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公开(公告)号：US06818352B2
公开(公告)日：2004-11-16
申请号：US09959538
申请日：2001-10-29
IPC分类号： H01M1044
CPC分类号： H01M10/44 , H01M2/022 , H01M2/14 , H01M2/145 , H01M2/162 , H01M2/1666 , H01M2/1686 , H01M10/0525 , H01M10/0565 , H01M10/4235 , H01M10/448 , H01M2010/4292 , H01M2200/10
摘要： A lithium ion secondary battery including a positive electrode, a negative electrode, a separator and a nonaqueous electrolyte, where the separator essentially includes a porous sheet. The positive electrode active material and the negative electrode active material can be reversibly doped and dedoped such that, where Qp (mAh) is an electric charge necessary for causing total lithium contained in the positive electrode to be dedoped and Qn (mAh) is an electric charge necessary for causing lithium to fully dope the negative electrode, Qp>Qn. Further, when the battery is charged at a charging current Ic (mA) in a range of 0.2 Qn/h
摘要翻译： 一种锂离子二次电池，其包括正极，负极，隔板和非水电解质，其中所述隔板基本上包括多孔片。 正极活性物质和负极活性物质可以被可逆地掺杂和去掺杂，使得其中Qp（mAh）是使包含在正极中的总锂被去除所需的电荷，并且Qn（mAh）是电 使锂充分掺杂负极所需的电荷Qp> Qn。 此外，当电池以0.2Qn / h
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公开(公告)号：US07094497B2
公开(公告)日：2006-08-22
申请号：US10180968
申请日：2002-06-27
IPC分类号： H01M2/16
CPC分类号： H01M2/14 , H01M2/022 , H01M2/145 , H01M2/162 , H01M2/1666 , H01M2/1686 , H01M10/0525 , H01M10/0565 , H01M10/4235 , H01M10/44 , H01M10/448 , H01M2010/4292 , H01M2200/10
摘要： A separator, used for a lithium ion secondary battery that produces electromotive force by lithium doping/dedoping, which is composed of a porous film comprising an organic polymer (component A) which can swell in an electrolyte solution to retain it, surrounding a nonwoven fabric which cannot swell in the electrolyte solution, the porous film including an electrolyte solution non-swelling organic polymer with a melting point of 210° C. or above (component B) and an electrolyte solution non-swelling organic polymer with a melting point of 180° C. or below (component C), wherein component B is incorporated in the fiber composing the nonwoven fabric. The separator is highly safe and exhibits low reduction mechanical properties with respect to organic solvents.
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公开(公告)号：US06881438B2
公开(公告)日：2005-04-19
申请号：US10180969
申请日：2002-06-27
申请人： Takahiro Daido , Satoshi Igarashi , Satoshi Nishikawa , Hiroyuki Honmoto , Hiroyoshi Minematsu , Youji Yanagi , Yasushi Kitagishi
发明人： Takahiro Daido , Satoshi Igarashi , Satoshi Nishikawa , Hiroyuki Honmoto , Hiroyoshi Minematsu , Youji Yanagi , Yasushi Kitagishi
CPC分类号： H01M2/145 , H01M2/022 , H01M2/162 , H01M2/1666 , H01M2/1686 , H01M10/052 , H01M10/44
摘要： A process for production of a composite porous film wherein a porous support, of which both sides have been coated with a solution (dope) of an organic polymer compound in a water-soluble organic solvent to form a coated film, is passed through an air gap step and conveyed into a coagulating bath comprising water or a mixture of water with the same solvent as the organic solvent, and is then immersed in the coagulating bath so that the coated film on both surfaces of the porous support directly contact the coagulating bath for coagulation, and is then washed and dried. This production process is suitable for production of non-aqueous secondary battery separators, and yields non-aqueous secondary battery separators with good handling properties and at low cost, whereby the ion permeability, adhesion with electrodes and electrolyte solution retention can be strictly controlled.
摘要翻译： 一种复合多孔膜的制造方法，其中在水溶性有机溶剂中双面涂布有机聚合物化合物的溶液（涂料）以形成涂膜的多孔载体通过空气 间隙步骤，并输送到包含水或与有机溶剂相同溶剂的水的混合物的凝结浴中，然后将其浸入凝固浴中，使得多孔载体两面上的涂膜直接接触凝固浴 凝结，然后洗涤并干燥。 该制造方法适用于非水二次电池隔板的制造，能够得到处理性能好，成本低的非水电解质二次电池隔膜，能够严格控制离子渗透性，与电极的粘附性和电解液保留性。
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4.发明申请Lithium ion secondary battery, separator, battery pack and charging method 审中-公开锂离子二次电池，隔膜，电池组和充电方法公开(公告)号：US20050079406A1
公开(公告)日：2005-04-14
申请号：US10957687
申请日：2004-10-05
IPC分类号： H01M2/02 , H01M2/14 , H01M2/16 , H01M6/50 , H01M10/05 , H01M10/0525 , H01M10/0565 , H01M10/36 , H01M10/42 , H01M10/44 , H01M10/52
CPC分类号： H01M10/44 , H01M2/022 , H01M2/14 , H01M2/145 , H01M2/162 , H01M2/1666 , H01M2/1686 , H01M10/0525 , H01M10/0565 , H01M10/4235 , H01M10/448 , H01M2010/4292 , H01M2200/10
摘要： A lithium ion secondary battery including a positive electrode, a negative electrode, a separator and a nonaqueous electrolyte, where the separator essentially includes a porous sheet. The positive electrode active material and the negative electrode active material can be reversibly doped and dedoped such that, where Qp (mAh) is an electric charge necessary for causing total lithium contained in the positive electrode to be dedoped and Qn (mAh) is an electric charge necessary for causing lithium to fully dope the negative electrode, Qp>Qn. Further, when the battery is charged at a charging current Ic (mA) in a range of 0.2 Qn/h Qp.
摘要翻译： 一种锂离子二次电池，其包括正极，负极，隔板和非水电解质，其中所述隔板基本上包括多孔片。 正极活性物质和负极活性物质可以被可逆地掺杂和去掺杂，使得其中Qp（mAh）是使包含在正极中的总锂被去除所需的电荷，并且Qn（mAh）是电 使锂充分掺杂负极所需的电荷Qp> Qn。 此外，当电池以0.2Qn / h
Qp而在负极上产生锂颗粒而开始的。 -
公开(公告)号：US20100143783A1
公开(公告)日：2010-06-10
申请号：US11996675
申请日：2005-07-25
IPC分类号： H01M2/14
CPC分类号： B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2255/10 , B32B2255/26 , B32B2255/28 , B32B2307/306 , B32B2307/724 , B32B2323/00 , B32B2377/00 , B32B2457/00 , B32B2457/10 , B32B2457/16 , B32B2605/00 , H01M2/145 , H01M2/1653 , H01M2/1686 , H01M10/0525 , H01M2300/0094
摘要： This invention provides a separator for a nonaqueous rechargeable battery comprising a composite porous membrane that has both a shutdown function and heat resistance good enough to be effective for the suppression of meltdown, desired in a high-performance nonaqueous rechargeable battery having increased energy density, increased output, and increased size, and can realize a separator for a nonaqueous rechargeable battery having excellent handling properties and ion permeability. The composite porous membrane comprises a polyolefin microporous membrane having an air permeability per thickness of not less than 15 sec/100 cc·μm and not more than 50 sec/100 cc·μm (JIS P 8117) and a membrane thickness of not less than 5 μm and not more than 25 μm and a porous layer formed of poly-m-phenylene isophthalamide covering and integrated with both sides of the polyolefin microporous membrane. The composite porous membrane is characterized in that the composite porous membrane has a thickness of not less than 6 μm and not more than 35 μm and an air permeability (JIS P 8117) of not less than 1.01 times and not more than 2.00 times that of the polyolefine microporous membrane, and the coverage of poly-m-phenylene isophthalamide is not less than 1.0 g/m2 and not more than 4.0 g/m2.
摘要翻译： 本发明提供了一种用于非水可再充电电池的隔膜，其包括复合多孔膜，其具有足够好的关闭功能和耐热性，以有效地抑制熔化，在具有增加的能量密度的高性能非水可再充电电池中是期望的 输出和增加的尺寸，并且可以实现具有优异的处理性能和离子渗透性的非水可再充电电池的隔膜。 复合多孔膜由聚烯烃微多孔膜构成，其膜厚为15sec / 100cc·m以上50sec / 100cc·μm以下（JIS P8117），膜厚不小于 5μm以上且25μm以下，由聚 - 间苯二甲酰间苯二胺形成的多孔层与聚烯烃微多孔膜的两面覆盖并整合。 复合多孔膜的特征在于，复合多孔膜的厚度为6μm以上且35μm以下，透气度（JIS P 8117）为不小于1.01倍且不大于2.00倍 聚烯烃微孔膜和聚间苯二甲酰间苯二胺的覆盖率不小于1.0g / m 2且不大于4.0g / m 2。
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公开(公告)号：US08409747B2
公开(公告)日：2013-04-02
申请号：US11996675
申请日：2005-07-25
IPC分类号： H01M2/14
CPC分类号： B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2255/10 , B32B2255/26 , B32B2255/28 , B32B2307/306 , B32B2307/724 , B32B2323/00 , B32B2377/00 , B32B2457/00 , B32B2457/10 , B32B2457/16 , B32B2605/00 , H01M2/145 , H01M2/1653 , H01M2/1686 , H01M10/0525 , H01M2300/0094
摘要： A nonaqueous secondary battery separator which is a composite porous membrane obtained by integrally covering both sides of a polyolefin microporous membrane having a gas permeability (JIS P8117) of between 15 seconds/100 cc·μm and 50 seconds/100 cc·μm per unit thickness and a film thickness of between 5 μm and 25 μm, with a porous layer composed of polymetaphenylene isophthalamide, and which exhibits both a shutdown function and effective heat resistance for meltdown resistance, as features desired for high-energy-density, high-output, large-sized, high-performance nonaqueous secondary batteries, while also having excellent handleability and ion permeability. The film thickness of the composite porous membrane is between 6 μm and 35 μm, the gas permeability (JIS P8117) is between 1.01 and 2.00 times that of the polyolefin microporous membrane, and the polymetaphenylene isophthalamide coating amount is between 1.0 g/m2 and 4.0 g/m2.
摘要翻译： 一种非水二次电池隔膜，其是通过将透气度（JIS P8117）为15秒/ 100cc·m〜50秒/ 100cc·μm的聚烯烃微多孔膜的两面整体地覆盖而得到的复合多孔膜 并且膜厚度在5μm和25μm之间，具有由聚邻亚苯基间苯二酰胺组成的多孔层，并且其具有断裂功能和耐熔融性的有效耐热性，作为高能量密度，高产量所需的特征， 大型高性能非水二次电池，同时具有优异的可操作性和离子透过性。 复合多孔膜的膜厚为6μm〜35μm，透气度（JIS P8117）为聚烯烃微多孔膜的1.01〜2.00倍，聚邻苯二甲酰间苯二胺的涂布量为1.0g / m 2〜4.0 g / m2。
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公开(公告)号：US20050277026A1
公开(公告)日：2005-12-15
申请号：US10524880
申请日：2003-08-21
IPC分类号： H01M2/14 , H01M2/16 , H01M4/131 , H01M4/133 , H01M4/36 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M10/0525 , H01M10/0567 , H01M10/36 , H01M10/42 , H01M4/48
CPC分类号： H01M2/16 , H01M2/145 , H01M2/1613 , H01M2/162 , H01M4/131 , H01M4/133 , H01M4/364 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0567 , H01M10/4235
摘要： A non-aqueous secondary battery separator composed of a porous film made of an organic polymer, which includes a network-like support, swells in the electrolyte solution and retains the electrolyte solution, wherein the network-like support has a mean film thickness of 10-30 μm, a basis weight of 6-20 g/m2, a Gurley value of no greater than 10 sec/100 cc, a McMullin number (25° C.) of no greater than 10 and a (McMullin number×mean film thickness (μm)) product of no greater than 200 μm, and the separator has a mean film thickness of 10-35 μm, a basis weight of 10-25 g/m2 and a Gurley value of no greater than 60 sec/100 cc, or exceeding 60 sec/100 cc and no greater than 500 sec/100 cc. Both battery characteristics and safety are achieved by establishing a specific electrochemical relationship between the effective active substance content of the battery system and the overcharge-preventing function characteristic values.
摘要翻译： 由包含网状载体的由有机聚合物制成的多孔膜构成的非水二次电池隔膜在电解液中溶胀并保持电解质溶液，其中网状载体的平均膜厚度为10 -30μm，基重为6-20g / m 2，Gurley值不大于10sec / 100cc，McMullin号（25℃）不大于10 和不大于200μm的（McMullin数量薄膜（母体））产品，隔膜的平均膜厚度为10-35μm，基重为10-25g / m 2 / >和不大于60秒/ 100cc，或超过60秒/ 100cc且不大于500秒/ 100cc的古利值。 通过建立电池系统的有效活性物质含量与过充电防止功能特征值之间的特定电化学关系，可实现电池特性和安全性。
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公开(公告)号：US20110023963A1
公开(公告)日：2011-02-03
申请号：US12922996
申请日：2009-03-19
申请人： Shogo Ishizuka , Shigeru Niki , Nobuaki Kido , Hiroyuki Honmoto
发明人： Shogo Ishizuka , Shigeru Niki , Nobuaki Kido , Hiroyuki Honmoto
IPC分类号： H01L31/032 , H01L31/18
CPC分类号： H01L31/03923 , Y02E10/541 , Y02P70/521
摘要： There is provided a solar cell in which a lower electrode layer, a photoelectric conversion layer having a chalcopyrite structure that includes a Group Ib element, a Group IIIb element, and a Group VIb element, and an upper electrode layer are sequentially formed on top of a substrate, wherein the solar cell is provided with a silicate layer between the substrate and the lower electrode layer.
摘要翻译： 提供了一种太阳能电池，其中下电极层，具有包含第Ib族元素，IIIb族元素和VIb族元素的黄铜矿结构的光电转换层和上电极层依次形成在 衬底，其中所述太阳能电池在所述衬底和所述下电极层之间设置有硅酸盐层。
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公开(公告)号：US08921691B2
公开(公告)日：2014-12-30
申请号：US12922996
申请日：2009-03-19
申请人： Shogo Ishizuka , Shigeru Niki , Nobuaki Kido , Hiroyuki Honmoto
发明人： Shogo Ishizuka , Shigeru Niki , Nobuaki Kido , Hiroyuki Honmoto
IPC分类号： H01L31/0336 , H01L31/0392
CPC分类号： H01L31/03923 , Y02E10/541 , Y02P70/521
摘要： There is provided a solar cell in which a lower electrode layer, a photoelectric conversion layer having a chalcopyrite structure that includes a Group Ib element, a Group IIIb element, and a Group VIb element, and an upper electrode layer are sequentially formed on top of a substrate, wherein the solar cell is provided with a silicate layer between the substrate and the lower electrode layer.
摘要翻译： 提供了一种太阳能电池，其中下电极层，具有包含第Ib族元素，IIIb族元素和VIb族元素的黄铜矿结构的光电转换层和上电极层依次形成在 衬底，其中所述太阳能电池在所述衬底和所述下电极层之间设置有硅酸盐层。
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