摘要:
Dialkoxyxanthogendisulphides, their production by reacting an alcohol and carbondisulphide in the presence of alkali and subsequent oxydation, use of these dialkoxyxanthogendisulphides as molecular weight regulators in polymerisation processes and a mixture of chloroprene-copolymers made in the presence of dialkoxyxanthogendisulphides.
摘要:
Polychloroprene for use in adhesive compositions and having the advantage of remaining in a single phase is prepared by effecting polychloroprene polymerization in the presence of a binary emulsifying system of 1.8 to 3% of resinic derivative and 0.1 to 1% of a fatty acid or salt thereof. Alternatively, a ternary emulsifying system may be used comprising 1 to 3% of the resinic derivative, 0.1 to 1.5% of the fatty acid or salt therof and 0.1 to 2.5% of a sticking agent of a colophony derivative or a polydiene resin.
摘要:
CHLOROPRENE POLYMERS, USEFUL IN NON-PHASING SOLVENT CEMENTS HAVING GOOD TACK, ARE PRODUCED BY POLYMERIZING CHLOROPRENE, OPTIONALLY WITH ANOTHER COPOLYMERIZABLE MONOMER, IN AN AQUEOUS ALKALINE EMULSION IN THE PRESENCE OF WATEER-SOLUBLE SALTS OF: (A) ABOUT 0.5 TO 1.5 PERCENT OF A ROSIN ACID (B) ABOUT 1 TO 2 PERCENT OF A C12 TO C20 UNSATURATED FATTY ACID AND (C) ABOUT 0.5 TO 1.5 PERCENT OF A CONDENSATION PRODUCT OF FORMALDEHYDE WITH A NAPHTHALENE SULFONIC ACID, ALL PERCENTAGES BEING BY WEIGHT BASED ON THE WEIGHT OF CHLOROPRENE AND ANY OTHER COPOLYMERIZABLE MONOMER PRESENT, THE PERCENTAGE OF (A) AND (B) BEING BASED ON THE FREE ACID AND OF (C) BEING BASED ON THE SALT; THE TOTAL PERCENTAGE OF (A) AND (B) BEING AT LEAST 2, AND THE CONVERSION OF MONOMER TO POLYMER BEING AT LEAST ABOUT 85 PERCENT; AND OPTIONALLY HAVING PRESENT DURING POLYMERIZATION FROM 1 TO 4 PERCENT BY WEIGHT OF A METHYL ESTER OF A NATURALLY OCCURING ROSIN ACID BASED ON THE WEIGHT OF CHLOROPRENE.
摘要:
POLYMERIZING CHLOROPRENE IN AN ALKALINE AQUEOUS EMULSION IN THE PRESENCE OF A DIALKYL XANTHOGEN DISULFIDE CHAIN TRANSFER AGENT TO FORM A CHLORPRENE POLYMER LATEX AND ADDING TO THE POLYMER LATEX AT A TIME WHEN THE DESIRED DEGREE OF POLYMERIZATION HAS BEEN REACHED A COMPOUND HAVING THE STRUCTURE
R-S-N(-R1)-R2
WHEREIN R IS HYDROCARBYL, 2-THIAZOLYL, 2-BENZOTHIAZOYL RADICALS OR
-S-N(-R3)-R4
R1, R2, R3, AND R4 ARE ALKYL, CYCLOALKYL, OR ARALKYL AND R1 AND R2 OR R3 AND R4 TOGETHER CAN FORM A SATURATED RING WITH THE NITROGEN.
摘要:
HIGH-SOLIDS CHLOROPRENE POLYMER LATEXES ARE PREPARED BY POLYMERIZING CHLOROPRENE IN AN ALKALINE AQUEOUS EMULSION CONTAINING CRITICAL AMOUNTS OF THEPOTASSIUM SALTS OR A MIXTURE OF THE SODIUM AND POTASSIUM SALTS OF (1) DISPROPORITIONATED WOOD ROSIN ACIDS, (2) A FORMALDEHYDE CONDENSATE OF A NAPHTHALENE SULFONIC ACID, AND (3) A POLYMERIZED UNSATURATED FATTY ACID.