摘要:
A separator, used for a lithium ion secondary battery that produces electromotive force by lithium doping/dedoping, which is composed of a porous film comprising an organic polymer (component A) which can swell in an electrolyte solution to retain it, surrounding a nonwoven fabric which cannot swell in the electrolyte solution, the porous film including an electrolyte solution non-swelling organic polymer with a melting point of 210° C. or above (component B) and an electrolyte solution non-swelling organic polymer with a melting point of 180° C. or below (component C), wherein component B is incorporated in the fiber composing the nonwoven fabric. The separator is highly safe and exhibits low reduction mechanical properties with respect to organic solvents.
摘要:
An example of the present invention is provided with porous sheets 11, 21 each formed by layering a porous base material including a polyolefin and a heat-resistant porous layer including a heat-resistant resin. The porous sheets 11, 21, respectively, are connected at connecting regions 15a and 15b, 25a and 25b, respectively, which have been formed by thermal fusion of the heat-resistant porous layers facing each other by folding the sheets. Furthermore, the porous sheets 11, 21 are additionally connected at a connecting region 27 that has been formed by thermal fusion.
摘要:
The present invention provides a separator for a non-aqueous electrolyte battery that includes a porous base material including a polyolefin and a heat-resistant porous layer provided on at least one surface of the porous base material and including a heat-resistant resin, in which when a thermomechanical analysis measurement has been performed by applying a constant load, the separator for a non-aqueous electrolyte battery satisfies the following conditions (i) and (ii): (i) at least one shrinkage peak appears in a temperature range of from 130 to 155° C. in a displacement waveform representing shrinkage displacement with respect to temperature; and (ii) an extension rate in a range from a shrinkage peak appearance temperature T1 to (T1+20)° C. is less than 0.5%/° C.
摘要:
An example of the present invention is provided with porous sheets 11, 21 each formed by layering a porous base material including a polyolefin and a heat-resistant porous layer including a heat-resistant resin. The porous sheets 11, 21, respectively, are connected at connecting regions 15a and 15b, 25a and 25b, respectively, which have been formed by thermal fusion of the heat-resistant porous layers facing each other by folding the sheets. Furthermore, the porous sheets 11, 21 are additionally connected at a connecting region 27 that has been formed by thermal fusion.
摘要:
A polyolefin microporous membrane, the membrane having, when measured by DSC, a degree of crystallinity of from 65 to 85%, a lamellar crystal/crystal ratio of from 30 to 85%, a crystal length of from 5 nm to 50 nm and an amorphous length of from 3 nm to 30 nm, and a polyolefin microporous membrane, the membrane having, when measured by X-ray diffractometry, crystal size of from 12.5 nm to 13.5 nm and a degree of crystallinity of from 64 to 68%.
摘要:
The present invention provides a polyolefin microporous membrane in which a degree of crystallinity is from 60 to 85%, and a tie molecular volume fraction is from 0.7 to 1.7%.
摘要:
The present invention provides a polyolefin microporous membrane in which a degree of crystallinity is from 60 to 85%, and a tie molecular volume fraction is from 0.7 to 1.7%.
摘要:
A polyolefin microporous membrane, the membrane having, when measured by DSC, a degree of crystallinity of from 65 to 85%, a lamellar crystal/crystal ratio of from 30 to 85%, a crystal length of from 5 nm to 50 nm and an amorphous length of from 3 nm to 30 nm, and a polyolefin microporous membrane, the membrane having, when measured by X-ray diffractometry, crystal size of from 12.5 nm to 13.5 nm and a degree of crystallinity of from 64 to 68%.
摘要:
An object of the invention is to provide a separator for a nonaqueous secondary battery, which has good adhesion to electrodes and is also capable of ensuring sufficient ion permeability even after attachment to electrodes. The separator for a nonaqueous secondary battery of the invention includes a porous substrate and an adhesive porous layer that is formed on at least one side of the porous substrate and contains a polyvinylidene-fluoride-based resin. The separator for a nonaqueous secondary battery is characterized in that the adhesive porous layer has a crystal size of 1 to 13 nm.
摘要:
An object of the invention is to provide a separator for a nonaqueous secondary battery, which has good adhesion to electrodes and is also capable of ensuring sufficient ion permeability even after attachment to an electrode. The separator for a nonaqueous secondary battery of the invention includes a porous substrate and an adhesive porous layer formed on at least one side of the porous substrate and containing a polyvinylidene-fluoride-based resin. The separator for a nonaqueous secondary battery is characterized in that the polyvinylidene-fluoride-based resin has a weight average molecular weight of 600,000 to 3,000,000.