Reversible electrode material
    11.
    发明授权
    Reversible electrode material 失效
    可逆电极材料

    公开(公告)号:US5324599A

    公开(公告)日:1994-06-28

    申请号:US826000

    申请日:1992-01-27

    摘要: The present invention provides an electrode material comprising a combination of a compound having a disulfide group and a conductive polymer, or a conductive polymer having a disulfide group, wherein an S-S bond of the disulfide group is cleaved by the electrolytic reduction to form a sulfur-metal ion bond or a sulfur-proton bond, and the sulfur-metal ion bond or the sulfur-proton bond re-forms an S-S bond by the electrolytic oxidation. The present invention also provides a lithium rechargeable battery comprising a cathode, a solid electrolyte, and an anode, wherein the cathode is made of a composition containing as its main components lithium thiolate having a sulfur-lithium ion bond capable of forming a disulfide bond by the electrolytic oxidation and a .pi. electron conjugated conductive polymer; or a composition containing as its main component a .pi. electron conjugated conductive polymer having a sulfur-lithium ion bond capable of forming a disulfide bond by electrolytic oxidation; the solid electrolyte is a composition containing a salt containing lithium, or a polymer containing the salt; and the anode is made of a composition containing as its main components aluminium or an alloy containing aluminium, and carbon.

    摘要翻译: 本发明提供了包含具有二硫化物的化合物和导电性聚合物的组合的电极材料或具有二硫键的导电性聚合物,其中通过电解还原将二硫键的SS键切割,形成硫 - 金属离子键或硫质子键,硫金属离子键或硫质子键通过电解氧化而重新形成SS键。 本发明还提供一种锂可再充电电池,其包含阴极,固体电解质和阳极,其中阴极由含有能够形成二硫键的硫 - 锂离子键的硫醇锂的组成的组合物制成 电解氧化和π电子共轭导电聚合物; 或含有通过电解氧化形成二硫键的具有硫 - 锂离子键的π电子共轭导电聚合物作为其主要成分的组合物; 固体电解质是含有含锂的盐或含有该盐的聚合物的组合物; 并且阳极由含有铝或含有铝的合金和碳的主要成分的组合物制成。

    Method for charging lithium secondary battery
    12.
    发明授权
    Method for charging lithium secondary battery 有权
    锂二次电池充电方法

    公开(公告)号:US6081097A

    公开(公告)日:2000-06-27

    申请号:US232323

    申请日:1999-01-18

    IPC分类号: H01M10/05 H01M10/44 H02J7/00

    摘要: A method for charging a secondary battery is disclosed. The method comprises the steps of detecting an impedance of the battery; charging the battery with a substantially constant first current having a value smaller than a predetermined current value if the detected impedance of the battery is equal to or greater than a predetermined impedance value; charging the battery with a substantially constant second current having a value equal to or greater than the predetermined current value if the detected impedance is less than the predetermined impedance value; and terminating charging the battery with the first and second constant currents when the closed circuit voltage of the battery reaches a predetermined voltage value.

    摘要翻译: 公开了一种用于对二次电池充电的方法。 该方法包括检测电池的阻抗的步骤; 如果电池的检测阻抗等于或大于预定的阻抗值,则电池具有基本恒定的具有小于预定电流值的值的第一电流; 如果检测到的阻抗小于预定阻抗值,则具有等于或大于预定电流值的基本恒定的第二电流对电池充电; 以及当所述电池的闭路电压达到预定电压值时,以所述第一和第二恒定电流终止所述电池的充电。

    Ion-conductive polymer electrolyte and electrolytic capacitor using the
same
    14.
    发明授权
    Ion-conductive polymer electrolyte and electrolytic capacitor using the same 失效
    离子导电聚合物电解质和电解电容器使用相同

    公开(公告)号:US5526224A

    公开(公告)日:1996-06-11

    申请号:US441519

    申请日:1995-05-15

    IPC分类号: H01G9/02 H01G9/025

    CPC分类号: H01G9/025 H01G9/028

    摘要: A stable ion-conductive polymer electrolyte having a sufficiently high ionic conductivity, which will not be decreased during a long-term storing at a high temperature, and being free from any physical change such as crack, contraction and dissolution, is disclosed. It comprises: at least one polyol selected from the group consisting of an adduct composed of sorbitol and polyethylene oxide and an adduct composed of tetramethylol methane and polyethylene oxide, at least one ammonium salt or morpholinium salt, and at least one organic solvent.

    摘要翻译: 公开了具有足够高的离子传导性的稳定的离子导电聚合物电解质,其在长期高温储存期间不会降低,并且没有任何物理变化如裂纹,收缩和溶解。 它包括:至少一种选自由山梨糖醇和聚环氧乙烷组成的加合物和由四羟甲基甲烷和聚环氧乙烷组成的加合物,至少一种铵盐或吗啉鎓盐和至少一种有机溶剂的多元醇。

    Reversible electrode
    15.
    发明授权
    Reversible electrode 失效
    可逆电极

    公开(公告)号:US5348819A

    公开(公告)日:1994-09-20

    申请号:US55858

    申请日:1993-04-30

    CPC分类号: H01M4/60 H01M6/181

    摘要: A reversible electrode of the present invention is provided, which includes an organic sulfur aromatic compound represented by the formula R(SX).sub.y (where R is an aromatic group, S is sulfur, X is a metal atom or hydrogen, and y is an integer of 2 or more) as a component so as to utilize the reversible electrochemical oxidation-reduction of sulfur atoms of the organic sulfur aromatic compound for an electrode reaction. Moreover, according to the present invention, a method for producing the reversible electrode is provided.

    摘要翻译: 提供本发明的可逆电极,其包括由式R(SX)y表示的有机硫芳族化合物(其中R是芳族基团,S是硫,X是金属原子或氢,y是 2以上的整数)作为成分,以利用有机硫磺芳族化合物的硫原子的可逆电化学氧化还原进行电极反应。 此外,根据本发明,提供了制造可逆电极的方法。

    Method of measuring quantities indicating state of electrochemical device and apparatus for the same
    18.
    发明授权
    Method of measuring quantities indicating state of electrochemical device and apparatus for the same 有权
    测量表示电化学装置状态的量的方法及其装置

    公开(公告)号:US06262577B1

    公开(公告)日:2001-07-17

    申请号:US09397923

    申请日:1999-09-17

    IPC分类号: H01M1046

    CPC分类号: G01R31/3651 G01R31/3675

    摘要: A method of measuring quantities that indicates the state of an electrochemical device having an electrode and an ionic conductor, such as material properties or a residual capacity, without disassembling the device. The quantities are measured by comparing (a) a series of theoretical data of an electrical characteristic of the device obtained by combining at least one of an electron transportation model of the electrode, an ion transportation model of the electrode, an ion conduction model of the ionic conductor and a model of an electrochemical reaction taking place in an interface between the electrode and the ionic conductor, with a potential model of the electrode, with (b) a series of measured data of the electrical characteristic of the electrochemical device.

    摘要翻译: 在不拆卸装置的情况下,测量表示具有电极和离子导体的电化学装置的状态的量的方法,例如材料特性或残余容量。 通过比较(a)通过组合电极的电子传输模型,电极的离子传输模型,电极的离子传导模型中的至少一个获得的器件的电特性的一系列理论数据, 离子导体和在电极和离子导体之间的界面中发生的电化学反应的模型,具有电极的潜在模型,其中(b)电化学装置的电特性的一系列测量数据。

    Composite electrode
    20.
    发明授权
    Composite electrode 失效
    复合电极

    公开(公告)号:US5413882A

    公开(公告)日:1995-05-09

    申请号:US950476

    申请日:1992-09-24

    摘要: A reversible electrode is provided comprising mainly organic disulfide compounds and having applications in such electrochemical devices as batteries, electrochromic displays, sensors, memories, etc. Large current charge/discharge is realized at room temperature with charge/discharge characteristics of excellent reversibility. Its structure is a composition combining organic disulfide compounds with disulfide bonding and conducting polymers. In other words, conducting polymers after being subjected to an electrolysis are put together with organic disulfide compounds. Thus, due to the effect of composition with conducting polymers, the oxidation/reduction reactions of organic disulfide compounds are accelerated and a reversible electrode characterized by utilization of a high energy density of organic disulfide compounds and the possibility of a large current charge/discharge is realized.

    摘要翻译: 提供主要包含有机二硫化物的可逆电极,并且可用于诸如电池,电致变色显示器,传感器,存储器等的电化学装置中。在室温下实现大电流充电/放电,具有极好的可逆性的充电/放电特性。 其结构是结合有机二硫化物与二硫键和导电聚合物的组合物。 换句话说,进行电解后的导电聚合物与有机二硫化物组合在一起。 因此,由于组成与导电聚合物的作用,有机二硫化物化合物的氧化/还原反应加快,特征在于利用有机二硫化物的高能量密度和大电流充电/放电的可能性的可逆电极是 实现了