公开(公告)号：US09856375B2

公开(公告)日：2018-01-02

申请号：US15036724

申请日：2014-11-07

Applicant: RHODIA OPERATIONS

Inventor： Stéphane Jeol ,  Thierry Badel ,  Jean-François Thierry

IPC: C08L77/06 ,  B29C49/00 ,  B29C45/00 ,  B29B9/10 ,  C08G69/26 ,  B29K77/00 ,  B29K105/16

CPC classification number: C08L77/06 ,  B29B9/10 ,  B29C45/0001 ,  B29C49/0005 ,  B29C2045/0091 ,  B29K2077/00 ,  B29K2105/16 ,  C08G69/26 ,  C08L2201/08 ,  C08L2203/20 ,  C08L2205/02

Abstract: The invention pertains to A polyannide composition [composition (C)] comprising: —from 20 to 95% wt of at least one polyamide [polyamide (A)]; —from 1 to 30% wt of at least one branched polyamide different from polyamide (A), said branched polyamide comprising recurring units derived from polycondensation of a mixture [mixture (B)] comprising: —at least one polyamine monomer comprising at least three amine functional groups selected from the group consisting of secondary amine group of formula —NH— and primary amine group of formula -MH2 [monomer (FN)], and—ε-caprolactam (or derivates thereof); said branched polyamide possessing a concentration of amine end groups (AEG) and a concentration of carboxylic end groups (CEG) such that the difference AEG−CEG is of at least 100 meq/kg [polyamide (B)]; and—from 0.01 to 3.5% wt of at least one thermal stabilizer [stabilizer (S)], —optionally, from 0 to 60% wt of at least one filler [filler (F)]; —optionally, from 0 to 20% wt of at least one impact modifying rubber [rubber (I)]; —optionally, from 0 to 20% wt of other conventional additives, with above % wt being referred to the total weight of composition (C).

公开(公告)号：US09670319B2

公开(公告)日：2017-06-06

申请号：US14416935

申请日：2013-07-10

Applicant: RHODIA OPERATIONS

Inventor： Stéphane Jeol ,  Floryan Decampo ,  Leon Zhu

IPC: C08G69/28 ,  C08G69/26 ,  B29C45/00 ,  B29C47/00 ,  B29C49/00 ,  C08G69/00 ,  B29K77/00 ,  B29L31/00

CPC classification number: C08G69/26 ,  B29C45/0001 ,  B29C47/0004 ,  B29C49/0005 ,  B29K2077/00 ,  B29K2077/10 ,  B29L2031/731 ,  C08G69/00 ,  C08G69/28

Abstract: The present invention relates to a novel polyamide synthesized from biobased monomers. The novel polyamide comprises the repeating unit of formula (I) below: Formula (I), in which R represents a covalent bond or a divalent hydrocarbon-based chosen from saturated or unsaturated aliphatics, saturated or unsaturated cycloaliphatics, aromatics, arylaliphatics and alkylaromatics. The present invention also relates to the process for preparing the said polyamide, to its uses, and to articles and compositions comprising the polyamide.

公开(公告)号：US20150045501A1

公开(公告)日：2015-02-12

申请号：US14345070

申请日：2012-09-18

Applicant: RHODIA OPERATIONS

Inventor： Stéphane Jeol

IPC: C08G73/10 ,  B29C49/04 ,  C07C211/09 ,  B29C45/00 ,  C08L79/08 ,  C07C63/313

CPC classification number: C08G73/1042 ,  B29C45/0001 ,  B29C49/04 ,  B29K2079/08 ,  B29K2105/0085 ,  C07C63/313 ,  C07C211/09 ,  C08G73/1075 ,  C08G73/1082 ,  C08K3/013 ,  C08L79/08

Abstract: The present invention relates to semiaromatic semicrystalline thermoplastic copolyimides obtained by polymerization of at least: (a) an aromatic compound comprising two anhydride functions and/or carboxylic acid and/or ester derivatives thereof; (b) a diamine of formula (I) NH2-R—NH2 in which R is a divalent aliphatic hydrocarbon-based radical optionally comprising heteroatoms, the two amine functions being separated by a number X of carbon atoms, X being between 4 and 12; and (c) a diamine of formula (II) NH2-R′—NH2 in which R′ is a divalent aliphatic hydrocarbon-based radical optionally comprising heteroatoms, the two amine functions being separated by a number Y of carbon atoms, Y being between 10 and 20; it being understood that diamine (b) is different from diamine (c).

Abstract translation: 本发明涉及通过至少聚合至少：（a）包含两个酸酐官能团的芳族化合物和/或其羧酸和/或酯衍生物而获得的半芳族半结晶热塑性共聚酰亚胺; （b）式（I）NH 2 -R-NH 2的二胺，其中R是任选地包含杂原子的二价脂族烃基自由基，两个胺官能团被X原子分开，X在4和12之间 ; 和（c）式（II）的二胺NH 2 -R'-NH 2，其中R'是任选地包含杂原子的二价脂族烃基自由基，两个胺官能团被Y分开的碳原子，Y在 10和20; 应理解二胺（b）不同于二胺（c）。