摘要:
VINYL CHLORIDE AND VINYLIDENE CHLORIDE POLYMERS CAN BE CROSS-LINKED OR OTHERWISE MODIFIED BY REACTION WITH A POLY (DIAZO) COMPOUND SELECTED FROM THE GROUP OF
R-(O-CO-CN2-R'')X AND A-(CN2-R'')X
WHERE X IS AN INTEGER GREATER THAN 1, R IS AN ORGANIC RADICAL INERT TO MODIFICATION REACTIONS, A IS AN AROMATIC RADICAL INERT TO MODIFICATION REACTIONS, AND R'' IS A HYDROGEN, ARYL OR -COOZ RADICAL WHERE Z IS AN ALKYL OR ARYL RADICAL. THE REACTION BETWEEN THE POLY (DIAZO) COMPOUND AND POLYMER CAN BE INITIATED EITHER BY HEATING OR BY EXPOSING TO ULTRAVIOLET RADIATION.
摘要:
THE ACCELERATION OF THE VULCANIZATION OF SATURATED, FLUORINATED POLYMERS BY THE USE OF CYCLIC POLYETHERS. THE ACCELERATORS ENABLE A MORE RAPID CURE WITH CONVENTIONAL AMINE-BASED VULCANIZATION SYSTEMS AND ALSO ENABLE A SATISFACTORY RATE AND STATE OF CURE WITH WEAKLY BASIC BISNUCLEOPHILES OTHERWISE INCAPABLE OF ADEQUATELY CURING FLUORINATED POLYMERS.
摘要:
Vinylidene fluoride is polymerized in an acidic aqueous medium in the presence of a peroxide disulfate polymerization initiator in a concentration of less than 0.5 gram/liter of the liquid reaction phase.
摘要:
Polymeric compositions characterized by being fiber-forming and stereospecific and capable of being melted and drawn into strong crystalline filaments and fibers. The compositions are useful as storage stable binders as well as adhesives for fluorcarbon material.
摘要:
POLYPERFLUOROPOLYENES SUCH AS POLYPERFLUOROBUTADIENE ARE REACTED WITH FLUORINE TO EITHER PROVIDE A STAURATED POLYMER CHAIN AND/OR CREATE REACTIVE SITES ON THE POLYMER CHAIN WHICH IS THEN FOLLOWED BY EXPOSURE TO A MONOMERIC SPECIES WHICH UNDREGOES FREEN REDICAL POLYMERIZATION TO GRAFT THE MONOMR ONTO THE POLYPERFLUOROPOLYENE.
摘要:
Vinyl halide polymers, preferably polyvinyl chloride, which exhibit improved processing characteristics without sacrificing physical properties are prepared by partially polymerizing vinyl halide monomer at a first reaction temperature and then changing the reaction temperature and continuing the polymerization at a second temperature conducive to forming a polymer of an average molecular weight range different from that obtainable at the first reaction temperature. The product provides the physical characteristics of polymer blends but can be processed without formation of fish eyes.
摘要:
Fluorine-, chlorine- and/or bromine-containing polymers are prepared by reacting A. A MONOMER OR MIXTURE OF MONOMERS HAVING THE STRUCTURAL FORMULA R-CX3)n, wherein n is an integer from 2 to 4, X is fluoro, chloro or bromo, and R is an n-valent hydrocarbon or halo-substituted hydrocarbon group, each -CX3 group being an allylic or benzylic trihalomethyl group; with B. CuX and/or CuX2, wherein X has the above meaning, and C. PHOSPHOROUS ACID, ALKYL HYDROGEN PHOSPHONATE AND/OR A DIALKYL HYDROGEN PHOSPHONATE. The polymers are thermally stable at elevated temperatures and are useful as heat-resistant, fire-resistant films, coatings, ablatives and the like.
摘要:
POLYCHLORPORENES WHICH MELT AT TEMPERATURES OF 80*C. AND ABOVE. AT LEAST 95% OF THE CHLOROPRENE UNITS OF THE POLYMER CHAIN ARE TRANS-2-CHLORO-2-BUTEN-1,4-YLENE UNITS AND AT LEAST 95% OF ALL 2-CHLORO-2-BUTEN-1,4-YLENE UNITJS IN THE POLYMER ARE IN THE HEAD-TO-TAIL SEQUENCE. THE POLYCHLOROPRENES ARE PREAPRED BY IRRADIATING CRYSTALLINE CHLOROPRENE AT TEMPERATURES BELOW-130*C.
摘要:
THE PRESENT INVENTION IS RELATED TO A PROCESS FOR THE MANUFACTURE OF POLYMERS AND COPOLYMERS OF FLUORINE-CONTAINING OLEFINS AT RELATIVELY LOW TEMPERATURES IN THE RANGE OF FROM 0 TO 50*C. AND AT ATMOSPHERIC OR SLIGHTLY ELEVATED PRESSURE. THE POLYMERIZATION IS CATALYZED BY ACIDS OR SALTS OF ACIDS OF SUBGROUP V TO VII METALS OR BY COMPOUNDS WHICH ARE CONVERTED INTO SUCH ACIDS UNDER THE REACTION CONDITIONS.