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公开(公告)号：US4529815A
公开(公告)日：1985-07-16
申请号：US608459
申请日：1984-05-09
IPC分类号： B01J29/00 , B01J29/06 , B01J31/00 , B01J31/26 , C07B61/00 , C07C67/333 , C07C69/533
CPC分类号： C07C67/333
摘要： 4-Pentenoates are prepared by isomerization of isomeric pentenoates in the presence of a catalyst, by a process in which isomeric pentenoates are treated at elevated temperatures with an acidic ion exchanger or acidic zeolite which contains a noble metal of group eight of the periodic table, and the 4-pentenoate is distilled off from the reaction mixture.
摘要翻译： 通过在酸性离子交换剂或包含元素周期表第八族的贵金属的酸性沸石的高温下处理异构戊烯酸酯的方法，在催化剂存在下异构戊烯酸酯制备4-戊烯酸酯， 并从反应混合物中蒸馏出4-戊烯酸酯。
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12.发明授权Purification of carboxylates containing aldehydes, acetals and/or unsaturated compounds 失效含醛，缩醛和/或不饱和化合物的羧酸盐的纯化
公开(公告)号：US4523027A
公开(公告)日：1985-06-11
申请号：US518006
申请日：1983-07-28
CPC分类号： C07C67/60
摘要： Carboxylates which contain aldehydes, acetals and/or unsaturated compounds and are obtained by reacting an olefinically unsaturated compound with carbon monoxide and an alkanol are purified by a process wherein the said carboxylates are treated with hydrogen at elevated temperatures in the presence of an acidic ion exchanger or zeolite doped with one or more metals of group VIII of the periodic table, and the resulting low and/or high boilers are separated off by distillation.
摘要翻译： 通过使烯属不饱和化合物与一氧化碳和链烷醇反应得到的含醛，缩醛和/或不饱和化合物的羧酸盐通过其中所述羧酸盐在酸性离子交换剂存在下在高温下用氢处理的方法进行纯化 或掺杂有周期表第Ⅷ族的一种或多种金属的沸石，并通过蒸馏分离得到的低和/或高沸点。
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公开(公告)号：US4316047A
公开(公告)日：1982-02-16
申请号：US166569
申请日：1980-07-07
IPC分类号： B01J31/00 , C07B61/00 , C07C69/533 , C07C67/38
CPC分类号： C07C69/533
摘要： A process for the preparation of C.sub.1 -C.sub.4 -alkyl pent-3-enoates, wherein butadiene, or a hydrocarbon mixture containing butadiene, either of which contains not more than 0.1% by weight of butynes, is reacted with carbon monoxide and an alkanol of 1 to 4 carbon atoms in the presence of a cobalt carbonyl catalyst and a tertiary nitrogen base, having a pK.sub.A of 3-11, at from 100.degree. to 140.degree. C. under a pressure of from 300 to 1,000 bar.
摘要翻译： 一种制备C 1 -C 4烷基戊-3-烯酸酯的方法，其中丁二烯或含有丁二烯的烃混合物（其中含有不超过0.1重量％的丁炔）与一氧化碳和链烷醇反应 在羰基钴催化剂和叔氮碱的存在下，在300-1000巴的压力下，pKA为3-11，在100-140℃下存在1至4个碳原子。
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公开(公告)号：US4586987A
公开(公告)日：1986-05-06
申请号：US721810
申请日：1985-04-10
申请人： Heinz-Walter Schneider , Rudolf Kummer , Otto Leman , Paul Panitz
发明人： Heinz-Walter Schneider , Rudolf Kummer , Otto Leman , Paul Panitz
CPC分类号： C07C67/54
摘要： C.sub.1 -C.sub.4 -alkyl pentenoates are obtained from reaction mixtures which contain this and which are obtained by reacting butadiene, or a butadiene-containing hydrocarbon mixture, with carbon monoxide and a C.sub.1 -C.sub.4 -alkanol, in the presence of a cobalt carbonyl catalyst and a tertiary nitrogen base at elevated temperatures and under superatmospheric pressure by a process in which(a) the liquid reaction mixture freed from excess carbon monoxide is treated with hydrogen at elevated temperatures and under from 5 to 80 bar,(b) hydrocarbons are distilled off from the resulting liquid reaction mixture,(c) the C.sub.1 -C.sub.4 -alkyl pentenoate, the alkanol and the nitrogen base are then distilled off under reduced pressure, and(d) the C.sub.1 -C.sub.4 -alkyl pentenoate is obtained by fractional distillation from the distillate containing this compound, the alkanol and the tertiary nitrogen base.
摘要翻译： 由含有这一点的反应混合物获得戊烯酸C 1 -C 4烷基酯，其通过使丁二烯或含丁二烯的烃混合物与一氧化碳和C 1 -C 4烷醇在羰基钴催化剂存在下反应获得， 在高温和超大气压下，通过一种方法，（a）在高温和5至80巴下用氢处理脱除过量一氧化碳的液体反应混合物，（b）将烃蒸馏掉， 从所得液体反应混合物中，（c）戊烯酸C 1 -C 4烷基酯，然后在减压下蒸馏除去链烷醇和氮碱，并且（d）戊烯酸C1-C4烷基酯是通过从 含有该化合物的馏出物，链烷醇和叔氮碱。
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公开(公告)号：US4537987A
公开(公告)日：1985-08-27
申请号：US629766
申请日：1984-07-11
IPC分类号： B01J31/00 , B01J31/20 , B01J31/24 , C07B61/00 , C07C67/313 , C07C67/38 , C07C67/39 , C07C69/44 , C07C69/67
CPC分类号： C07C67/39
摘要： Pure monoesters of adipic acid are prepared by a process in which(a) a pentenoate is reacted with carbon monoxide and hydrogen at from 90.degree. to 140.degree. C. and under from 5 to 300 bar in the presence of a carbonyl complex of cobalt or of rhodium, and a 5-formylvalerate is separated off, and(b) the 5-formylvalerate thus obtained is oxidized with molecular oxygen, or with a gas containing this, at from 20.degree. to 100.degree. C. under from 1 to 10 bar.
摘要翻译： 己二酸的纯单酯通过以下方法制备，其中（a）戊烯酸酯与一氧化碳和氢气在90至140℃和5至300巴下在钴或羰基络合物存在下反应 的铑，并分离出5-甲酰基戊酸酯，（b）将所得的5-甲酰基戊酸酯用分子氧或含有该气体的气体在20至100℃下在1至10巴 。
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公开(公告)号：US4360692A
公开(公告)日：1982-11-23
申请号：US205569
申请日：1980-11-10
CPC分类号： C07C67/347 , C07C67/38
摘要： An improved process for the preparation of alkyl formylvalerates, wherein butadiene or a butadiene-containing hydrocarbon mixture is reacted, in a first stage, with carbon monoxide and alkanols in the presence of cobalt carbonyl complexes and, per mole of butadiene, from 0.5 to 2 moles of tertiary nitrogen bases having a pK.sub.a of from 3 to 11, at from 80.degree. to 150.degree. C. and from 300 to 2,000 bar, and, in a second stage, the resulting alkyl pentenoate is reacted with carbon monoxide and hydrogen in the presence of cobalt carbonyl complexes at from 100.degree. to 160.degree. C. and from 100 to 300 bar, the improvement being that tertiary nitrogen bases, excess alkanols and any unconverted hydrocarbons are distilled off from the reaction mixture obtained in the first stage, with the proviso that the reaction mixture is treated, before or during the distillation, with gases containing molecular oxygen, and the residual reaction mixture containing alkyl pentenoate and cobalt catalyst is used in the second stage.
摘要翻译： 一种改进的制备烷基甲酰基戊酸酯的方法，其中丁二烯或含丁二烯的烃混合物在第一阶段中与一氧化碳和链烷醇在钴羰基络合物和每摩尔丁二烯的存在下反应，为0.5至2 具有pKa为3至11，80至150℃和300至2,000巴的叔氮碱的摩尔数，并且在第二阶段中，使得到的戊烯酸烷基酯与一氧化碳和氢气在 在100至160℃和100至300巴存在钴羰基络合物，其改进是从第一阶段获得的反应混合物中蒸馏掉叔氮碱，过量链烷醇和任何未转化的烃， 条件是反应混合物在蒸馏之前或期间用含有分子氧的气体进行处理，并且含有戊烯酸烷基酯和钴催化剂的残余反应混合物用于 第二阶段
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17.发明授权Isolation and regeneration of rhodium-containing catalysts from distillation residues of hydroformylation reactions 失效从加氢甲酰化反应的蒸馏残余物中分离和再生含铑催化剂
公开(公告)号：US4113754A
公开(公告)日：1978-09-12
申请号：US780297
申请日：1977-03-23
IPC分类号： B01J31/40 , B01J38/68 , B01J38/74 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00 , C07F15/00
CPC分类号： B01J31/4046 , B01J31/20 , B01J31/24 , B01J31/2404 , C07C45/50 , B01J2231/321 , B01J2531/822 , Y02P20/582 , Y02P20/584
摘要： The isolation and regeneration of catalysts of type I or IIclRh(CO)(PR.sub.3).sub.2 Ihrh(CO)(PR.sub.3).sub.3 II,where the R's are identical or different hydrocarbon radicals, to give the catalysts in a pure form, is effected by regenerating aqueous rhodium salt solutions, as obtained on treating distillation residues of hydroformylation mixtures with oxygen-containing mineral acids and peroxides, by a method wherein the said aqueous rhodium salt solutions are treated with a cation exchanger, the latter is then separated from the solution, the absorbed rhodium ions are desorbed with hydrochloric acid, the hexachlororhodate solutions, containing hydrochloric acid, are reacted, in the presence of a water-soluble organic solvent and a tertiary phosphine PR.sub.3, with carbon monoxide, or with compounds which eliminate carbon monoxide, at from 0.degree. to 150.degree. C and from 1 to 5 bars, and the resulting complexes I or, if the process is carried out under hydrogenating conditions, the resulting complexes II, are separated off.
摘要翻译： 分离和再生I或II型ClRh（CO）（PR3）2I HRh（CO）（PR3）3II的催化剂，其中R是相同或不同的烃基，得到纯形式的催化剂，是通过 通过其中所述水合铑盐溶液用阳离子交换剂处理的方法，在用含氧无机酸和过氧化物处理加氢甲酰化混合物的蒸馏残余物时获得的再生铑水溶液溶液，然后将该铑盐溶液与溶液分离， 吸收的铑离子用盐酸解吸，含有盐酸的六氯乙酸溶液在水溶性有机溶剂和叔膦PR3存在下与一氧化碳或与一氧化碳消除的化合物反应， 0至150℃和1至5巴，所得的络合物I或如果该方法在氢化条件下进行，则得到的络合物II为sepa 评分。
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18.发明授权
公开(公告)号：US4454358A
公开(公告)日：1984-06-12
申请号：US337683
申请日：1982-01-07
IPC分类号： C07C29/132 , B01J31/00 , B01J31/20 , C07B61/00 , C07C27/00 , C07C27/04 , C07C29/149 , C07C29/80 , C07C29/92 , C07C31/08 , C07C67/00 , B01D3/00
CPC分类号： C07C29/80 , C07C29/149 , C07C67/08 , C07C67/36 , C07C67/54 , Y02P20/52 , Y10S203/06 , Y10S203/20
摘要： Ethanol is produced continuously via the carbonylation of methanol, by(a) carbonylating methanol, in a reactor R, in the presence of a carbonyl complex of a metal of group VIII of the periodic table and of a halogen compound,(b) separating, in a distillation column D1, the reactor discharge, into a top fraction comprising methyl acetate, methanol, dimethyl ether and an organohalogen compound, and into a bottom fraction comprising water, small quantities of acetic acid and the catalyst, if the latter is not in a fixed bed, the residence time being so adjusted that the greater part of the acetic acid reacts with the methanol present to give methyl acetate,(c) separating the top fraction from D1, in a distillation column D2, into a top fraction comprising small quantities of methyl acetate, methanol, dimethyl ether and the organo-halogen compound, and a bottom fraction comprising methyl acetate and methanol, and recycling the top fraction to reactor R,(d) distilling off, via the top of distillation column D3, the greater part of the water from the bottom fraction from D1and removing this water from circulation, and recycling to reactor R the bottom fraction consisting of small quantities of water, acetic acid and the catalyst,(e) using hydrogen to hydrogenate, in the hydrogenation reactor H, the bottom fraction from D2, in a conventional manner, to give a mixture of methanol and ethanol, and(f) separating the mixture into ethanol and methanol in a distillation column D4, and recycling the methanol to reactor R.
摘要翻译： 通过（a）在反应器R中羰基化甲醇，在周期表第VIII族金属的羰基络合物和卤素化合物的存在下，连续生产乙醇，（b）分离， 在蒸馏塔D1中，反应器排出成为包含乙酸甲酯，甲醇，二甲醚和有机卤素化合物的顶级馏分，并进入包含水，少量乙酸和催化剂的底部馏分，如果后者不在 固定床，停留时间如此调节，使得大部分乙酸与存在的甲醇反应得到乙酸甲酯，（c）将蒸馏塔D2中的顶馏分与D1分离成包含小分子的顶馏分 数量的乙酸甲酯，甲醇，二甲醚和有机卤素化合物，以及包含乙酸甲酯和甲醇的底部馏分，并将顶部馏分再循环到反应器R中，（d）通过顶部o蒸馏 f蒸馏塔D3，来自D1的底部馏分的大部分水从循环中除去，并且将反应器R再循环到由少量水，乙酸和催化剂组成的底部馏分，（e）使用氢气 以常规方式在氢化反应器H中将来自D2的塔底馏分氢化，得到甲醇和乙醇的混合物，和（f）将混合物在蒸馏塔D4中分离成乙醇和甲醇，并将甲醇再循环至 反应器
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19.发明授权
公开(公告)号：US4350572A
公开(公告)日：1982-09-21
申请号：US204637
申请日：1980-11-06
CPC分类号： C07C67/60
摘要： A process for purifying carboxylic acid esters which have been obtained by reacting olefinically unsaturated compounds with carbon monoxide and alkanols and which contain aldehydes or acetals, wherein the said esters are treated with a strongly acidic agent, with or without addition of water.
摘要翻译： 通过使烯属不饱和化合物与一氧化碳和链烷醇反应并且含有醛或缩醛而获得的羧酸酯的方法，其中所述酯用强酸性剂处理，或不加入水。
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公开(公告)号：US4305888A
公开(公告)日：1981-12-15
申请号：US813971
申请日：1977-07-08
IPC分类号： C07C55/02 , C07C51/00 , C07C55/10 , C07C55/12 , C07C55/14 , C07C55/16 , C07C55/18 , C07C55/20 , C07C55/21 , C07C67/00 , C07C209/00 , C07C211/09 , C07C87/14
摘要： A process for the manufacture of salts of alkanedicarboxylic acids of 4 to 12 carbon atoms and alkanediamines of 3 to 14 carbon atoms, comprising reacting esters of alkanols of 1 to 4 carbon atoms and alkanedicarboxylic acids of 4 to 12 carbon atoms with alkanediamines of 3 to 14 carbon atoms in stoichiometric amounts in the presence of water at an elevated temperature, with continuous removal of the alkanols formed, in which process the reaction is carried out, from the start, in the presence of the particular salt of alkanedicarboxylic acid and alkanediamine which is to be manufactured.
摘要翻译： 一种制备4至12个碳原子的链烷二羧酸盐和3至14个碳原子的烷二胺的方法，包括使1至4个碳原子的链烷醇与4至12个碳原子的烷基二羧酸酯与3个烷二胺反应 在高温存在下，在水存在下，化学计算量为14个碳原子，连续除去所形成的链烷醇，在该过程中进行反应，从一开始就在特定的烷基二羧酸和烷二胺盐存在下 将被制造。
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