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11.
公开(公告)号:US20160264474A1
公开(公告)日:2016-09-15
申请号:US15064436
申请日:2016-03-08
Applicant: TDK CORPORATION
Inventor: Toshihiko KANEKO , Tatsuya FUJINO , Takeru YOSHIDA , Haruki EBINA , Nobuto MORIGASAKI
IPC: C04B35/468 , H01G4/12
CPC classification number: C04B35/4682 , C04B35/465 , C04B35/47 , C04B35/488 , C04B35/49 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3236 , C04B2235/3239 , C04B2235/3248 , C04B2235/3249 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3418 , C04B2235/5454 , C04B2235/6025 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/6584 , C04B2235/6588 , C04B2235/768 , C04B2235/79 , C04B2237/68 , H01G4/1209 , H01G4/1227 , H01G4/1236 , H01G4/1245 , H01G4/30
Abstract: A dielectric ceramic composition and a ceramic electric device having a dielectric layer composed of the dielectric ceramic composition including a main component having a perovskite crystal structure expressed by general formula ABO3, an oxide of Eu, an oxide of Ra (Sc, Er, Tm, Yb and Lu), an oxide of Rb (Y, Dy, Ho, Tb and Gd) and an oxide of Si, in which 0.075≦α≦0.5, 0.5≦β≦3, 1.0≦γ≦4, 1.5≦δ≦5, and 0.030≦α/δ≦0.250 where a content of an oxide of Eu is α mole, a content of the oxide of Ra is β mole, a content of the oxide of Rb is γ mole, and a content of the second sub-component is δ mole with respect to 100 moles of the main component.
Abstract translation: 一种电介质陶瓷组合物和陶瓷电气装置,具有由介电陶瓷组合物构成的电介质层,该电介质陶瓷组合物包括具有由通式ABO 3表示的钙钛矿晶体结构的主要成分,Eu的氧化物,Ra(Sc,Er,Tm, Yb和Lu),Rb(Y,Dy,Ho,Tb和Gd)的氧化物和Si的氧化物,其中0.075≤α≤0.5,0.5≤β≤3,1.0≤γ≤4,1.5≤δ≤ 5和0.030≤α/δ≤0.250其中Eu的氧化物的含量为α摩尔,Ra的氧化物的含量为β摩尔,Rb的氧化物的含量为γ摩尔,第二 亚成分相对于100摩尔的主成分为δ摩尔。
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12.
公开(公告)号:US20150274597A1
公开(公告)日:2015-10-01
申请号:US14663160
申请日:2015-03-19
Applicant: TDK CORPORATION
Inventor: Nobuto MORIGASAKI , Takeru YOSHIDA , Tomohisa FUKUOKA , Yuhta MATSUNAGA , Kazuhiro KOMATSU
IPC: C04B35/468
CPC classification number: C04B35/4682 , C04B35/638 , C04B2235/3206 , C04B2235/3215 , C04B2235/3224 , C04B2235/3236 , C04B2235/3239 , C04B2235/3262 , C04B2235/3418 , C04B2235/5445 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/6584 , C04B2235/79 , C04B2235/85 , H01G4/1227
Abstract: A dielectric ceramic composition includes at least dielectric particles having a core-shell structure and segregation particles, a concentration of a rare earth compound in the segregation particle is twice or more than an average concentration of the rare earth compound in a shell part of the dielectric particle having the core-shell structure, an area occupied by the segregation particles is 0.1 to 1.1%, when a maximum particle size of the segregation particle is defined as rbmax, a minimum particle size of the segregation particle is defined as rbmin, and an average particle size of the dielectric particle having the core-shell structure is defined as ra, a relation of rbmax/ra≦2.00 and rbmin/ra≧0.25 is satisfied, and the segregation particles substantially do not include Mg.
Abstract translation: 电介质陶瓷组合物至少包括具有核 - 壳结构和偏析粒子的电介质粒子,偏析粒子中稀土化合物的浓度是电介质的外壳部分中稀土化合物的平均浓度的两倍或更多 具有核 - 壳结构的粒子,由偏析粒子占据的面积为0.1〜1.1%,将分离粒子的最大粒径定义为rbmax时,将分离粒子的最小粒径定义为rbmin,将 具有核 - 壳结构的电介质粒子的平均粒径被定义为ra,满足rbmax / ra≦̸ 2.00和rbmin /ra≥0.25的关系,并且偏析粒子基本上不包括Mg。
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公开(公告)号:US20240177936A1
公开(公告)日:2024-05-30
申请号:US18498794
申请日:2023-10-31
Applicant: TDK CORPORATION
Inventor: Taku MURAKAMI , Nobuto MORIGASAKI , Takuma ARIIZUMI , Yoshitaka NAGASHIMA , Tsubasa AOKI
CPC classification number: H01G4/30 , H01G4/008 , H01G4/012 , H01G4/1227
Abstract: A multilayer electronic device includes an element body including an interior region and an exterior region and a pair of external electrodes. The interior region includes inner dielectric layers and internal electrode layers laminated alternately. The exterior region is disposed outwards from the interior region in a lamination direction. The pair of external electrodes is disposed on a surface of the element body and connected to the internal electrode layers. DRAa DRBb>DRBc are satisfied, where “RA” includes an element having a highest mole ratio among “RE” in the inner dielectric layers of a third region at a center of the interior region in the lamination direction, “RB” includes an element having a highest mole ratio among “RE” in a first region at a center of the exterior region in the lamination direction, and “RA” and “RB” are different from each other.
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公开(公告)号:US20220254568A1
公开(公告)日:2022-08-11
申请号:US17588582
申请日:2022-01-31
Applicant: TDK CORPORATION
Inventor: Taku MURAKAMI , Nobuto MORIGASAKI , Takuma ARIIZUMI , Toshihiko KANEKO , Yasuhiro ITO
IPC: H01G4/12 , H01G4/30 , C04B35/468
Abstract: A dielectric composition includes main-phase particles each including a main component having a perovskite crystal structure represented by a general formula of ABO3. At least a part of the main-phase particles has a core-shell structure. The dielectric composition includes RA, RB, M, and Si. Each of A, B, RA, RB, and M is one or more elements selected from a specific element group. SRA/SRB>CRA/CRB is satisfied, where CRA is an RA content (mol %) to the main component in terms of RA2O3, and CRB is an RB content (mol %) to the main component in terms of RB2O3, in the dielectric composition, and SRA is an average RA content (mol %), and SRB is an average RB content (mol %), in a shell part of the core-shell structure.
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公开(公告)号:US20220246354A1
公开(公告)日:2022-08-04
申请号:US17569617
申请日:2022-01-06
Applicant: TDK CORPORATION
Inventor: Kosuke TAKANO , Toshihiko KANEKO , Nobuto MORIGASAKI , Yasushi KAWASHIMA , Momoyo SASAKI
Abstract: An electronic component includes an element body having a functional layer and an internal electrode layer, and an external electrode formed on a surface of the element body and connected to the internal electrode layer electrically. The chlorine concentration of the element body of the electronic component is 10 ppm or less.
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公开(公告)号:US20200039887A1
公开(公告)日:2020-02-06
申请号:US16511286
申请日:2019-07-15
Applicant: TDK CORPORATION
Inventor: Takuma ARIIZUMI , Toshihiko KANEKO , Nobuto MORIGASAKI , Yasuhiro ITO
IPC: C04B35/47 , C04B35/468 , C04B35/49 , H01G4/12 , H01G4/30 , H01G4/005 , C04B35/628
Abstract: The object of the present invention is to provide a dielectric ceramic composition having even improved insulation specific resistance and highly accelerated lifetime. A dielectric ceramic composition comprising a dielectric particle having a core-shell structure including a main component expressed by a general formula ABO3 (A is Ba and the like; and B is Ti and the like) and a rare earth element component R, in which a shell part of the core-shell structure has an average rare earth element concentration C of 0.3 atom % or more, and a rare earth element concentration gradient S is −0.010 atom %/nm≤S≤0.009 atom %/nm or a rare earth element concentration variation satisfies σ/C≤0.15 (a is a standard deviation of a rare earth element concentration and C is an average rare earth element concentration).
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公开(公告)号:US20190237254A1
公开(公告)日:2019-08-01
申请号:US16230154
申请日:2018-12-21
Applicant: TDK CORPORATION
Inventor: Dan SAKURAI , Toshihiko KANEKO , Nobuto MORIGASAKI , Toshinari TAKAHASHI , Yasuhiro ITO
IPC: H01G4/12 , H01G4/30 , C04B35/468
Abstract: The object of the present invention is to provide a dielectric ceramic composition having good properties, particularly good IR property and high temperature accelerated lifetime.The dielectric ceramic composition of the present invention has a main component made of a perovskite type compound expressed by a compositional formula of (Ba1-x-ySrxCay)m(Ti1-zZrz)O3 (note that, m, x, y, and z of the above compositional formula all represent molar ratios, and each satisfies 0.9≤m≤1.1, 0≤x≤0.5, 0≤y≤0.3, 0≤(x+y)≤0.6, and 0.03≤z≤0.3), anda first sub component made of an oxide of a rare earth element R (note that, R is at least one selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu), whereinthe dielectric ceramic composition includes a dielectric particle and a particle boundary, and the dielectric particle include a complete solid solution particle in which Zr is solid dissolved to the entire dielectric particle,when Za represents a concentration of Zr in the dielectric ceramic composition in case a concentration of Ti atom in the dielectric ceramic composition is deemed to be 100 atom % and when Zb represents an average concentration of Zr in the complete solid solution particle in case a concentration of Ti atom in the complete solid solution particle is deemed to be 100 atom %,0.7
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公开(公告)号:US20220254570A1
公开(公告)日:2022-08-11
申请号:US17590541
申请日:2022-02-01
Applicant: TDK CORPORATION
Inventor: Takuma ARIIZUMI , Taku MURAKAMI , Nobuto MORIGASAKI , Toshihiko KANEKO , Yasuhiro ITO
IPC: H01G4/12 , H01G4/30 , C04B35/468
Abstract: A dielectric composition includes a main phase, first segregation phases, and second segregation phases. The main phase includes a main component having a perovskite crystal structure of ABO3 (A is one or more selected from Ba, Sr, and Ca, and B is one or more selected from Ti, Zr, and Hf). The first segregation phases include RE (one or more selected from rare earth elements), A, Si, Ti, and O. The second segregation phases include RE, A, Ti, and O and do not substantially include Si. 0.10
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公开(公告)号:US20220194859A1
公开(公告)日:2022-06-23
申请号:US17551633
申请日:2021-12-15
Applicant: TDK CORPORATION
Inventor: Dan SAKURAI , Yasuhiro ITO , Nobuto MORIGASAKI , Toshihiko KANEKO , Toshihiro IGUCHI
IPC: C04B35/47
Abstract: A dielectric ceramic composition contains dielectric particles containing a main component represented by a composition formula (Ba1-x-ySrxCay)m(Ti1-zZrz)O3 and grain boundaries present between the dielectric particles. The values of m, x, y, and z in the composition formula are all molar ratios. In the composition formula, 0.9≤m≤1.4, 0≤x
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公开(公告)号:US20190237264A1
公开(公告)日:2019-08-01
申请号:US16250911
申请日:2019-01-17
Applicant: TDK CORPORATION
Inventor: Dan SAKURAI , Toshihiko KANEKO , Nobuto MORIGASAKI , Toshinari TAKAHASHI , Yasuhiro ITO
CPC classification number: H01G4/30 , H01G4/008 , H01G4/1245
Abstract: The object of the present invention is to provide the multilayer ceramic capacitor having no deterioration of dielectric properties even in case an inhibitor of an internal electrode layer is pushed out to a dielectric layer when sintering. The multilayer ceramic capacitor 1 including a capacitor element body 10 comprising a dielectric layer 2 and an internal electrode layer 3 stacked in an alternating manner, wherein when Za represents Zr concentration of an dielectric particle in a center part 6 of the dielectric layer 2 and Zb represents Zr concentration of a dielectric particle near the internal electrode layer, 0
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