公开(公告)号：US4239873A

公开(公告)日：1980-12-16

申请号：US863695

申请日：1977-12-23

申请人： Sebastiano Cesca ,  Alberto Greco ,  Guglielmo Bertolini ,  Mario Bruzzone

发明人： Sebastiano Cesca ,  Alberto Greco ,  Guglielmo Bertolini ,  Mario Bruzzone

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F110/00 ,  C08F4/02 ,  C08F10/02

CPC分类号： C08F110/00

摘要： An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (2) the combination product of a transition metal chloride and titanium trichloride, supported on a previously chlorinated material such as chlorinated .gamma.-alumina having a high superficial area.

摘要翻译： 在由（1）属于周期性系统的前三组之一的金属的烷基卤化物，烷基衍生物或氢化物的催化剂体系的存在下聚合乙烯等α-烯烃，（2） 过渡金属氯化物和三氯化钛的组合产物，负载在具有高表面积的预先氯化的材料如氯化γ-氧化铝上。

公开(公告)号：US4197420A

公开(公告)日：1980-04-08

申请号：US911921

申请日：1978-06-02

申请人： Giuseppe Ferraris ,  Aldo Priola ,  Sebastiano Cesca

发明人： Giuseppe Ferraris ,  Aldo Priola ,  Sebastiano Cesca

IPC分类号： C08F4/00 ,  B01J31/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/22 ,  C07C2/26 ,  C07C2/30 ,  C07C5/03 ,  C07C9/00 ,  C07C11/02 ,  C07C67/00 ,  C08F4/42 ,  C08F10/00 ,  C07C3/21

CPC分类号： C07C9/00 ,  C07C2/22 ,  C07C2/30 ,  C07C5/03 ,  C08F10/00 ,  C07C2527/08 ,  C07C2531/14

摘要： Oligomers are obtained from straight-chain alpha olefins by contacting these with a catalytic system of the binary type, which is composed of an organic metallic compound of aluminum and a haloid acid. Subsequent hydrogenation of the oligomers is carried out in order to remove possible residual unsaturations.

摘要翻译： 通过使它们与由铝和卤代酸的有机金属化合物组成的二元型催化体系接触，从直链α-烯烃获得低聚物。 进行低聚物的随后氢化以除去可能的残余不饱和度。

公开(公告)号：US4107417A

公开(公告)日：1978-08-15

申请号：US503600

申请日：1974-09-06

申请人： Aldo Priola ,  Sebastiano Cesca ,  Giuseppe Ferraris

发明人： Aldo Priola ,  Sebastiano Cesca ,  Giuseppe Ferraris

IPC分类号： C08F10/10 ,  C08F4/64 ,  C08F4/60 ,  C08F210/12 ,  C08F236/04

CPC分类号： C08F10/10

摘要： A process is described whereby homopolymers and copolymers of isobutylene are prepared by effecting the polymerization at a temperature in the range of -100.degree. to 30.degree. C in the presence of a catalyst system including:(a) a compound selected from the group consisting of: AlCl.sub.3, AlBr.sub.3, AlEtCl.sub.2, TiCl.sub.4, SnCl.sub.4, SiCl.sub.4, VCl.sub.4, BF.sub.3, Al.sub.2 Et.sub.3 Cl.sub.3, SbCl.sub.5, SbF.sub.5, FeCl.sub.3, VOCl.sub.3, ZrCl.sub.4, AlI.sub.3, GaCl.sub.3 ; and(b) a compound adapted to react with the compounds of group (a) and selected from the group consisting of: SnR.sub.4, SnRX.sub.3, SrR.sub.4, TiX.sub.2 (OR).sub.2, Ti(OR).sub.4, PbR.sub.4, Ti(OR)X.sub.3, VO(OR).sub.3, Ti(OR).sub.3 X, (C.sub.5 H.sub.5).sub.2 Ti(C.sub.6 H.sub.5).sub.2, (C.sub.5 H.sub.5).sub.2 Ti(CH.sub.3).sub.2, Ti(Acac).sub.4, SnCl.sub.2 (acetate).sub.2 in which R is a hydrocarbon radical with from 1 to 10 carbon atoms and X is a halogen atom.The process is of particular value in the production of butyl rubber through the copolymerization of isobutylene and isoprene.

摘要翻译： 描述了一种方法，其中通过在-100至30℃范围内的温度下，在催化剂体系存在下进行聚合制备异丁烯的均聚物和共聚物，所述催化剂体系包括：

公开(公告)号：US4017553A

公开(公告)日：1977-04-12

申请号：US601186

申请日：1975-08-01

申请人： Sebastiano Cesca ,  Aldo Priola ,  Giuseppe Ferraris

发明人： Sebastiano Cesca ,  Aldo Priola ,  Giuseppe Ferraris

IPC分类号： C08F4/00 ,  B01J31/00 ,  C07C1/00 ,  C07C2/30 ,  C07C11/02 ,  C07C67/00 ,  C08F4/42 ,  C08F4/52 ,  C08F8/00 ,  C08F8/04 ,  C08F10/00 ,  C08F110/00 ,  C07C3/10

CPC分类号： C08F110/00 ,  C07C2/30 ,  C08F8/04 ,  C07C2527/06 ,  C07C2531/02 ,  C07C2531/14 ,  Y10S585/952

摘要： The invention relates to the preparation of oligomers starting from linear alpha-olefins and to the subsequent hydrogenation thereof to saturated oligomers products, and more particularly to the catalyst system used in the oligomer preparation reaction, the catalyst system consisting of a first component selected amongst the halogenated organo-metal aluminium components, and a second component capable of reacting with the first one and chosen amongst halogens or interhalogenic compounds and metal halides; thus higher yields of oligomers, as well as an easier performance and a control of the reaction are achieved. In turn the hydrogenation step is carried out in the presence of a known hydrogenation catalyst, at a temperature of 150 to 300.degree. C and under a pressure of from 20 to 150 atmospheres.

摘要翻译： 本发明涉及从线性α-烯烃开始制备低聚物，随后将其氢化为饱和低聚物产物，更具体地说，涉及用于低聚物制备反应的催化剂体系，催化剂体系由选自以下的第一组分组成： 卤化有机金属铝组分和能够与第一组分反应并选自卤素或卤代卤化合物和金属卤化物的第二组分; 因此实现了低聚物的更高产率，以及更容易的性能和对反应的控制。 反应氢化步骤在已知的氢化催化剂的存在下，在150至300℃的温度和20至150大气压的压力下进行。

公开(公告)号：US4284526A

公开(公告)日：1981-08-18

申请号：US148975

申请日：1980-05-12

申请人： Sebastiano Cesca ,  Alberto Greco ,  Guglielmo Bertolini ,  Mario Bruzzone

发明人： Sebastiano Cesca ,  Alberto Greco ,  Guglielmo Bertolini ,  Mario Bruzzone

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F110/00 ,  C08F4/02

CPC分类号： C08F110/00

摘要： An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (2) the combination product of a transition metal chloride and titanium trichloride, supported on a previously chlorinated material such as chlorinated .alpha.-alumina having a high superficial area.

摘要翻译： 在由（1）属于周期性系统的前三组之一的金属的烷基卤化物，烷基衍生物或氢化物的催化剂体系的存在下聚合乙烯等α-烯烃，（2） 过渡金属氯化物和三氯化钛的组合产物，负载在预先氯化的材料如具有高表面积的氯化α-氧化铝上。

公开(公告)号：US4151110A

公开(公告)日：1979-04-24

申请号：US781480

申请日：1977-03-25

申请人： Sebastiano Cesca ,  Alberto Greco ,  Guglielmo Bertolini ,  Mario Bruzzone

发明人： Sebastiano Cesca ,  Alberto Greco ,  Guglielmo Bertolini ,  Mario Bruzzone

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F110/00 ,  C08F4/02 ,  C08F4/68

CPC分类号： C08F110/00

摘要： An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (a) the combination product of a transition metal chloride and titanium trichloride said transition metal chloride being derived from the reaction of a transition metal carbonyl and titanium tetrachloride.

摘要翻译： 在由（1）属于周期性系统的前三组之一的金属的烷基卤化物，烷基衍生物或氢化物的催化剂体系的存在下聚合α-烯烃，如（a） 过渡金属氯化物和三氯化钛的组合产物表示过渡金属氯化物是由羰基过渡金属和四氯化钛的反应产生的。

公开(公告)号：US4037041A

公开(公告)日：1977-07-19

申请号：US562800

申请日：1975-03-27

申请人： Sebastiano Cesca ,  Alberto Greco ,  Guglielmo Bertolini ,  Mario Bruzzone

发明人： Sebastiano Cesca ,  Alberto Greco ,  Guglielmo Bertolini ,  Mario Bruzzone

IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/20 ,  C08F4/26 ,  C08F4/60 ,  C08F4/64 ,  C08F4/652 ,  C08F110/00 ,  C08F110/02 ,  C08F10/02

CPC分类号： C08F110/00

摘要： Ethylene is polymerized through the use of an improved catalyst system consisting of a carrier such as neodymium oxide having a high superficial area, an aluminum compound such as triisobutylaluminum and the combination product of titanium trichloride and an isostructural chloride of another transition metal prepared by impregnating the carrier with a solution of a carbonyl derivative of the other transition metal, refluxing the impregnated carrier with titanium tetrachloride until that carbonyl derivative is converted to the chloride of the other transition metal, and then removing the excess of titanium tetrachloride.

摘要翻译： 乙烯通过使用由载体如高表面积的氧化钕，三异丁基铝等铝化合物和三氯化钛的组合产物和另一种过渡金属的结构氯化物组成的改进的催化剂体系进行聚合，所述过渡金属通过浸渍 载体与其他过渡金属的羰基衍生物的溶液，使浸渍的载体与四氯化钛回流，直到羰基衍生物转化为其它过渡金属的氯化物，然后除去过量的四氯化钛。