骤,其特征在于在开始运行之前,所述反应容器包含在明胶水溶液中 氨基改性的聚乙烯醇作为水溶性聚合物的量。

    Method for processing photographic silver halide photosensitive element
    10.
    发明授权
    Method for processing photographic silver halide photosensitive element 失效
    照相卤化银感光元件的处理方法

    公开(公告)号:US5948602A

    公开(公告)日:1999-09-07

    申请号:US063865

    申请日:1998-04-21

    CPC分类号: G03C1/053 G03C5/26 G03C1/0053

    摘要: When a double-sided photographic silver halide photosensitive element having a crossover light quantity of up to 15% is processed through an automatic processor, it is developed with a developer containing an ascorbic acid type developing agent. By restricting the drag-out of the developer to 1.0 ml or less per 10.times.12-inch size sheet, the photosensitive element can be processed and effectively dried so as to produce high-quality images free of residual color.

    摘要翻译: 当通过自动处理器处理具有高达15%的交叉光量的双面照相卤化银感光元件时,用含有抗坏血酸型显影剂的显影剂显影。 通过将显影剂的拉伸限制为每10×12英寸尺寸的片材1.0ml或更少,可以处理和有效地干燥感光元件,以产生没有残留颜色的高质量图像。