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11.发明授权Electrolytic ozonizer and method of decomposing ozone-containing waste gas using said ozonizer 失效电解臭氧发生器和使用所述臭氧发生器分解含臭氧废气的方法
公开(公告)号：US5180502A
公开(公告)日：1993-01-19
申请号：US701014
申请日：1991-05-13
IPC分类号： B01D53/86
CPC分类号： B01D53/8675
摘要： The present invention is directed toward an electrolytic ozonier for treating ozone-containing waste gas and a method of treating ozone-containing waste gas using the ozonier, wherein the method includes evolving oxygen and ozone in an anode compartment of an electrolytic cell by electrolysis of water while evolving hydrogen in a cathode compartment; directing the evolved hydrogen into a waste gas treating section that contains a waste gas decomposition catalyst so as to convert the hydrogen to a harmless form by means of the catalyst; bringing the oxygen and ozone into contact with a medium to be treated in an ozone contactor so as to treat the medium; and subsequently directing waste gas containing oxygen and ozone produced as a result of treatment of the medium into the waste gas treating section where they are brought into either direct or indirect contact with the catalyst so that the ozone in the waste gas is converted into a harmless form.
摘要翻译： 本发明涉及一种用于处理含臭氧废气的电解臭氧化物和使用该臭氧臭氧物处理含臭氧废气的方法，其中该方法包括通过电解电解在电解槽的阳极室中放出氧气和臭氧 同时在阴极室中演化氢气; 将放出的氢气导入含有废气分解催化剂的废气处理段，以便通过催化剂将氢转化成无害形式; 使氧气和臭氧与臭氧接触器中要处理的介质接触，以便处理介质; 并且随后将由于处理介质而产生的含有氧气和臭氧的废气引导到废气处理部分中，在那里它们与催化剂直接或间接接触，使得废气中的臭氧转化为无害的 形成。
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公开(公告)号：US5114549A
公开(公告)日：1992-05-19
申请号：US784738
申请日：1991-10-29
摘要： A method and apparatus for water treatment is described, using electrolytic zone, which comprises electrolyzing water to generate an ozone-containing gas in the anode compartment of an electrolytic cell, separating the ozone-containing gas from the anolyte, and contacting the separated ozone-containing gas with the water to be treated said water to be treated being different than the water for electrolysis.
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公开(公告)号：US5015354A
公开(公告)日：1991-05-14
申请号：US349617
申请日：1989-05-10
CPC分类号： C25B9/04 , C02F1/46109 , C25B9/18 , C02F2001/46128 , C02F2201/46115
摘要： A bipolar-electrode electrolytic cell is disclosed, which is to be used in electrolysis of an electrolytic solution having a high electric resistance and including at least two diaphragms positioned to form a plurality of electrode compartments comprising two outer compartments defined between the side walls of the electrolytic cell and the diaphragms positioned closest to the cell walls having a single electrode and at least one electrode compartment having two same-polar electrodes on both sides thereof, each of said electrodes being placed on a diaphragm such that different-polar electrodes are positioned at opposing sides of the diaphragm, wherein the distance between same-polar electrodes within the same compartment is sufficiently large such that electrolysis therebetween does not substantially occur and wherein two of said electrodes at the terminal ends of the series connected electrolytic cell, an anode and a cathode, being further electrically connected to an anode collector and a cathode collector, respectively, and each of the remaining anode electrodes and cathode electrodes is further connected to a different-polar electrode, respectively, which face the same direction and are placed on adjacent diaphragms.
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公开(公告)号：US6165333A
公开(公告)日：2000-12-26
申请号：US419904
申请日：1999-10-18
CPC分类号： C25B11/035 , C25B11/00
摘要： A cathode assembly comprising a cathode, an ion-exchange membrane, and an electroconductive porous member permeable to gas and liquid sandwiched between the cathode and the membrane. The porous member may have, deposited on a part thereof, a catalyst active in hydrogen generation. The porous member preferably is in the form of a plate, sheet, fibers, web, paper, net, or sinter of any of these, and comprises at least a carbonaceous material and has a thickness of from 0.05 to 5 mm and a porosity of from 10 to 95%. Also disclosed is a method of reactivating a cathode assembly, which comprises conducting electrolysis using the cathode assembly until its activity decreases, and then depositing a catalyst active in hydrogen generation on the porous member.
摘要翻译： 一种阴极组件，其包括阴极，离子交换膜和可渗透于阴极和膜之间的气体和液体的导电多孔构件。 多孔构件可以在其一部分上沉积氢生成活性的催化剂。 多孔构件优选为其中任何一种的板，片，纤维，纤维网，纸，网或烧结体的形式，并且至少包含碳质材料，并且具有0.05至5mm的厚度和孔隙率 从10％到95％。 还公开了一种重新激活阴极组件的方法，其包括使用阴极组件进行电解，直到其活性降低，然后在多孔构件上沉积生成氢气的催化剂。
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公开(公告)号：US5589052A
公开(公告)日：1996-12-31
申请号：US759975
申请日：1991-09-17
CPC分类号： C25B1/10 , C25B1/13 , Y02E60/366
摘要： A method and apparatus for water electrolysis is described, using an electrolytic cell comprising an anode compartment, a cathode compartment, and a diaphragm separating the anode and cathode compartments, comprising the steps of electrolyzing water to evolve oxygen or an ozone-containing oxygen gas in the anode compartment and hydrogen in the cathode compartment, thereby resulting in a net transfer of electrolyte from the anode compartment to the cathode compartment through the diaphragm, and recycling electrolyte from the cathode compartment to the anode compartment.
摘要翻译： 描述了一种用于水电解的方法和装置，其使用包括阳极室，阴极室和隔离阳极和阴极室的隔膜的电解池，包括以下步骤：电解水以产生氧气或含臭氧的氧气 阳极室和阴极室中的氢气，从而导致电解质从阳极室经隔膜转移到阴极室，并将电解质从阴极室再循环到阳极室。
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公开(公告)号：US4978438A
公开(公告)日：1990-12-18
申请号：US352427
申请日：1989-05-16
CPC分类号： C02F1/46104 , C02F1/4674 , C02F1/4672 , C02F1/763 , C02F2001/46142 , C02F2201/46115 , C02F2201/46195
摘要： The present invention is directed toward an electrolytic cell for treating fluids with gases that are evolved by electrolysis comprising an anode compartment separated from a cathode compartment by a diaphragm, and a gas-permeable and liquid-impermeable window formed in the anode and the cathode compartment, or formed in the anode or the cathode compartment, wherein the window is formed such that a gas evolved in the anode or cathode compartment or gases evolved in these two compartments are allowed to pass through the window to make contact with a fluid to be treated, said fluid being located outside said electrolytic cell, thereby treating the fluid.
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公开(公告)号：US4927800A
公开(公告)日：1990-05-22
申请号：US276703
申请日：1988-11-28
CPC分类号： C25B11/16 , C25B1/13 , C25B11/0478 , C25B9/10
摘要： An electrode catalyst comprising a lead dioxide electrically deposited layer, the layer having particles containing .beta.-lead dioxide powder dispersed therein, and a method for producing the electrode catalyst are disclosed. The particles contain .beta.-lead dioxide powder and optionally an electrolytic cocatalyst selected from PTFE, agar, gelatin, a perfluoro ion exchange resin and the like. The present electrode catalyst is useful for production of ozone by electrolysis of water and for production of peroxides by electrolysis of aqueous solutions.
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公开(公告)号：US4900419A
公开(公告)日：1990-02-13
申请号：US213047
申请日：1988-06-29
CPC分类号： C25B11/0484
摘要： A cathode for electrolysis, particularly of a sodium chloride aqueous solution by an ion-exchange membrane method, and a process for producing the same, the cathode comprising a conductive base having a nickel surface and having provided thereon (a) at least one platinum group component selected from the group consisting of a platinum group metal, a platinum group metal oxide, and a platinum group metal hydroxide, and (b) at least one cerium component selected from the group consisting of cerium, cerium oxide, and cerium hydroxide, retaining a markedly reduced hydrogen overpotential for an extended period of time and exhibiting excellent resistance to impurities in the electrolytic solution.
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公开(公告)号：US4173525A
公开(公告)日：1979-11-06
申请号：US926775
申请日：1978-07-21
摘要： An electrolytic cell for electrolysis of sea water comprisinga housing having an opening at the bottom and top of the housing for in-flow of sea water and out-flow of electrolyzed sea water, respectively;a plurality of flat plate-like anodes vertically disposed in the housing with the major surface area of the anodes being parallel to the flow of sea water through the cell;a plurality of flat plate-like cathodes vertically disposed in the housing with the major surface area of the cathodes being parallel to the flow of sea water through the cell;an outwardly projecting portion for passing an electric current provided at the lower side edge of each of the anodes;an outwardly projecting portion for passing an electric current provided at the upper side edge of each of the cathodes;an electric current-passing plate secured to the lower portion of the housing and connected to the portions for passing an electric current to each of the anodes; andan electric current-passing plate secured to the upper portion of the housing and connected to the portions for passing an electric current to each of the cathodes; and whereinthe anodes and the cathodes are alternatingly disposed with respect to each other,the side edges of each of the anodes and the side edges of each of the cathodes, except for the portions for passing an electric current of each of the anodes and each of the cathodes, are spaced from the inner wall of the housing,and each of the flat plate-like cathodes and each of the flat plate-like anodes have an external contour such that the external contour of each of the flat plate-like cathodes, except for the portions for passing an electric current to each of the cathodes, is located inwardly of the external contour of each of the flat plate-like anodes.
摘要翻译： 一种用于海水电解的电解池，包括壳体，该壳体在壳体的底部和顶部具有开口，用于海水的流入和电解海水的流出; 垂直设置在壳体中的多个平板状阳极，阳极的主表面积平行于通过电池的海水流; 垂直设置在壳体中的多个平板状阴极，阴极的主表面积平行于通过电池的海水流; 用于使设置在每个阳极的下侧边缘处的电流通过的向外突出部分; 用于使设置在每个阴极的上侧边缘处的电流通过的向外突出的部分; 电流通过板，其固定到壳体的下部并连接到用于使电流流向每个阳极的部分; 以及电流通过板，其固定到所述壳体的上部并且连接到用于使每个阴极通过电流的部分; 并且其中阳极和阴极相对于彼此交替设置，每个阴极的每个阳极的侧边缘和每个阴极的侧边缘除了用于使每个阳极和每个阳极的电流通过的部分 的阴极与壳体的内壁间隔开，并且每个平板状阴极和每个平板状阳极具有外部轮廓，使得每个平板状阴极的外部轮廓 除了用于使每个阴极通过电流的部分位于每个平板状阳极的外部轮廓的内侧。
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