Electroluminescent materials and devices
    13.
    发明申请
    Electroluminescent materials and devices 有权
    电致发光材料和器件

    公开(公告)号:US20070259208A1

    公开(公告)日:2007-11-08

    申请号:US11796256

    申请日:2007-04-27

    IPC分类号: B32B9/00 H01J1/62

    摘要: An electroluminescent composition is provided comprising: (a) a compound of the general chemical formula (I): wherein M is lithium, sodium, potassium, rubidium, caesium, beryllium, magnesium, calcium, strontium, barium, copper, silver, gold, zinc, boron, aluminum, gallium, indium, germanium, tin, antimony, lead, manganese, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, cadmium or chromium; n is the valence of M; and R1, R2 and R3 can be the same or different, and are selected from hydrogen, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic, heterocyclic or polycyclic ring structure, a fluorocarbon, a halogen or a nitrile group; and (b) a suitable dopant. The composition may be used in forming electroluminescent devices.

    摘要翻译: 提供一种电致发光组合物,其包含:(a)一般化学式(I)的化合物:其中M为锂,钠,钾,铷,铯,铍,镁,钙,锶,钡,铜,银,金, 锌,硼,铝,镓,铟,锗,锡,锑,铅,锰,铁,钌,锇,钴,铑,铱,镍,钯,铂,镉或铬; n是M的化合价; 和R 1,R 2和R 3可以相同或不同,并且选自氢,取代或未取代的脂族基, 取代或未取代的芳族,杂环或多环结构,碳氟化合物,卤素或腈基; 和(b)合适的掺杂剂。 该组合物可用于形成电致发光器件。

    COMPOUNDS HAVING ELECTROLUMINESCENT OR ELECTRON TRANSPORT PROPERTIES
    18.
    发明申请
    COMPOUNDS HAVING ELECTROLUMINESCENT OR ELECTRON TRANSPORT PROPERTIES 有权
    具有电致发光或电子传输特性的化合物

    公开(公告)号:US20110006295A1

    公开(公告)日:2011-01-13

    申请号:US12922291

    申请日:2009-02-24

    摘要: A compound of the formula R1(CR3═CR4)nAr(CR4═CR3)nR2 wherein: n is 0 or 1; Ar represents aryl or heteroaryl having 1-5 aromatic rings which may be chain or fused or a combination of chain and fused, which may be substituted with alkoxy, fluoro, fluoroalkyl or cyano and which in the case of a 5-membered ring nitrogen heteroatom may be N-substituted with aryl or substituted aryl optionally further substituted with alkoxy, fluoro, fluoroalkyl or cyano; R1 and R2 independently represent aryl or nitrogen, oxygen or sulphur-containing heteroaryl having two to four fused aromatic rings one of which may be 5-membered and optionally substituted by aryl or heteroaryl having 1-5 chain or fused aromatic rings which may be further substituted with alkoxy, fluoro, fluoroalkyl or cyano; and R3 and R4 independently represent hydrogen, methyl, ethyl or benzyl. Also provided is a method of making a compound having electroluminescent and/or electroconductive properties, which comprises condensing an aromatic dialdehyde with a methyl-substituted heteroaryl compound having two to four fused rings which maybe unsubstituted or may be further substituted by aryl or heteroaryl having from one to four aromatic rings, said aryl or heteroaryl substituent or substituents optionally being substituted with one or more fluoro, fluoroalkyl or cyano substituents. The condensation may be carried out in acetic anhydride under reflux. The compounds may be incorporated e.g. as an electron transport layer into an optical light emitting diode, where embodiments can provide high electron mobility, low turn-on voltage and good lifetime, or into an electrostatic imaging member. A composition is provided comprising a compound as above and a second host or electron transport material and/or at least one dopant.

    摘要翻译: 式R1(CR3 = CR4)nAr(CR4 = CR3)nR2的化合物其中:n为0或1; Ar表示可以是链或稠合的具有1-5个芳环的芳基或杂芳基或可以被烷氧基,氟,氟代烷基或氰基取代的链和稠合的结合,并且在5元环氮杂原子的情况下 可以被任选进一步被烷氧基,氟,氟烷基或氰基取代的芳基或取代芳基取代; R 1和R 2独立地表示芳基或氮,具有2至4个稠合芳环的氧或含硫杂芳基,其中一个可以是5元并且任选被具有1-5个链或稠合芳环的芳基或杂芳基取代, 被氟烷基或氰基取代; 并且R 3和R 4独立地表示氢,甲基,乙基或苄基。 还提供了制备具有电致发光和/或导电性质的化合物的方法,其包括将芳族二醛与具有2-4个稠合环的甲基取代的杂芳基化合物缩合,所述稠环可以是未取代的或可以进一步被芳基或杂芳基取代, 一至四个芳环,所述芳基或杂芳基取代基或任选被一个或多个氟,氟代烷基或氰基取代基取代的取代基。 缩合反应可在乙酸酐中进行。 可以将化合物例如, 作为电子传输层进入光发射二极管,其中实施例可以提供高电子迁移率,低导通电压和良好的寿命,或者进入静电成像构件。 提供了包含上述化合物和第二主体或电子传输材料和/或至少一种掺杂剂的组合物。

    Phenanthroline compounds and electroluminescent devices using the same
    19.
    发明授权
    Phenanthroline compounds and electroluminescent devices using the same 失效
    菲咯啉化合物和使用其的电致发光器件

    公开(公告)号:US08642188B2

    公开(公告)日:2014-02-04

    申请号:US12520349

    申请日:2007-12-19

    IPC分类号: H01L51/54

    摘要: In OLEDs, improved efficiency is obtained by using compounds of formula [Ar](CH═CH—R1)n wherein n is an integer from 1 to 4; [Ar] is a polycyclic aromatic or heteroaromatic scaffold optionally substituted with one or more alkyl or alkoxy groups; and R1 is a 5-membered heteroaryl group optionally substituted with methyl, methoxy, aryl or heteroaryl, or is phenyl or naphthyl optionally substituted with methyl, methoxy, trifluoromethyl or cyano or is biphenyl or substituted biphenyl. The compounds are believed to be novel and can be made by condensing a compound of formula wherein [Ar] and n are as defined above with a compound of formula [Ar](CH3)nR1CHO in the presence of an acid catalyst e.g. an anhydride of an organic acid.

    摘要翻译: 在OLED中,通过使用式[Ar](CH = CH-R 1)n的化合物,其中n是1至4的整数,可以获得提高的效率; [Ar]是任选被一个或多个烷基或烷氧基取代的多环芳族或杂芳族支架; 并且R 1是任选被甲基,甲氧基,芳基或杂芳基取代的5元杂芳基,或者是被甲基,甲氧基,三氟甲基或氰基任选取代的苯基或萘基,或是联苯基或取代的联苯基。 这些化合物被认为是新的,并且可以通过在酸催化剂的存在下将下式化合物其中[Ar]和n如上所定义的化合物与式[Ar](CH 3)n R 1 CHO的化合物缩合制备。 有机酸的酸酐。