公开(公告)号：US5321077A

公开(公告)日：1994-06-14

申请号：US962953

申请日：1992-10-16

申请人： John E. Hayes ,  Robert G. Gastinger

发明人： John E. Hayes ,  Robert G. Gastinger

IPC分类号： C08G18/63 ,  C08G18/72 ,  C08G81/02 ,  C08L71/02 ,  C08L75/08

CPC分类号： C08G18/728 ,  C08G18/636 ,  C08G81/025

摘要： A polymer polyol composition comprising a continuous phase, a disperse phase within the continuous phase, and a dispersant to enhance the stability of the polymer polyol is disclosed. The dispersant is a grafted polyol-polyacrylate dispersant comprised of a isocyanate vinyl monomer/ethylenically unsaturated monomer random copolymer and a polyoxyalkylene polyether, wherein the random copolymer and the polyoxyalkylene polyether are connected through at least one urethane graft site.Methods of preparing the polymer polyol composition and the grafted polyol-polyacrylate dispersant are provided. The polymer polyol compositions have low viscosities as well as high stability and may be prepared with high levels of dispersed vinyl polymer and high styrene:acrylonitrile ratios in the dispersed vinyl polymer. The polymer polyol compositions are useful for the preparation of polyurethanes, particularly polyurethane foams.

摘要翻译： 公开了一种包含连续相，连续相内的分散相和增强聚合物多元醇稳定性的分散剂的聚合物多元醇组合物。 分散剂是由异氰酸酯乙烯基单体/烯键式不饱和单体无规共聚物和聚氧化烯聚醚组成的接枝多元醇 - 聚丙烯酸酯分散剂，其中无规共聚物和聚氧化烯聚醚通过至少一个氨基甲酸酯移植部位连接。 提供了制备聚合物多元醇组合物和接枝多元醇 - 聚丙烯酸酯分散剂的方法。 聚合物多元醇组合物具有低粘度和高稳定性，并且可以在分散的乙烯基聚合物中以高含量的分散的乙烯基聚合物和高苯乙烯：丙烯腈比制备。 聚合物多元醇组合物可用于制备聚氨酯，特别是聚氨酯泡沫。

公开(公告)号：US5250581A

公开(公告)日：1993-10-05

申请号：US588648

申请日：1990-09-26

申请人： Robert G. Gastinger ,  John E. Hayes ,  Philippe C. Motte

发明人： Robert G. Gastinger ,  John E. Hayes ,  Philippe C. Motte

IPC分类号： C08F2/44 ,  C08F283/00 ,  C08F283/02 ,  C08F283/06 ,  C08F291/08 ,  C08G18/63 ,  C08G101/00 ,  C08G18/50 ,  C08G18/28

CPC分类号： C08G18/638 ,  C08F283/00 ,  C08F291/08 ,  C08G2101/00

摘要： Novel polymer polyols based on halogenated aromatic monomers such as tribromostyrene give polyurethane foams with improved flame retardant properties. For example, replacing conventional SAN polymer polyols with tribromostyrene (TBS)/acrylonitrile polymer polyols allows the preparation of polyurethane foams passing British Standard 5852, Part 2, Ignition Source 5 Combustion Test and having better ASTM E-906 values without the need for solid fillers such as melamine or aluminum trihydrate, although these and other flame retardant additives may be optionally employed as well. Elimination of these fillers also provides other improvements such as superior strength and better compression set properties. The TBS dispersions may also be used in conjunction with melamine to eliminate the need for liquid fire retardant additives.

公开(公告)号：US5194493A

公开(公告)日：1993-03-16

申请号：US789215

申请日：1991-11-07

申请人： John E. Hayes ,  Robert G. Gastinger

发明人： John E. Hayes ,  Robert G. Gastinger

IPC分类号： C08G18/63 ,  C08G18/72 ,  C08G81/02

CPC分类号： C08G18/728 ,  C08G18/636 ,  C08G81/025

摘要： A polymer polyol composition comprising a continuous phase, a disperse phase within the continuous phase, and a dispersant to enhance the stability of the polymer polyol is disclosed. The dispersant is a grafted polyol-polyacrylate dispersant comprised of a isocyanate vinyl monomer/ethylenically unsaturated monomer random copolymer and a polyoxyalkylene polyether, wherein the random copolymer and the polyoxyalkylene polyether are connected through at least one urethane graft site.Methods of preparing the polymer polyol composition and the grafted polyol-polyacrylate dispersant are provided. The polymer polyol compositions have low viscosities as well as high stability and may be prepared with high levels of dispersed vinyl polymer and high styrene:acrylonitrile ratios in the dispersed vinyl polymer. The polymer polyol compositions are useful for the preparation of polyurethanes, particularly polyurethane foams.

摘要翻译： 公开了一种包含连续相，连续相内的分散相和增强聚合物多元醇稳定性的分散剂的聚合物多元醇组合物。 分散剂是由异氰酸酯乙烯基单体/烯键式不饱和单体无规共聚物和聚氧化烯聚醚组成的接枝多元醇 - 聚丙烯酸酯分散剂，其中无规共聚物和聚氧化烯聚醚通过至少一个氨基甲酸酯移植部位连接。 提供了制备聚合物多元醇组合物和接枝多元醇 - 聚丙烯酸酯分散剂的方法。 聚合物多元醇组合物具有低粘度和高稳定性，并且可以在分散的乙烯基聚合物中以高含量的分散的乙烯基聚合物和高苯乙烯：丙烯腈比制备。 聚合物多元醇组合物可用于制备聚氨酯，特别是聚氨酯泡沫。

公开(公告)号：US5021506A

公开(公告)日：1991-06-04

申请号：US226347

申请日：1988-07-29

申请人： Robert G. Gastinger ,  John E. Hayes

发明人： Robert G. Gastinger ,  John E. Hayes

IPC分类号： C08L51/08 ,  C08G18/08 ,  C08G18/48 ,  C08G18/63 ,  C08L25/06 ,  C08L25/12 ,  C08L35/06 ,  C08L71/02 ,  C08L75/00

CPC分类号： C08G18/636 ,  C08G18/638

摘要： A stable, low viscosity polymer polyol composition comprising a continuous phase, a disperse phase within the continuous phase, and a dispersant for enhancing the stability of the resultant polymer polyol is disclosed. In one embodiment, the dispersant is formed by polymerizing at least one acrylate monomer in a polyether polyol to form a single phase homogeneous liquid intermediate reaction product which is transesterified to form a polyol polyacrylate dispersant.

公开(公告)号：US4891395A

公开(公告)日：1990-01-02

申请号：US198035

申请日：1988-05-24

申请人： Robert G. Gastinger ,  John E. Hayes

发明人： Robert G. Gastinger ,  John E. Hayes

IPC分类号： C08F283/06 ,  C08F2/18 ,  C08F2/20 ,  C08G18/58 ,  C08G18/63

CPC分类号： C08G18/636

摘要： Very low viscosity polymer polyols having high styrene/acrylonitrile ratios and good stability may be achieved by the use of epoxy resin-modified polyols as dispersants. The epoxy resin-modified polyols useful as dispersants may be made by reacting a polyol initiator having an active hydrogen functionality of 3 to 8 and one or more alkylene oxides with an epoxy resin. It is preferred that all of the epoxy resin-modified base polyol dispersant be initially charged to the reactor, along with part of the base polyol. In this invention, the base polyol is a conventional polyol unmodified with epoxy resin. The use of epoxy resin-modified polyols as dispersants results in polymer polyols having higher styrene contents, and improved stability and viscosity properties.

公开(公告)号：US20130261207A1

公开(公告)日：2013-10-03

申请号：US13900814

申请日：2013-05-23

申请人： Jose F. Pazos ,  John E. Hayes

发明人： Jose F. Pazos ,  John E. Hayes

IPC分类号： C08G65/00

CPC分类号： C08G65/002 ,  C08G18/4866 ,  C08G18/632 ,  C08G65/26 ,  C08G65/2663 ,  C08G2101/00

摘要： The present invention provides a process for preparing a polymer polyol (PMPO) by alkoxylating a starter compound(s) having active hydrogen atoms in the presence of a double metal cyanide (DMC) catalyst, radical initiator(s) and optionally PMPO stabilizers and simultaneously polymerizing unsaturated monomer(s) with radical initiator(s). The polymer polyols (PMPOs) made by the inventive process may find use in the preparation of polyurethane foams and elastomers,

摘要翻译： 本发明提供一种通过在双金属氰化物（DMC）催化剂，自由基引发剂和任选的PMPO稳定剂的存在下烷氧基化具有活性氢原子的起始化合物来制备聚合物多元醇（PMPO）的方法，同时 用自由基引发剂聚合不饱和单体。 通过本发明方法制备的聚合物多元醇（PMPO）可用于制备聚氨酯泡沫和弹性体，

公开(公告)号：US20080090966A1

公开(公告)日：2008-04-17

申请号：US11546882

申请日：2006-10-12

申请人： John E. Hayes ,  Albert Magnotta ,  Nigel Barksby

发明人： John E. Hayes ,  Albert Magnotta ,  Nigel Barksby

IPC分类号： C08F8/30

CPC分类号： C08J5/043 ,  C08G18/4812 ,  C08G18/4816 ,  C08G18/4866 ,  C08G18/7664 ,  C08J2375/04

摘要： The present invention provides a reaction system for the preparation of a fiber reinforced composite according to the pultrusion process made from continuous fiber reinforcing material and an immiscible polyurethane formulation containing a polyisocyanate component including at least one polyisocyanate and an isocyanate-reactive component including at least one isocyanate-reactive compound. The inventive polyurethane formulations and improved pultrusion processes offer better processing and may yield better reinforced composites.

摘要翻译： 本发明提供了一种根据由连续纤维增强材料制成的拉挤成型方法制备纤维增强复合材料的反应体系，以及含有至少一种多异氰酸酯和异氰酸酯反应性组分的多异氰酸酯组分的不混溶性聚氨酯制剂，所述多异氰酸酯组分包括至少一种 异氰酸酯反应性化合物。 本发明的聚氨酯配方和改进的拉挤成型方法提供更好的加工并且可以产生更好的增强复合材料。

公开(公告)号：US20080090921A1

公开(公告)日：2008-04-17

申请号：US11546639

申请日：2006-10-12

申请人： John E. Hayes ,  Albert Magnotta ,  Nigel Barksby

发明人： John E. Hayes ,  Albert Magnotta ,  Nigel Barksby

IPC分类号： C08J9/00

CPC分类号： C08G18/4866 ,  C08G18/246 ,  C08G18/4812 ,  C08G18/4816 ,  C08G18/6677 ,  C08G18/7664 ,  C08K7/02 ,  C08L75/04

摘要： The present invention provides a reaction system for the preparation of a fiber reinforced composite according to the pultrusion process made from continuous fiber reinforcing material and a polyurethane formulation containing a polyisocyanate component including at least one polyisocyanate and an isocyanate-reactive component containing at least one double metal cyanide (“DMC”)-catalyzed polyol. The inventive polyurethane formulations and improved pultrusion processes offer better processing and may yield better reinforced composites.

摘要翻译： 本发明提供了一种根据由连续纤维增强材料制成的拉挤成型方法制备纤维增强复合材料的反应体系，以及含有至少一种多异氰酸酯和含有至少一个双 金属氰化物（“DMC”） - 催化多元醇。 本发明的聚氨酯配方和改进的拉挤成型方法提供更好的加工并且可以产生更好的增强复合材料。

公开(公告)号：US07977501B2

公开(公告)日：2011-07-12

申请号：US11491680

申请日：2006-07-24

申请人： Karl W. Haider ,  Kenneth G. McDaniel ,  John E. Hayes ,  Jianzhong Shen

发明人： Karl W. Haider ,  Kenneth G. McDaniel ,  John E. Hayes ,  Jianzhong Shen

IPC分类号： C07C69/96 ,  C08G64/02 ,  C08G64/32

CPC分类号： C08G64/183 ,  C08G64/32 ,  C08G65/2663

摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.

摘要翻译： 本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001wt。 ％至约0.2wt。 ％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。 ％至约40wt。 ％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。 本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。

公开(公告)号：US20080087373A1

公开(公告)日：2008-04-17

申请号：US11546606

申请日：2006-10-12

申请人： John E. Hayes ,  Nigel Barksby ,  Albert Magnotta

发明人： John E. Hayes ,  Nigel Barksby ,  Albert Magnotta

IPC分类号： B29C70/52

CPC分类号： B29C70/521 ,  B29K2075/00

摘要： The present invention provides a reaction system for the preparation of a fiber reinforced composite according to the pultrusion process made from continuous fiber reinforcing material and a polyurethane formulation made from a polyisocyanate component containing at least one polyisocyanate and an isocyanate-reactive component containing at least one polymer polyol (“PMPO”). The inventive polyurethane formulations and improved pultrusion processes offer better processing and may yield better reinforced composites.

摘要翻译： 本发明提供了一种根据由连续纤维增强材料制成的拉挤成型方法制备纤维增强复合材料的反应体系，以及由含有至少一种多异氰酸酯和含有至少一种 聚合物多元醇（“PMPO”）。 本发明的聚氨酯配方和改进的拉挤成型方法提供更好的加工并且可以产生更好的增强复合材料。