-
公开(公告)号：US07626068B2
公开(公告)日：2009-12-01
申请号：US11786489
申请日：2007-04-11
申请人： Yumin Liu
发明人： Yumin Liu
IPC分类号： C07C5/327
CPC分类号： C07C45/34 , B01J23/76 , B01J23/80 , B01J23/83 , B01J23/8474 , B01J23/8476 , C07C5/48 , C07C45/33 , C07C45/35 , C07C51/25 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/30 , C07C2523/75 , C07C2523/755 , C07C11/02 , C07C47/22 , C07C49/08 , C07C49/10 , C07C47/21 , C07C49/205 , C07C53/08
摘要： Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel-containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), hafnium (Hf), tungsten (W), yttrium (Y), zinc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected from the group consisting of ethane, propane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-fed with the alkane to a reaction zone maintained at a temperature ranging from about 250° C. to about 350° C., and the ethane is oxidatively dehydrogenated to form the corresponding alkene with an alkane conversion of at least about 10% and an alkene selectivity of at least about 70%.
-
公开(公告)号：US07227049B2
公开(公告)日：2007-06-05
申请号：US10719441
申请日：2003-11-20
申请人： Yumin Liu
发明人： Yumin Liu
IPC分类号： C07C5/37
CPC分类号： C07C45/34 , B01J23/76 , B01J23/80 , B01J23/83 , B01J23/8474 , B01J23/8476 , C07C5/48 , C07C45/33 , C07C45/35 , C07C51/25 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/30 , C07C2523/75 , C07C2523/755 , C07C11/02 , C07C47/22 , C07C49/08 , C07C49/10 , C07C47/21 , C07C49/205 , C07C53/08
摘要： Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel-containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), hafnium (Hf), tungsten (W), yttrium (Y), zinc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected from the group consisting of ethane, propane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-fed with the alkane to a reaction zone maintained at a temperature ranging from about 250° C. to about 350° C., and the ethane is oxidatively dehydrogenated to form the corresponding alkene with an alkane conversion of at least about 10% and an alkene selectivity of at least about 70%.
-
公开(公告)号：US06891075B2
公开(公告)日：2005-05-10
申请号：US09815914
申请日：2001-03-22
申请人： Yumin Liu
发明人： Yumin Liu
IPC分类号： B01J23/00 , B01J23/76 , B01J23/80 , B01J23/83 , B01J23/847 , C07C5/48 , C07C45/33 , C07C45/34 , C07C45/35 , C07C5/327 , C07C5/333
CPC分类号： C07C45/34 , B01J23/002 , B01J23/76 , B01J23/80 , B01J23/83 , B01J23/847 , B01J23/8474 , B01J23/8476 , B01J2523/00 , C07C5/48 , C07C45/33 , C07C45/35 , C07C2523/755 , C07C11/02 , C07C47/22 , C07C49/08 , C07C49/10 , C07C49/205 , C07C47/21 , B01J2523/56 , B01J2523/57 , B01J2523/847 , B01J2523/31 , B01J2523/13 , B01J2523/842 , B01J2523/845 , B01J2523/55 , B01J2523/68
摘要： Processes for oxidative dehydrogenation of alkane to one or more olefins, exemplified by ethane to ethylene, are disclosed using novel catalysts. The catalysts comprise a mixture of metal oxides having as an important component nickel oxide (NiO), which give high conversion and selectivity in the process. For example, the catalyst can be used to make ethylene by contacting it with a gas mixture containing ethane and oxygen. The gas mixture may optionally contain ethylene, an inert diluent such as nitrogen, or both ethylene and an inert diluent.
摘要翻译： 使用新型催化剂公开了将烷烃氧化脱氢成一种或多种烯烃的方法，例如乙烷至乙烯。 催化剂包含具有作为重要组分的氧化镍（NiO）的金属氧化物的混合物，其在该过程中具有高的转化率和选择性。 例如，催化剂可用于通过使乙烯与含有乙烷和氧气的气体混合物接触来制备乙烯。 气体混合物可任选地含有乙烯，惰性稀释剂如氮气，或乙烯和惰性稀释剂。
-
14.发明授权公开(公告)号：US06329553B1
公开(公告)日：2001-12-11
申请号：US09709221
申请日：2000-11-10
申请人： Heinz Frei , Fritz Blatter , Hai Sun
发明人： Heinz Frei , Fritz Blatter , Hai Sun
IPC分类号： C07C4504
CPC分类号： C07C45/35 , B01J29/06 , B01J29/084 , B01J29/60 , B01J2229/37 , B01J2229/42 , C07B41/06 , C07B41/14 , C07C45/33 , C07C45/34 , C07C45/36 , C07C45/53 , C07C407/00 , C07C409/04 , C07C409/08 , C07C409/10 , C07C409/14 , C07C2601/02 , C07C2601/04 , C07C2601/14 , C07C2601/18 , C07C49/08 , C07C47/22 , C07C47/54 , C07C49/403 , C07C49/205 , C07C49/78
摘要： A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.
摘要翻译： 一种吸附在沸石基质上的烃的组合选择性热氧化和光氧化的方法。 在暗热条件下或在可见光照射下，在无溶剂沸石中未经取代或烷基取代的烷烃，烯烃，芳族化合物和环烷基的高度组合的选择性热氧化和光氧化。 该方法几乎完全选择性地氧化烃，而不会大量生产副产物。
-
公开(公告)号：US2549508A
公开(公告)日：1951-04-17
申请号：US5482148
申请日：1948-10-15
申请人： STANDARD OIL DEV CO
发明人： MOTTERN HENRY O
IPC分类号： C07C45/73 , C07C45/74 , C07C45/75 , C07C49/203
CPC分类号： C07C49/203 , C07C45/73 , C07C45/74 , C07C45/75 , C07C49/205
-
公开(公告)号：US2267829A
公开(公告)日：1941-12-30
申请号：US23230738
申请日：1938-09-29
发明人： HEINRICH LANGE , OTTO HORN
IPC分类号： C07C45/78
CPC分类号： C07C45/78 , C07C49/205
-
公开(公告)号：US2263379A
公开(公告)日：1941-11-18
申请号：US28958439
申请日：1939-08-11
申请人： DU PONT
IPC分类号： C07C45/27
CPC分类号： C07C45/27 , C07C49/205
-
公开(公告)号：US2158290A
公开(公告)日：1939-05-16
申请号：US16534037
申请日：1937-09-23
发明人： HEINRICH LANGE , OTTO HORN
IPC分类号： C07C45/78
CPC分类号： C07C45/783 , C07C49/205
-
公开(公告)号：US1967225A
公开(公告)日：1934-07-24
申请号：US63053532
申请日：1932-08-26
申请人： DU PONT
发明人： CONAWAY ROLLIN F
IPC分类号： C07C45/26
CPC分类号： C07C45/26 , C07C49/205
-
公开(公告)号：US20070197847A1
公开(公告)日：2007-08-23
申请号：US11786573
申请日：2007-04-11
申请人： Yumin Liu
发明人： Yumin Liu
CPC分类号： C07C45/34 , B01J23/76 , B01J23/80 , B01J23/83 , B01J23/8474 , B01J23/8476 , C07C5/48 , C07C45/33 , C07C45/35 , C07C51/25 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/30 , C07C2523/75 , C07C2523/755 , C07C11/02 , C07C47/22 , C07C49/08 , C07C49/10 , C07C47/21 , C07C49/205 , C07C53/08
摘要： Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel-containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), hafnium (Hf), tungsten (W), yttrium (Y), zinc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected from the group consisting of ethane, propane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-fed with the alkane to a reaction zone maintained at a temperature ranging from about 250° C. to about 350° C., and the ethane is oxidatively dehydrogenated to form the corresponding alkene with an alkane conversion of at least about 10% and an alkene selectivity of at least about 70%.
摘要翻译： 公开了烷烃氧化脱氢的催化剂和方法。 本发明的催化剂通常包括（i）镍或含镍化合物和（ii）钛（Ti），钽（Ta），铌（Nb），铪（Hf），钨（W）中的至少一种或多种 ），钇（Y），锌（Zn），锆（Zr）或铝（Al），或含有这些元素中的一种或多种的化合物。 在优选的实施方案中，催化剂是负载催化剂，烷烃选自乙烷，丙烷，异丁烷，正丁烷和乙基氯，分子氧与烷烃共同进料至维持在温度 范围为约250℃至约350℃，并且乙烷被氧化脱氢以形成相应的烯烃，烷烃转化率为至少约10％，烯烃选择性为至少约70％。
-
-
-
-
-
-
-
-
-
搜索结果
42 条记录 (耗时 0.022 秒)