公开(公告)号：US08933319B2

公开(公告)日：2015-01-13

申请号：US13223650

申请日：2011-09-01

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Tetsu Kitamura

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Tetsu Kitamura

IPC分类号： H01L31/00 ,  H01L51/00 ,  B82Y10/00 ,  H01L27/30 ,  H01L51/42

CPC分类号： H01L51/0051 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0061 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/4246 ,  H01L51/4253 ,  H01L2251/308 ,  Y10S428/917

摘要： A photoelectric conversion element includes: an electrically conductive thin layer; an organic photoelectric conversion layer containing a compound having a partial structure represented by formula (I) and a fullerene or a fullerene derivative; and a transparent electrically conductive thin layer: X represents O, S or N—R10, R10 represents a hydrogen atom or a substituent, Rx and Ry represent a hydrogen atom or a substituent, with at least one representing an electron-withdrawing group, Rx and Ry may combine to form a ring, R represents a bond (—), a hydrogen atom or a substituent, with at least one being the bond, nr represents an integer of 1 to 4, R's may be the same or different when nr is 2 or more, and R's at the 2- and 3-positions or R's at the 5- and 6-positions may combine with each other to form a ring.

摘要翻译： 光电转换元件包括：导电薄层; 含有具有式（I）表示的部分结构的化合物和富勒烯或富勒烯衍生物的有机光电转换层; 和透明导电薄层：X表示O，S或N-R10，R10表示氢原子或取代基，Rx和Ry表示氢原子或取代基，其中至少一个表示吸电子基团，Rx 和R y可以结合形成环，R表示键（ - ），氢原子或取代基，其中至少一个为键，nr表示1至4的整数，R可以相同或不同，当nr 为2以上，R 3为2-和3-位，R 6为5-和6-位可以相互结合形成环。

公开(公告)号：US08053661B2

公开(公告)日：2011-11-08

申请号：US12358335

申请日：2009-01-23

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Tetsu Kitamura

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Tetsu Kitamura

IPC分类号： H01L25/00 ,  H01L31/11 ,  B32B9/00 ,  B32B9/04 ,  C07D321/00 ,  C07D335/00

CPC分类号： H01L51/0051 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0061 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/4246 ,  H01L51/4253 ,  H01L2251/308 ,  Y10S428/917

摘要： A photoelectric conversion element is provided and includes: an electrically conductive thin layer; an organic photoelectric conversion layer containing a compound having a partial structure represented by the following formula (I) and a fullerene or a fullerene derivative; and a transparent electrically conductive thin layer. X represents O, S or N—R10, R10 represents a hydrogen atom or a substituent, Rx and Ry represent a hydrogen atom or a substituent, with at least one representing an electron-withdrawing group, Rx and Ry may combine to form a ring, R represents a bond (—), a hydrogen atom or a substituent, with at least one being the bond, nr represents an integer of 1 to 4, R's may be the same or different when nr is 2 or more, and R's at the 2- and 3-positions or R's at the 5- and 6-positions may combine with each other to form a ring.

摘要翻译： 提供了一种光电转换元件，包括：导电薄层; 含有具有下述式（I）所示的部分结构的化合物和富勒烯或富勒烯衍生物的有机光电转换层; 和透明导电薄层。 X表示O，S或N-R 10，R 10表示氢原子或取代基，Rx和Ry表示氢原子或取代基，其中至少一个表示吸电子基团，Rx和Ry可以结合形成环 ，R表示键（ - ），氢原子或取代基，至少一个为键，nr表示1〜4的整数，当nr为2以上时，R可以相同或不同，R为 5-和6-位上的2-和3-位或R可以彼此结合形成环。

公开(公告)号：US08513651B2

公开(公告)日：2013-08-20

申请号：US12794220

申请日：2010-06-04

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano

IPC分类号： H01L29/12

CPC分类号： H01L51/4253 ,  B82Y10/00 ,  H01L51/0012 ,  H01L51/0047 ,  H01L51/0053 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0061 ,  Y02E10/549 ,  Y02P70/521

摘要： Provided is a photoelectric conversion device comprising an electrically conductive film, a photoelectric conversion film, and a transparent electrically conductive film, wherein the photoelectric conversion film contains a fullerene or a fullerene derivative and a photoelectric conversion material having an absorption spectrum satisfying at least either the following condition (A) or (B): λM1 Δ|λM2−λL2|  (B) wherein λL1, λL2, λM1 and λM2 are the wavelength at an absorption intensity of ½ of the maximum absorption intensity in the wavelength range of from 400 to 800 nm, each of λL1 and λL2 represents the wavelength in a chloroform solution spectrum when the photoelectric conversion material is dissolved in chloroform, and each of λM1 and λM2 represents the wavelength in a thin-film absorption spectrum of the photoelectric conversion material alone, provided that λL1

摘要翻译： 本发明提供一种光电转换元件，其特征在于，具有导电膜，光电转换膜和透明导电膜，其中，所述光电转换膜含有富勒烯或富勒烯衍生物，以及具有满足以下条件的吸收光谱的光电转换材料： 以下条件（A）或（B）：λM1<λL1和λM2<λL2（A）λM1<λL1和Δ|λM1-λL1|>Δ|λM2-λL2|（B）其中λL1，λL2，λM1和λM2是 在400至800nm的波长范围内，吸收强度为最大吸收强度的1/2的波长，λL1和λL2中的每一个表示当光电转换材料溶解在氯仿中时氯仿溶液光谱中的波长，λM1 λM2表示单独的光电转换材料的薄膜吸收光谱中的波长， 条件是λL1

公开(公告)号：US08378101B2

公开(公告)日：2013-02-19

申请号：US12604582

申请日：2009-10-23

申请人： Kimiatsu Nomura ,  Mitsumasa Hamano

发明人： Kimiatsu Nomura ,  Mitsumasa Hamano

IPC分类号： C07D221/18 ,  H01L51/00

CPC分类号： C07D277/30 ,  C07D401/06 ,  C07D405/06 ,  C07D413/06 ,  C07D417/06 ,  C07D417/14 ,  H01L51/0053 ,  H01L51/0059 ,  H01L51/424

摘要： Provided is an organic semiconductor which is a compound represented by the following formula (I): wherein each of R11, R12, R13, R14 and R15 independently represents a hydrogen atom or a substituent, and each of a pair of R11 and R12 and a pair of R12 and R13 may combine to form a ring, B1 represents a ring structure containing at least one nitrogen atom, and n1 represents an integer of 0 to 2.

摘要翻译： 提供一种有机半导体，它是由下式（I）表示的化合物：其中R11，R12，R13，R14和R15各自独立地表示氢原子或取代基，并且一对R11和R12和 R12和R13可以组合形成环，B1表示含有至少一个氮原子的环结构，n1表示0〜2的整数。

公开(公告)号：US20120298846A1

公开(公告)日：2012-11-29

申请号：US13574969

申请日：2011-02-08

申请人： Kimiatsu Nomura ,  Tetsuro Mitsui

发明人： Kimiatsu Nomura ,  Tetsuro Mitsui

IPC分类号： H01L51/42 ,  H01L31/0232

CPC分类号： C07D223/26 ,  C07D209/86 ,  C07D209/88 ,  C07D219/14 ,  H01L27/14621 ,  H01L27/14623 ,  H01L27/14645

摘要： A photoelectric element includes a conductive layer, an organic photoelectric layer, a blocking layer and a transparent conductive layer, the organic photoelectric layer contains a p type organic photoelectric material having a glass transition temperature of 100° C. or higher and forms an amorphous layer, and the blocking layer contains a blocking material having a glass transition temperature of 140° C. or higher.

摘要翻译： 光电元件包括​​导电层，有机光电层，阻挡层和透明导电层，有机光电层含有玻璃化转变温度为100℃以上的ap型有机光电材料，形成非晶层， 并且阻挡层含有玻璃化转变温度为140℃以上的阻挡材料。

公开(公告)号：US08525577B2

公开(公告)日：2013-09-03

申请号：US12891897

申请日：2010-09-28

申请人： Katsuyuki Yofu ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Tetsuro Mitsui

发明人： Katsuyuki Yofu ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Tetsuro Mitsui

IPC分类号： H01L31/00 ,  H01L29/08 ,  H01L35/24 ,  H01L51/00 ,  C07D209/82 ,  C07D495/02

CPC分类号： H01L51/42 ,  B82Y10/00 ,  C07D333/36 ,  C07D333/56 ,  C07D333/72 ,  C07D409/04 ,  C07D409/06 ,  C07D409/12 ,  C07D495/04 ,  C07D495/14 ,  C09B3/00 ,  C09B23/105 ,  C09B57/008 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/4253 ,  Y02E10/549

摘要： A photoelectric conversion device comprising an electrically conductive film, an organic photoelectric conversion film, and a transparent electrically conductive film, wherein the organic photoelectric conversion film contains a compound represented by the following formula (1) and an n-type organic semiconductor: wherein each of R1 and R2 independently represents a substituted aryl group, an unsubstituted aryl group, a substituted heteroaryl group or an unsubstituted heteroaryl group, each of R3 to R11 independently represents a hydrogen atom or a substituent provided that an acidic group is excluded, m represents 0 or 1, n represents an integer of 0 or more, R1 and R2, R3 and R4, R3 and R5, R5 and R6, R6 and R8, R7 and R8, R7 and R9, or R10 and R11 may be combined each other to form a ring, and when n is an integer of 2 or more, out of a plurality of R7's and R8's, a pair of R7's, a pair of R8's, or a pair of R7 and R8 may be combined each other to form a ring.

公开(公告)号：US08378339B2

公开(公告)日：2013-02-19

申请号：US12877252

申请日：2010-09-08

申请人： Kimiatsu Nomura ,  Eiji Fukuzaki ,  Tetsuro Mitsui

发明人： Kimiatsu Nomura ,  Eiji Fukuzaki ,  Tetsuro Mitsui

IPC分类号： H01L29/08 ,  C07D209/82

CPC分类号： H01L51/0072 ,  B82Y10/00 ,  C09B23/04 ,  C09B57/008 ,  C09B57/10 ,  H01L51/0046 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0094 ,  H01L51/4253 ,  Y02E10/549

摘要： A photoelectric conversion device comprising a transparent electrically conductive film, a photoelectric conversion film and an electrically conductive film in this order, wherein the photoelectric conversion film comprises a photoelectric conversion layer, and an electron blocking layer, wherein the electron blocking layer contains a compound represented by the specific formula.

摘要翻译： 一种光电转换装置，包括透明导电膜，光电转换膜和导电膜，其中光电转换膜包括光电转换层和电子阻挡层，其中电子阻挡层含有表示的化合物 具体公式。

公开(公告)号：US08338691B2

公开(公告)日：2012-12-25

申请号：US12399417

申请日：2009-03-06

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Katsuyuki Yofu

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Katsuyuki Yofu

IPC分类号： H01L31/00 ,  H01L31/042

CPC分类号： H01L51/0032 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0047 ,  H01L51/0059 ,  H01L51/0072 ,  H01L51/424 ,  H01L51/4253

摘要： A photoelectric conversion element is provided and includes: an electrically conductive thin layer; an organic photoelectric conversion layer; and a transparent electrically conductive thin layer. The organic photoelectric conversion layer contains: a compound represented by formula (I); and a fullerene or a fullerene derivative. In the formula, Z1 represents an atomic group necessary for forming a 5- or 6-membered ring, L1, L2 and L3 each independently represents an unsubstituted methine group or a substituted methine group, D1 represents an atomic group, and n represents an integer of 0 or more.

摘要翻译： 提供了一种光电转换元件，包括：导电薄层; 有机光电转换层; 和透明导电薄层。 有机光电转换层包含：式（I）表示的化合物; 和富勒烯或富勒烯衍生物。 在该式中，Z1表示形成5元或6元环所必需的原子团，L1，L2和L3各自独立地表示未取代的次甲基或取代的次甲基，D1表示原子团，n表示整数 为0以上。

公开(公告)号：US20090223566A1

公开(公告)日：2009-09-10

申请号：US12399417

申请日：2009-03-06

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Katsuyuki Yofu

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Katsuyuki Yofu

IPC分类号： H01L31/00

CPC分类号： H01L51/0032 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0047 ,  H01L51/0059 ,  H01L51/0072 ,  H01L51/424 ,  H01L51/4253

摘要： A photoelectric conversion element is provided and includes: an electrically conductive thin layer; an organic photoelectric conversion layer; and a transparent electrically conductive thin layer. The organic photoelectric conversion layer contains: a compound represented by formula (I); and a fullerene or a fullerene derivative. In the formula, Z1 represents an atomic group necessary for forming a 5- or 6-membered ring, L1, L2 and L3 each independently represents an unsubstituted methine group or a substituted methine group, D1 represents an atomic group, and n represents an integer of 0 or more.

摘要翻译： 提供了一种光电转换元件，包括：导电薄层; 有机光电转换层; 和透明导电薄层。 有机光电转换层包含：式（I）表示的化合物; 和富勒烯或富勒烯衍生物。 在该式中，Z1表示形成5元或6元环所必需的原子团，L1，L2和L3各自独立地表示未取代的次甲基或取代的次甲基，D1表示原子团，n表示整数 为0以上。

公开(公告)号：US07442459B2

公开(公告)日：2008-10-28

申请号：US11433286

申请日：2006-05-12

申请人： Masashi Kaneko ,  Kimiatsu Nomura

发明人： Masashi Kaneko ,  Kimiatsu Nomura

IPC分类号： H01M8/10 ,  H01M8/08 ,  B01J49/00

CPC分类号： H01M4/8807 ,  H01M4/8605 ,  H01M4/92 ,  H01M4/926 ,  H01M8/0289 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1072 ,  Y02P70/56

摘要： A solid electrolyte having an aromatic ring in a main chain, wherein a sulfuric acid group bonds to the aromatic ring via a linking group containing a sulfur atom. The solid electrolyte exhibits a high ion conductivity.

摘要翻译： 一种在主链中具有芳香环的固体电解质，其中硫酸基通过含硫原子的连接基与芳环结合。 固体电解质表现出高的离子传导性。