公开(公告)号：US09175121B2

公开(公告)日：2015-11-03

申请号：US14353821

申请日：2012-10-25

Applicant: Rohm and Haas Company

Inventor： William C. Finch ,  Sudhir M. Mulik ,  C. Damien Rodowski ,  Barry Weinstein

IPC: C08F220/28 ,  C08F8/14 ,  C08F8/44 ,  C08F120/06

CPC classification number: C08F220/28 ,  C08F8/14 ,  C08F2220/285 ,  C08F8/44 ,  C08F120/06

Abstract: The present invention provides aqueous compositions comprising β-hydroxy propyl gamma-polyoxyalkylene ether functional resins chosen from (poly)oxyalkylene ether β-hydroxy propyl (meth)acrylates, maleates and itaconates, water soluble copolymers thereof, and mixtures thereof. The water soluble copolymers are comb polymers and (meth)acrylate, maleate and itaconate monomer resins can be addition polymerized to form comb polymers suitable for many uses, such as superplasticizers, dispersants, detergents and floor care compositions. In addition, the present invention provides methods of making the resins by reacting in water or aqueous solvent one or more reactant a) a glycidyl polyether or glycidyl ether, optionally having an alkyl or aryl end group with one or more reactant b) a carboxylate anion containing vinyl compound or polymer, preferably a polymer such as poly(meth)acrylic acid. The methods enable simple formation of comb polymers.

Abstract translation: 本发明提供包含选自（聚）氧化烯醚和（ - ）羟基丙基（甲基）丙烯酸酯，马来酸酯和衣康酸酯，其水溶性共聚物和它们的混合物的β-羟基丙基γ-聚氧化烯醚官能树脂的含水组合物。 水溶性共聚物是梳状聚合物，（甲基）丙烯酸酯，马来酸酯和衣康酸酯单体树脂可加成聚合以形成适用于许多用途的梳状聚合物，如超增塑剂，分散剂，洗涤剂和地板护理组合物。 此外，本发明提供了通过在水或水性溶剂中反应制备所述树脂的方法，一种或多种反应物a）任选具有烷基或芳基端基的缩水甘油醚或缩水甘油醚与一种或多种反应物b）羧酸根阴离子 含有乙烯基化合物或聚合物，优选聚合物如聚（甲基）丙烯酸。 该方法能够简单地形成梳状聚合物。

公开(公告)号：US20150159000A1

公开(公告)日：2015-06-11

申请号：US14563069

申请日：2014-12-08

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Charles J. Rand ,  William C. Finch ,  Thomas P. Clark

IPC: C08L5/00

CPC classification number: C08B30/18 ,  C08L3/02 ,  C09D103/02 ,  C09J103/02

Abstract: The present invention provides thermosetting aqueous binder compositions comprising a diprimary amine or poly(primary amine) and one or more water soluble oxidized dextrin made by oxidizing a dextrin having a DE value of from 2 to 25 and having from 2 to 10 millieq CHO/g of dry oxidized dextrin or a larger oxidized dextrin or an oxidized dextrin made by oxidizing a dextrin having a DE value of below 2 and having from 0.25 to 5 millieq CHO/g of dry oxidized dextrin. The aqueous biobased binders provide hot wet tensile strength when heat cured.

Abstract translation: 本发明提供了包含二原子胺或聚（伯胺）和一种或多种水溶性氧化糊精的热固性水性粘合剂组合物，其通过氧化DE值为2至25的糊精和具有2至10毫克CHO / g 的干氧化糊精或通过氧化DE值低于2的糊精和0.25至5毫克CHO / g干氧化糊精制成的较大氧化糊精或氧化糊精。 水性生物基粘合剂在热固化时提供热湿拉伸强度。

公开(公告)号：US20150093952A1

公开(公告)日：2015-04-02

申请号：US14501638

申请日：2014-09-30

Applicant: Rohm and Haas Company

Inventor： William C. Finch ,  Michael D. Kelly ,  Sudhir M. Mulik ,  C. Damien Rodowski

IPC: C09D161/24 ,  B05D3/00

CPC classification number: B05D3/007 ,  B32B17/04 ,  C08J5/043 ,  C08L33/02 ,  C08L61/24 ,  Y10T442/2959 ,  C08L33/14

Abstract: The present invention provides methacrylic acid polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g. for roofing shingles, wherein the methacrylic acid polymer comprises the reaction product of at least 50 wt. %, based on the total weight of monomers used to make the methacrylic acid polymer, of methacrylic acid or its salts, or mixtures thereof, a water-soluble phosphorous or sulfur containing compound and the remainder of a carboxylic acid group containing monomer, such as acrylic acid. The methacrylic acid polymers have at least one of a phosphite group, hypophosphite group, phosphinate group, diphosphinate group, and/or sulfonate group and enable modified UF resins to have early strength development even when the binder compositions comprise from 0.1 to less than 5 wt. % of the polymer modifier, based on total solids of the UF resin and the polymer modifier.

Abstract translation: 本发明提供甲基丙烯酸聚合物改性的含水尿素甲醛树脂（UF树脂）粘合剂组合物，其可用于制备经处理的玻璃垫，例如 对于屋顶瓦片，其中所述甲基丙烯酸聚合物包含至少50wt。 ％，基于用于制备甲基丙烯酸聚合物的单体的总重量，甲基丙烯酸或其盐或其混合物，水溶性含磷或含硫化合物和其余含羧酸基团的单体，例如 丙烯酸。 甲基丙烯酸聚合物具有亚磷酸酯基，次磷酸酯基，次膦酸酯基，二亚膦酸酯基和/或磺酸酯基中的至少一种，并且使得改性的UF树脂即使当粘合剂组合物包含0.1至小于5wt 。 基于UF树脂和聚合物改性剂的总固体的聚合物改性剂的％。

公开(公告)号：US20140303317A1

公开(公告)日：2014-10-09

申请号：US14353821

申请日：2012-10-25

Applicant: ROHM AND HAAS COMPANY

Inventor： William C. Finch ,  Sudhir M. Mulik ,  C. Damien Rodowski ,  Barry Weinstein

IPC: C08F220/28

CPC classification number: C08F220/28 ,  C08F8/14 ,  C08F2220/285 ,  C08F8/44 ,  C08F120/06

Abstract: The present invention provides aqueous compositions comprising β-hydroxy propyl gamma-polyoxyalkylene ether functional resins chosen from (poly)oxyalkylene ether β-hydroxy propyl (meth)acrylates, maleates and itaconates, water soluble copolymers thereof, and mixtures thereof. The water soluble copolymers are comb polymers and (meth)acrylate, maleate and itaconate monomer resins can be addition polymerized to form comb polymers suitable for many uses, such as superplasticizers, dispersants, detergents and floor care compositions. In addition, the present invention provides methods of making the resins by reacting in water or aqueous solvent one or more reactant a) a glycidyl polyether or glycidyl ether, optionally having an alkyl or aryl end group with one or more reactant b) a carboxylate anion containing vinyl compound or polymer, preferably a polymer such as poly(meth)acrylic acid. The methods enable simple formation of comb polymers.

Abstract translation: 本发明提供包含选自（聚）氧化烯醚和（ - ）羟基丙基（甲基）丙烯酸酯，马来酸酯和衣康酸酯，其水溶性共聚物和它们的混合物的β-羟基丙基γ-聚氧化烯醚官能树脂的含水组合物。 水溶性共聚物是梳状聚合物，（甲基）丙烯酸酯，马来酸酯和衣康酸酯单体树脂可加成聚合以形成适用于许多用途的梳状聚合物，如超增塑剂，分散剂，洗涤剂和地板护理组合物。 此外，本发明提供了通过在水或水性溶剂中反应制备所述树脂的方法，一种或多种反应物a）任选具有烷基或芳基端基的缩水甘油醚或缩水甘油醚与一种或多种反应物b）羧酸根阴离子 含有乙烯基化合物或聚合物，优选聚合物如聚（甲基）丙烯酸。 该方法能够简单地形成梳状聚合物。

公开(公告)号：US20180327310A1

公开(公告)日：2018-11-15

申请号：US15770980

申请日：2016-10-24

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Ann E. Evans ,  William C. Finch ,  Miroslav Janco ,  Sudhir M. Mulik ,  Margarita Perello ,  Marc Schmitz

IPC: C04B24/26 ,  C04B24/06 ,  C04B28/06 ,  C04B40/02

CPC classification number: C04B24/2652 ,  C04B7/02 ,  C04B14/06 ,  C04B24/06 ,  C04B24/2641 ,  C04B24/2676 ,  C04B24/2688 ,  C04B28/06 ,  C04B40/029 ,  C04B2103/0062 ,  C04B2103/12 ,  C04B2111/00801 ,  C04B2111/27 ,  C04B20/0076 ,  C04B22/143 ,  C04B24/383 ,  C04B40/065

Abstract: The present invention provides two-component compositions for making a waterproofing membrane comprising as component A) one or more acrylic aqueous emulsion copolymerization product (copolymer) of (i) from 60 to 89.9 wt. % of one or more nonionic (meth)acrylic monomers, preferably, butyl acrylate, methyl acrylate or ethylhexyl (meth)acrylate, (ii) from 10 to 40 wt. % of one or more vinyl aromatic monomers, (iii) from 0.1 to 2.0 wt. % of one or more amide functional acrylic monomer, and mixtures thereof with itaconic acid or methacrylic acid, wherein the emulsion copolymer has at least one residue of an ascorbic acid reducing agent and of t-butyl hydroperoxide and has less than 40 ppm or, preferably, less than 20 ppm, or more preferably, less than 10 ppm, of residual (meth)acrylamide.

公开(公告)号：US09962731B2

公开(公告)日：2018-05-08

申请号：US14501638

申请日：2014-09-30

Applicant: Rohm and Haas Company

Inventor： William C. Finch ,  Michael D. Kelly ,  Sudhir M. Mulik ,  C. Damien Rodowski

IPC: C08K5/00 ,  B05D3/00 ,  C08J5/04 ,  C08L61/24 ,  B32B17/04 ,  C08L33/02

CPC classification number: B05D3/007 ,  B32B17/04 ,  C08J5/043 ,  C08L33/02 ,  C08L61/24 ,  Y10T442/2959 ,  C08L33/14

Abstract: The present invention provides methacrylic acid polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g. for roofing shingles, wherein the methacrylic acid polymer comprises the reaction product of at least 50 wt. %, based on the total weight of monomers used to make the methacrylic acid polymer, of methacrylic acid or its salts, or mixtures thereof, a water-soluble phosphorous or sulfur containing compound and the remainder of a carboxylic acid group containing monomer, such as acrylic acid. The methacrylic acid polymers have at least one of a phosphite group, hypophosphite group, phosphinate group, diphosphinate group, and/or sulfonate group and enable modified UF resins to have early strength development even when the binder compositions comprise from 0.1 to less than 5 wt. % of the polymer modifier, based on total solids of the UF resin and the polymer modifier.

公开(公告)号：US20230174771A1

公开(公告)日：2023-06-08

申请号：US17923000

申请日：2021-07-23

Applicant: Rohm and Haas Company

Inventor： Sudhir M. Mulik ,  William C. Finch ,  C. Damien Rodowski

IPC: C08L61/24 ,  D04H1/4218 ,  D04H1/587 ,  D04H1/645

CPC classification number: C08L61/24 ,  D04H1/4218 ,  D04H1/587 ,  D04H1/645 ,  D10B2101/06

Abstract: The present invention provides modified urea formaldehyde (UF) resin binder compositions and mineral fiber mats having an emulsion polymer modifier comprising, in copolymerized form, from 5 to 25 wt. % of co polymerized carboxylic acid functional monomers. The emulsion polymers have a measured glass transition temperature (DSC) ranging from −40° C. to 70° C. and a large average particle size. Further, the emulsion polymers comprise less than 30% of the copolymerized acid in neutralized form and do not excessively thicken aqueous compositions containing them. The modified UF resin binder compositions enable good dilution stability in use and high tensile strength in products containing them.

公开(公告)号：US10899666B2

公开(公告)日：2021-01-26

申请号：US15773593

申请日：2016-11-18

Applicant: Rohm and Haas Company

Inventor： William C. Finch ,  Mike McGinnis ,  Sudhir M. Mulik ,  Charles J. Rand

IPC: C04B24/24 ,  C04B24/26 ,  C08F120/06 ,  C08F2/38 ,  C08F2/02 ,  C08G81/02 ,  C04B103/32

Abstract: The present invention provides efficient methods to form a high solids content polymeric polyacid or a comb polymer useful as a superplasticizer or dispersant which comprise heating to from 80 to 100 C. for a first time period, and then, sequentially, heating to a second temperature of from 150 to 250° C. for a second time period a wet reaction mixture having a solids content of from 80 to 99 wt. % and comprising from 15 to 60 wt. % of one or more ethylenically unsaturated acid or a salt thereof, from 37 to 76.99 wt. % of one or more polyether polyols, alkyl polyether polyols, polyether amines or alkyl polyether amines in the presence of (i) from 0.01 to 1 wt. %, of one or more water soluble radical initiators or redox pairs and (ii) from 2 to 22 wt. % of one or more phosphorus oxide containing compounds, all weights based on the total weight of the wet reaction mixture.

公开(公告)号：US20180298534A1

公开(公告)日：2018-10-18

申请号：US15762581

申请日：2016-10-24

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Silvia Isabel Endres ,  William C. Finch ,  Drew E. Williams

IPC: D04H1/587 ,  C08L3/02 ,  C08L5/00 ,  C08L5/02 ,  D04H1/64

Abstract: According to the present invention, curable aqueous compositions provide excellent wet tensile strength and comprise (i) one or more polyacid, (ii) a mixture of two or more polyols including pentaerythritol, (iii) a carbohydrate, such as a starch, and (iv) from 0.5 to 12 wt. %, based on total solids, of one or more azetidinium group containing polyamidoamine resins. The compositions are useful in providing fibrous articles, such as heat resistant nonwovens.

公开(公告)号：US20170356134A1

公开(公告)日：2017-12-14

申请号：US15526781

申请日：2015-11-20

Applicant: Rohm and Haas Company

Inventor： Charles J. Rand ,  William C. Finch ,  C. Damien Rodowski ,  Drew E. Williams

IPC: D21C9/00 ,  D21H17/37 ,  D21H17/53 ,  D21H17/38 ,  D21H17/10 ,  D21H15/00

CPC classification number: D21C9/005 ,  D21C9/002 ,  D21C9/007 ,  D21H15/00 ,  D21H17/10 ,  D21H17/37 ,  D21H17/38 ,  D21H17/53

Abstract: The present invention provides aqueous compositions for treating fluff pulp comprising (i) one or more acrylic acid polymers containing phosphinate groups and having a weight average molecular weight of from 1,000 to 6,000 and (ii) from 5 to 50 wt. %, based on the total solids weight of the aqueous compositions, of one or more polyethylene glycols, having a formula weight of from 150 to 7,000, or, preferably, from 200 to 600. The present invention also provides individualized, intrafiber crosslinked cellulosic fibers comprising the cellulosic fiber and, in cured form, the aqueous compositions, as well as methods of making the individualized, intrafiber crosslinked cellulosic fibers.