公开(公告)号：US20140323743A1

公开(公告)日：2014-10-30

申请号：US14356969

申请日：2012-11-06

Applicant: Rohm and Haas Company

Inventor： Charles J. Rand ,  Barry Weinstein ,  C. Damien Rodowski

IPC: C08F220/08

CPC classification number: C08F220/08 ,  C08F2/38

Abstract: The present invention provides hypophosphite (co)telomers of methacrylic anhydride having a weight average molecular weight of from 1,000 to 20,000, and having, on average, at least one phosphorus atom bound to two carbon atoms, and at least one carboxylic acid or salt group.

Abstract translation: 本发明提供重均分子量为1,000〜20,000的甲基丙烯酸酐的次亚磷酸酯（共）调聚物，并且平均具有至少一个结合至两个碳原子的磷原子和至少一个羧酸或盐基团 。

公开(公告)号：US20180340045A1

公开(公告)日：2018-11-29

申请号：US15534143

申请日：2015-12-09

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Charles J. Rand ,  Ryan J. DePuit ,  William J. Harris ,  Thomas Oswald ,  C. Damien Rodowski ,  Jeffrey D. Weinhold

IPC: C08G81/02 ,  C08F220/08 ,  C08F222/40

Abstract: The present invention provides polymer compositions of one or more phosphorus acid group containing, polymers of six-membered cyclic methacrylic acid imide comprising a backbone polymer having one or more one methacrylic acid in polymerized form or its salt, quaternary ammonium group, ester side chain group or amide side chain group, wherein the backbone polymers comprise from 60 to 100 wt. %, based on the total weight of monomers used to make the backbone polymer, of total methacrylic acid polymerized units, regardless of their form, and wherein a total of from 7.5 to 95 wt. %, or, preferably, less than 70 wt. % of the methacrylic acid polymerized units comprise methacrylic anhydride groups or six-membered cyclic methacrylic imide groups. The polymer can be readily tailored to boost modulus and modify surface energies when added to polymers like polyolefins, and to make them compatible with other polymers, like polyamide.

公开(公告)号：US09365657B2

公开(公告)日：2016-06-14

申请号：US13644832

申请日：2012-10-04

Applicant: Rohm and Haas Company

Inventor： Charles J. Rand ,  C. Damien Rodowski ,  Barry Weinstein

IPC: C08F2/38 ,  C08F20/08 ,  C08F220/06 ,  C08F220/08 ,  C04B24/26 ,  C08G81/02 ,  C04B103/32 ,  C04B103/40

CPC classification number: C08F2/38 ,  C04B24/2647 ,  C04B2103/32 ,  C04B2103/408 ,  C08F20/08 ,  C08F220/06 ,  C08F220/08 ,  C08F2500/24 ,  C08G81/025 ,  Y10T428/2982

Abstract: The present invention provides compositions comprising particles or agglomerates of one or more telomer or cotelomer ((co)telomer) of one or more methacrylic acids or anhydrides having a mean average particle size of from 2 μm to 1 mm, preferably from 5 to 500 μm. In addition, the present invention provides methods comprising aqueous solution addition polymerizing a monomer mixture of one or more methacrylic acid in the presence of a heteroatom containing compound, drying the resulting copolymer at a temperature of from 120 to 230° C. and reducing its particle size to make a (co)telomer particle or agglomerate; the methods may further comprise reacting the (co)telomer particle or agglomerate with one or more polyether polyol, alkyl polyether polyol, polyether amine or alkyl polyether amine, with heating, to form a comb polymer useful, e.g. as a superplasticizer or dispersant.

Abstract translation: 本发明提供一种包含一种或多种平均粒度为2μm至1mm，优选5至500μm的甲基丙烯酸或酸酐的一种或多种调聚物或调色剂（（共）调聚物）的颗粒或附聚物的组合物 。 此外，本发明提供了在含杂原子的化合物的存在下将水溶液加成聚合一种或多种甲基丙烯酸的单体混合物的方法，在120-230℃的温度下干燥得到的共聚物并还原其颗粒 调整颗粒或团聚体的大小; 所述方法还可以包括使（共）调聚剂颗粒或附聚物与一种或多种聚醚多元醇，烷基聚醚多元醇，聚醚胺或烷基聚醚胺反应加热，以形成有用的例如， 作为超增塑剂或分散剂。

公开(公告)号：US09193867B2

公开(公告)日：2015-11-24

申请号：US13901627

申请日：2013-05-24

Applicant: Rohm and Haas Company

Inventor： William Christopher Finch ,  Haksu Lee ,  Charles J. Rand ,  C. Damien Rodowski ,  Barry Weinstein

IPC: C08L79/02 ,  C09J103/02 ,  C08L3/02

CPC classification number: C08L79/02 ,  C08L3/02 ,  C09J103/02 ,  Y10T428/249921

Abstract: The present invention provides thermosetting aqueous binder compositions comprising one or more reducing sugar, one or more diprimary diamine or poly(primary amine), and from 7 to 45 wt. %, based on total solids, of one or more polysaccharide having a dextrose equivalent (DE) value of from 5 to 30. The compositions provide treated articles, such as fiberglass mat. The binders provide articles having a dramatically reduced binder weight loss upon cure and a reduction in cure energy needed to achieve early dry strength.

Abstract translation: 本发明提供包含一种或多种还原糖，一种或多种二原子二胺或聚（伯胺）的热固性水性粘合剂组合物和7至45wt。 基于总固体含有一种或多种葡萄糖当量（DE）值为5至30的多糖的组合物提供经处理的制品，例如玻璃纤维垫。 粘合剂提供在固化时具有显着降低的粘合剂重量损失并且实现实现早期干燥强度所需的固化能力降低的制品。

公开(公告)号：US09175121B2

公开(公告)日：2015-11-03

申请号：US14353821

申请日：2012-10-25

Applicant: Rohm and Haas Company

Inventor： William C. Finch ,  Sudhir M. Mulik ,  C. Damien Rodowski ,  Barry Weinstein

IPC: C08F220/28 ,  C08F8/14 ,  C08F8/44 ,  C08F120/06

CPC classification number: C08F220/28 ,  C08F8/14 ,  C08F2220/285 ,  C08F8/44 ,  C08F120/06

Abstract: The present invention provides aqueous compositions comprising β-hydroxy propyl gamma-polyoxyalkylene ether functional resins chosen from (poly)oxyalkylene ether β-hydroxy propyl (meth)acrylates, maleates and itaconates, water soluble copolymers thereof, and mixtures thereof. The water soluble copolymers are comb polymers and (meth)acrylate, maleate and itaconate monomer resins can be addition polymerized to form comb polymers suitable for many uses, such as superplasticizers, dispersants, detergents and floor care compositions. In addition, the present invention provides methods of making the resins by reacting in water or aqueous solvent one or more reactant a) a glycidyl polyether or glycidyl ether, optionally having an alkyl or aryl end group with one or more reactant b) a carboxylate anion containing vinyl compound or polymer, preferably a polymer such as poly(meth)acrylic acid. The methods enable simple formation of comb polymers.

Abstract translation: 本发明提供包含选自（聚）氧化烯醚和（ - ）羟基丙基（甲基）丙烯酸酯，马来酸酯和衣康酸酯，其水溶性共聚物和它们的混合物的β-羟基丙基γ-聚氧化烯醚官能树脂的含水组合物。 水溶性共聚物是梳状聚合物，（甲基）丙烯酸酯，马来酸酯和衣康酸酯单体树脂可加成聚合以形成适用于许多用途的梳状聚合物，如超增塑剂，分散剂，洗涤剂和地板护理组合物。 此外，本发明提供了通过在水或水性溶剂中反应制备所述树脂的方法，一种或多种反应物a）任选具有烷基或芳基端基的缩水甘油醚或缩水甘油醚与一种或多种反应物b）羧酸根阴离子 含有乙烯基化合物或聚合物，优选聚合物如聚（甲基）丙烯酸。 该方法能够简单地形成梳状聚合物。

公开(公告)号：US20150093952A1

公开(公告)日：2015-04-02

申请号：US14501638

申请日：2014-09-30

Applicant: Rohm and Haas Company

Inventor： William C. Finch ,  Michael D. Kelly ,  Sudhir M. Mulik ,  C. Damien Rodowski

IPC: C09D161/24 ,  B05D3/00

CPC classification number: B05D3/007 ,  B32B17/04 ,  C08J5/043 ,  C08L33/02 ,  C08L61/24 ,  Y10T442/2959 ,  C08L33/14

Abstract: The present invention provides methacrylic acid polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g. for roofing shingles, wherein the methacrylic acid polymer comprises the reaction product of at least 50 wt. %, based on the total weight of monomers used to make the methacrylic acid polymer, of methacrylic acid or its salts, or mixtures thereof, a water-soluble phosphorous or sulfur containing compound and the remainder of a carboxylic acid group containing monomer, such as acrylic acid. The methacrylic acid polymers have at least one of a phosphite group, hypophosphite group, phosphinate group, diphosphinate group, and/or sulfonate group and enable modified UF resins to have early strength development even when the binder compositions comprise from 0.1 to less than 5 wt. % of the polymer modifier, based on total solids of the UF resin and the polymer modifier.

Abstract translation: 本发明提供甲基丙烯酸聚合物改性的含水尿素甲醛树脂（UF树脂）粘合剂组合物，其可用于制备经处理的玻璃垫，例如 对于屋顶瓦片，其中所述甲基丙烯酸聚合物包含至少50wt。 ％，基于用于制备甲基丙烯酸聚合物的单体的总重量，甲基丙烯酸或其盐或其混合物，水溶性含磷或含硫化合物和其余含羧酸基团的单体，例如 丙烯酸。 甲基丙烯酸聚合物具有亚磷酸酯基，次磷酸酯基，次膦酸酯基，二亚膦酸酯基和/或磺酸酯基中的至少一种，并且使得改性的UF树脂即使当粘合剂组合物包含0.1至小于5wt 。 基于UF树脂和聚合物改性剂的总固体的聚合物改性剂的％。

公开(公告)号：US20140303317A1

公开(公告)日：2014-10-09

申请号：US14353821

申请日：2012-10-25

Applicant: ROHM AND HAAS COMPANY

Inventor： William C. Finch ,  Sudhir M. Mulik ,  C. Damien Rodowski ,  Barry Weinstein

IPC: C08F220/28

CPC classification number: C08F220/28 ,  C08F8/14 ,  C08F2220/285 ,  C08F8/44 ,  C08F120/06

Abstract: The present invention provides aqueous compositions comprising β-hydroxy propyl gamma-polyoxyalkylene ether functional resins chosen from (poly)oxyalkylene ether β-hydroxy propyl (meth)acrylates, maleates and itaconates, water soluble copolymers thereof, and mixtures thereof. The water soluble copolymers are comb polymers and (meth)acrylate, maleate and itaconate monomer resins can be addition polymerized to form comb polymers suitable for many uses, such as superplasticizers, dispersants, detergents and floor care compositions. In addition, the present invention provides methods of making the resins by reacting in water or aqueous solvent one or more reactant a) a glycidyl polyether or glycidyl ether, optionally having an alkyl or aryl end group with one or more reactant b) a carboxylate anion containing vinyl compound or polymer, preferably a polymer such as poly(meth)acrylic acid. The methods enable simple formation of comb polymers.

Abstract translation: 本发明提供包含选自（聚）氧化烯醚和（ - ）羟基丙基（甲基）丙烯酸酯，马来酸酯和衣康酸酯，其水溶性共聚物和它们的混合物的β-羟基丙基γ-聚氧化烯醚官能树脂的含水组合物。 水溶性共聚物是梳状聚合物，（甲基）丙烯酸酯，马来酸酯和衣康酸酯单体树脂可加成聚合以形成适用于许多用途的梳状聚合物，如超增塑剂，分散剂，洗涤剂和地板护理组合物。 此外，本发明提供了通过在水或水性溶剂中反应制备所述树脂的方法，一种或多种反应物a）任选具有烷基或芳基端基的缩水甘油醚或缩水甘油醚与一种或多种反应物b）羧酸根阴离子 含有乙烯基化合物或聚合物，优选聚合物如聚（甲基）丙烯酸。 该方法能够简单地形成梳状聚合物。