公开(公告)号：US4780545A

公开(公告)日：1988-10-25

申请号：US931849

申请日：1986-11-18

Applicant: Thomas Meul ,  Leander Tenud ,  Laurent Duc ,  John McGarrity

Inventor： Thomas Meul ,  Leander Tenud ,  Laurent Duc ,  John McGarrity

IPC: C07D207/38 ,  C07D201/02

CPC classification number: C07D207/38

Abstract: 4-Alkoxy-3-pyrrolin-2-on-1-yl acetic acid alkyl esters are intermediate products for the production of cerebrally-active pharmaceutical products. The advantageous process for production of the new intermediate products is described.

Abstract translation: 4-烷氧基-3-吡咯烷-2-酮-1-基乙酸烷基酯是制备脑活性药物产品的中间产物。 描述了生产新中间产品的有利方法。

公开(公告)号：US4111952A

公开(公告)日：1978-09-05

申请号：US745018

申请日：1976-11-26

Applicant: John F. Knifton

Inventor： John F. Knifton

IPC: C07D201/02 ,  C07D207/26

CPC classification number: C07D201/02

Abstract: This invention concerns processes for preparing cyclic, 5-membered ring, lactams through the carbonylation of allylic substrates in the presence of rhodium catalysts.

Abstract translation: 本发明涉及在铑催化剂存在下通过烯丙基底物的羰基化制备环状5元环，内酰胺的方法。

公开(公告)号：US3947406A

公开(公告)日：1976-03-30

申请号：US667061

申请日：1967-09-12

Applicant: Edwin George Edward Hawkins

Inventor： Edwin George Edward Hawkins

IPC: C07D201/02 ,  C07D211/76 ,  C07D273/00 ,  C07D53/06

CPC classification number: C07D201/02 ,  C07C255/00

Abstract: Compounds of formula ##EQU1## where X,X' are divalent aliphatic radicals which may be the same or different are heated to decompose them to lactams.

Abstract translation: 其中X，X'是可以相同或不同的二价脂族基团的式NH XC ANGLE ANGLE CX'OO的化合物被加热以将其分解成内酰胺。

公开(公告)号：US3922254A

公开(公告)日：1975-11-25

申请号：US49043974

申请日：1974-07-22

Applicant: MONSANTO CO

Inventor： HEDRICK ROSS MELVIN ,  GABBERT JAMES D

IPC: C08G69/00 ,  B01J27/00 ,  B01J31/00 ,  C07D201/02 ,  C08G63/82 ,  C08G69/44 ,  C08L23/00 ,  C08L23/16 ,  C08L67/00 ,  C08L77/00 ,  C08G69/16

CPC classification number: C08G63/82 ,  C08G69/44

Abstract: A catalyzed process for the preparation of monomeric and/or polymeric compounds such as esters, polyesters, ester-amides, and polyester-polyamides which result from the reaction of an imide and an alcohol in the presence of a Group IA, IIA, IIB and/or IIIA metal or metal compound, imide-alcohol condensation catalyst.

Abstract translation: 用于制备单体和/或聚合化合物的催化方法，所述单体和/或聚合化合物例如酯，酯，酯 - 酰胺和聚酯 - 聚酰胺，其由IA，IIA，IIB族和IIB族的存在下由酰亚胺和醇反应而产生 /或IIIA金属或金属化合物，酰亚胺 - 醇缩合催化剂。

公开(公告)号：US3836525A

公开(公告)日：1974-09-17

申请号：US7255170

申请日：1970-09-15

Applicant: UBE INDUSTRIES

Inventor： MASAKI M ,  UCHIDA M ,  ODA T ,  YAMAMOTO K

IPC: C07B45/02 ,  C07C303/32 ,  C07D201/02 ,  C07D201/14 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07B45/02 ,  C07C303/32 ,  C07D201/14

Abstract: A PROCESS FOR THE PREPARATION OF LACTAMS AND SULFONIC ACID DERIVATIVES OF ACTIVE HYDROGEN-CONTAINING ORGANIC COMPOUNDS OF THE GROUP CONSISTING OF OXIMES, ALCOHOLS, PHENOLS, THIOLS, PRIMARY AMINES AND SECONDARY AMINES, WHICH COMPRISES REACTING A LACTAM-O-SULFONIC ACID WITH A COMPOUND SELECTED FROM THE SPECIFIED ORGANIC COMPOUNDS UNDER SUBSTANTIALLY ANHYDROUS CONDITIONS.

公开(公告)号：US3654268A

公开(公告)日：1972-04-04

申请号：US3654268D

申请日：1968-12-09

Applicant: BP CHEM INT LTD

Inventor： HAWKINS EDWIN GEORGE EDWARD

IPC: C07D201/02 ,  C07D273/00 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07D273/00

Abstract: CYCLOHEXANONE IS CONVERTED TO 1,1''-PEROXYDICYCLOHEXYLAMINE WHICH IS THEN HEATED IN THE LIQUID PHASE TO PRODUCE CAPROLACTAM AND CYCLOHEXANONE, WHICH CYCLOHEXAMONE IS RECYCLED AS FEED TO THE PROCESS.

公开(公告)号：US3590032A

公开(公告)日：1971-06-29

申请号：US3590032D

申请日：1968-10-07

Applicant: BP CHEM INT LTD

Inventor： HARRIS BRIAN WALTON

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

Abstract: CAPROLACTAM IS PRODUCED BY HEATING TOGETHER 1,1''-PEROXYDICYCLOHEXYLAMINE AND A LITHIUM HALIDE IN A MOLTEN CAPROLACTAM ENVIRONMENT.

公开(公告)号：US3560484A

公开(公告)日：1971-02-02

申请号：US83417369

申请日：1969-06-17

Applicant: TEIJIN LTD

Inventor： TANAKA IKUZO ,  UEHARA HIDEO ,  OSAKI HUKUE ,  YAMAGATA MASAYUKI

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

Abstract: CAPROLACTAM IS PREPARED IN A SINGLE STEP WITHOUT FORMATION OF BY-PRODUCT AMMONIUM SULFATE BY CONTACTING 2-NITROCYCLOHEXANONE AND/OR 2-NITROCYCLOHEXEN-1-O1 WITH HYDROGEN AT A TEMPERATURE RANGING FROM 150* TO 300* C. IN THE PRESENCE OF A LIQUID MEDIUM SUCH AS WATER, ALCOHOLS, ETHERS, BENZENE OR MIXTURES THEREOF AND OF AN ACTIVE HYDROGENATION CATALYST, PERFERABLY IN THE FURTHER PRESENCE OF A NITROGEN-CONTAINING BASIC SUBSTANCE SUCH AS AMMONIA. THIS INVENTION RELATS TO A NOVEL PROCESS FOR THE PREPARATION OF E-CAPROLACTAM.

公开(公告)号：US3535311A

公开(公告)日：1970-10-20

申请号：US3535311D

申请日：1967-04-21

Applicant: UGINE KUHLMANN

Inventor： BESSON PAUL ,  NALLET ALBERT

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

公开(公告)号：US08283466B2

公开(公告)日：2012-10-09

申请号：US12527848

申请日：2008-02-20

Applicant: John W. Frost

Inventor： John W. Frost

IPC: C07D201/02 ,  C07D201/08

CPC classification number: C07D201/00 ,  C07D201/02 ,  C07D201/08 ,  Y02P20/52

Abstract: Catalytic processes for preparing caprolactam, pipecolinic acid, and their derivatives, from lysine or alpha-amino-epsilon-caprolactam starting materials, and products produced thereby. A process for preparing caprolactam or a derivative thereof, the process comprising contacting a reactant comprising lysine or alpha aminocaprolactam with a catalyst and a gas comprising hydrogen gas, in the presence of a solvent. The catalyst may be provided on a support material, such as a transition metal.

Abstract translation: 从赖氨酸或α-氨基-ε-己内酰胺起始原料制备己内酰胺，哌可啶酸及其衍生物的催化方法，以及由此产生的产物。 一种制备己内酰胺或其衍生物的方法，该方法包括在溶剂存在下使包含赖氨酸或α-氨基己内酰胺的反应物与催化剂和包含氢气的气体接触。 催化剂可以设置在载体材料如过渡金属上。