摘要:
The present invention is directed to a process for the preparation of an aqueous polyurea dispersion bya) dispersing in water at an NCO:NH equivalent ratio of 0.5:1.0 to 2.0:1.0i) a polyisocyanate which has an average functionality of 1.5 to 4.0 and an isocyanate content of at least 12% by weight andii) a polyamine having at least two primary and/or secondary amino groups and a molecular weight of at least at an NCO:OH equivalent ratio of 0.5:1.0 to 2.0:1.01000 andb) allowing the polyisocyanate and polyamine to react to form an aqueous polyurea dispersion.The present invention is also directed to the aqueous polyurea dispersion prepared by this process.
摘要:
The present invention is directed to a process for the preparation of a polyurethane coating by a) preparing a coating composition having an improved potlife fromi) a compound containing at least two hydroxyl groups,ii) a polyisocyanate containing aliphatically-, cycloaliphatically- or araliphatically-bound isocyanate groups,iii) about 0.005 to 2.0 to weight percent, based on the weight of components i) and ii), of a tine catalyst andiv) at least about 50 mole percent, based on the tin catalyst, of hydrogen chloride,b) applying the coating composition to a substrate andc) curing the coating composition, optionally in the presence of an amine vapor, to form the polyurethane coating.
摘要:
The present invention is directed to a one-component polyurethane or polyurea composition which may be cured at either ambient or elevated temperature and is based ona) a liquid blocked polyisocyanate wherein the isocyanate groups have been blocked with a phenolic blocking agent.b) a solid polyamine salt which is insoluble in and dispersed throughout the liquid blocked polyisocyanate, the solid polyamine salt being based on the reaction product of a polyamine with an organic or inorganic acid.The present invention is also directed to a process for the preparation of a high molecular weight polymer by heating the one-component composition at elevated temperature or by adding a polar solvent to the above coating composition and allowing the composition to cure.
摘要:
A polyurethane-forming reaction mixture characterized by its ability to be adjusted with respect to its viscosity in response to changing temperature and humidity conditions is achieved with a mixture that includes a liquid polyisocyanate having an isocyanate group content of at least 10% by weight, an isocyanate-reactive component which includes at least one high molecular weight polyol, a urethane catalyst and from 0.2 to 5 parts by weight per 100 parts by weight of isocyanate reactive component of a viscosity adjusting component. The viscosity adjusting component is preferably a diamine, a polyamine and/or an amine-terminated polyol. This reaction mixture is particularly useful for producing polyurethane geotextile composite materials useful as liners for ditches and canals.
摘要:
This invention relates to syntactic foams comprising the reaction product of a liquid diphenylmethane diisocyanate component, with an isocyanate-reactive component, a filler having a density of less than 1 g/cm 3, and at least one organo-metallic catalyst. This invention also relates to the use of these syntactic foams for insulating pipes.
摘要翻译:本发明涉及包含液体二苯基甲烷二异氰酸酯组分与异氰酸酯反应性组分,密度小于1g / cm 3的填料和至少一种有机金属催化剂的反应产物的复合泡沫体。 本发明还涉及这些用于绝缘管的复合泡沫的用途。
摘要:
This invention relates to a process for the production of an optically clear, light-stable polyurethane-urea elastomer having an onset softening point of at least 130° C., processed at ambient temperature and casted in a mold at an isocyanate index of 95 to 120. This process comprises reacting: A) a liquid polyisocyanate or polyisocyanate prepolymer having an NCO group content of about 5 to about 50%, an average functionality of 2 to 3, a viscosity of less than 5,000 mPa.s at 25° C.; and B) an isocyanate-reactive component; in the presence of C) at least one organometallic catalyst. The present invention also relates to the optically clear, light-stable polyurethane-urea elastomers produced by this process.
摘要:
This invention relates to a process for the preparation of polyurethane encapsulated fertilizer particles. This process comprises applying an isocyanate-reactive component to fertilizer particles, and applying an aliphatic polyisocyanate to fertilizer particles in separate steps to form polyurethane encapsulated fertilizer particles. The two reactants may be applied in either order, with the polyisocyanate being first or last. These two steps may optionally be repeated as many times, as necessary to yield polyurethane encapsulated fertilizer particles which contain from 0.5 to 15% by weight of polyurethane, based on the total weight of the encapsulated fertilizer particles. It is also possible to mix the isocyanate-reactive component and the polyisocyanate together to form a mixture which is then applied to the fertilizer particles. These polyurethane coatings which encapsulates the fertilizer particles are biodegradable.
摘要:
This invention relates to liquid polyisocyanate compositions having improved freeze stability. These liquid polyisocyanate compositions have an NCO group content of 15 to 30%, and comprise a blend of (A) an MDI adduct having an NCO group content of 15 to 30%, and (B) an allophanate-modified MDI having an NCO group content of 12 to 32.5%.
摘要:
The present invention relates to highly elastic polyurethane contact adhesives, a process to coat substrates with these contact adhesives, and the coated substrates produced by this process. This invention requires a) a polyisocyanate with a functionality of less than about 4 and b) a polyol blend comprising 1) about 90 to 100% polyethers with molecular weights from about 1,800 to 12,000 and average functionality from about 1.5 to about 4, and 2) up to about 10% of chain extenders with molecular weights from about 60 to 400 and average functionality from about 1.5 to about 3. The functionalities and amounts of components a) and b) are such that the molecular weight between crosslinks is from about 7,000 to about 16,000 and the equivalent ratio of isocyanate groups to isocyanate-reactive groups is from about 80:100 to about 120:100 and the urethane group content is from about 1 to about 8%. It is preferred that at least one of components a) and b) have a functionality of greater than about 2.2.