Preparation of polychloroprene for use in adhesives
    12.
    发明授权
    Preparation of polychloroprene for use in adhesives 失效
    用于粘合剂的聚氯丁二烯的制备

    公开(公告)号:US3872043A

    公开(公告)日:1975-03-18

    申请号:US31010572

    申请日:1972-11-28

    申请人: DISTUGIL

    CPC分类号: C09J111/00 C08F36/16

    摘要: Polychloroprene for use in adhesive compositions and having the advantage of remaining in a single phase is prepared by effecting polychloroprene polymerization in the presence of a binary emulsifying system of 1.8 to 3% of resinic derivative and 0.1 to 1% of a fatty acid or salt thereof. Alternatively, a ternary emulsifying system may be used comprising 1 to 3% of the resinic derivative, 0.1 to 1.5% of the fatty acid or salt therof and 0.1 to 2.5% of a sticking agent of a colophony derivative or a polydiene resin.

    摘要翻译: 用于粘合剂组合物并具有保留在单相中的优点的聚氯丁二烯通过在1.8至3%的树脂衍生物和0.1至1%的脂肪酸​​或其盐的二元乳化体系的存在下进行聚氯丁二烯聚合来制备 。 或者,可以使用三元乳化系统,其包含1至3%的树脂衍生物,0.1至1.5%的脂肪酸​​或盐,以及0.1至2.5%的松香衍生物或聚二烯树脂的粘合剂。

    Polychloroprene for non-phasing solvent cements
    13.
    发明授权
    Polychloroprene for non-phasing solvent cements 失效
    用于非相溶溶剂的聚氯乙烯

    公开(公告)号:US3824203A

    公开(公告)日:1974-07-16

    申请号:US6912470

    申请日:1970-09-02

    申请人: DU PONT

    发明人: TABIBIAN R

    摘要: CHLOROPRENE POLYMERS, USEFUL IN NON-PHASING SOLVENT CEMENTS HAVING GOOD TACK, ARE PRODUCED BY POLYMERIZING CHLOROPRENE, OPTIONALLY WITH ANOTHER COPOLYMERIZABLE MONOMER, IN AN AQUEOUS ALKALINE EMULSION IN THE PRESENCE OF WATEER-SOLUBLE SALTS OF: (A) ABOUT 0.5 TO 1.5 PERCENT OF A ROSIN ACID (B) ABOUT 1 TO 2 PERCENT OF A C12 TO C20 UNSATURATED FATTY ACID AND (C) ABOUT 0.5 TO 1.5 PERCENT OF A CONDENSATION PRODUCT OF FORMALDEHYDE WITH A NAPHTHALENE SULFONIC ACID, ALL PERCENTAGES BEING BY WEIGHT BASED ON THE WEIGHT OF CHLOROPRENE AND ANY OTHER COPOLYMERIZABLE MONOMER PRESENT, THE PERCENTAGE OF (A) AND (B) BEING BASED ON THE FREE ACID AND OF (C) BEING BASED ON THE SALT; THE TOTAL PERCENTAGE OF (A) AND (B) BEING AT LEAST 2, AND THE CONVERSION OF MONOMER TO POLYMER BEING AT LEAST ABOUT 85 PERCENT; AND OPTIONALLY HAVING PRESENT DURING POLYMERIZATION FROM 1 TO 4 PERCENT BY WEIGHT OF A METHYL ESTER OF A NATURALLY OCCURING ROSIN ACID BASED ON THE WEIGHT OF CHLOROPRENE.

    Odor improvement of xanthogen-modified chloroprene polymers
    14.
    发明授权
    Odor improvement of xanthogen-modified chloroprene polymers 失效
    改性氯化聚乙烯的改性

    公开(公告)号:US3775388A

    公开(公告)日:1973-11-27

    申请号:US3775388D

    申请日:1972-02-18

    申请人: DU PONT

    发明人: KHAN A

    CPC分类号: C08F36/16

    摘要: POLYMERIZING CHLOROPRENE IN AN ALKALINE AQUEOUS EMULSION IN THE PRESENCE OF A DIALKYL XANTHOGEN DISULFIDE CHAIN TRANSFER AGENT TO FORM A CHLORPRENE POLYMER LATEX AND ADDING TO THE POLYMER LATEX AT A TIME WHEN THE DESIRED DEGREE OF POLYMERIZATION HAS BEEN REACHED A COMPOUND HAVING THE STRUCTURE

    R-S-N(-R1)-R2

    WHEREIN R IS HYDROCARBYL, 2-THIAZOLYL, 2-BENZOTHIAZOYL RADICALS OR

    -S-N(-R3)-R4

    R1, R2, R3, AND R4 ARE ALKYL, CYCLOALKYL, OR ARALKYL AND R1 AND R2 OR R3 AND R4 TOGETHER CAN FORM A SATURATED RING WITH THE NITROGEN.

    15.
    发明授权
    失效

    公开(公告)号:UST900023I4

    公开(公告)日:1972-07-25

    申请号:US900023D

    申请日:1971-05-25

    IPC分类号: C08F36/16

    CPC分类号: C08F36/16

    Process for preparing high-solids chloroprene polymer latex
    16.
    发明授权
    Process for preparing high-solids chloroprene polymer latex 失效
    制备高固体氯仿聚合物的方法

    公开(公告)号:US3651037A

    公开(公告)日:1972-03-21

    申请号:US3651037D

    申请日:1969-09-30

    申请人: DU PONT

    IPC分类号: C08F36/16 C08F3/16

    CPC分类号: C08F36/16

    摘要: HIGH-SOLIDS CHLOROPRENE POLYMER LATEXES ARE PREPARED BY POLYMERIZING CHLOROPRENE IN AN ALKALINE AQUEOUS EMULSION CONTAINING CRITICAL AMOUNTS OF THEPOTASSIUM SALTS OR A MIXTURE OF THE SODIUM AND POTASSIUM SALTS OF (1) DISPROPORITIONATED WOOD ROSIN ACIDS, (2) A FORMALDEHYDE CONDENSATE OF A NAPHTHALENE SULFONIC ACID, AND (3) A POLYMERIZED UNSATURATED FATTY ACID.