公开(公告)号：US3956353A

公开(公告)日：1976-05-11

申请号：US488365

申请日：1974-07-15

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C08K5/00 ,  C07F7/18 ,  C08G77/26 ,  C08K5/54 ,  C08K5/544 ,  C08L1/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L67/00 ,  C09J11/00 ,  C07F7/10

CPC classification number: C08G77/26 ,  C07F7/1804 ,  Y10T428/31536

Abstract: Anionic silanes of the formula ##EQU1## are made by reacting silanes of the formula (RO).sub.3 SiR'(NHCH.sub.2 CH.sub.2).sub.n NHCH.sub.2 ##EQU2## with 1 or 2 moles of an anhydride of a 1,2-dicarboxylic acid. A typical compound is ##EQU3## these compounds are used as coupling agents between inorganic substrates and organic resins such as epoxides, phenolic and polyester.

Abstract translation: 通式（RO）3 SiR'（NHCH 2 CH 2）n NHCH 2 CH = CH 2的硅烷与1或2摩尔的式（Ⅳ）的硅烷反应制备式HOOCR“O = C（（RO）3SiR'（NCH2CH2）nNHCH2CH = 1,2-二羧酸的酸酐。 典型的化合物是（MeO）3 Si（CH2）3NCH2CH2NHCH2CH = CH2。 | C = O | CH = CHCOOH这些化合物用作无机基质和有机树脂如环氧化物，酚醛和聚酯之间的偶联剂。

公开(公告)号：US5073195A

公开(公告)日：1991-12-17

申请号：US650121

申请日：1991-02-04

Applicant: Robert L. Cuthbert ,  Edwin P. Plueddemann

Inventor： Robert L. Cuthbert ,  Edwin P. Plueddemann

IPC: C04B41/49 ,  C04B41/64 ,  C09D4/00

CPC classification number: C04B41/64 ,  C04B41/4944 ,  C09D4/00 ,  Y10T428/12014 ,  Y10T428/31663

Abstract: A water repellent composition for treating surfaces which is an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane. The alkyltrialkoxysilane is either an alkyltrialkoxysilanes with C.sub.1 to C.sub.6 alkyl groups on silicon or a blend of alkyltrialkoxysilanes each with C.sub.1 to C.sub.6 alkyl groups on silicon. A treatmetn method for wood and masonry is disclosed.

Abstract translation: 一种用于处理作为水溶性硅烷偶联剂和烷基三烷氧基硅烷的水溶液的表面的防水组合物。 烷基三烷氧基硅烷是在硅上具有C1至C6烷基的烷基三烷氧基硅烷或在硅上各自具有C1至C6烷基的烷基三烷氧基硅烷的共混物。 公开了一种木材和砖石的处理方法。

公开(公告)号：US5041593A

公开(公告)日：1991-08-20

申请号：US381916

申请日：1989-07-19

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C07F7/08 ,  C07F7/18 ,  C08J5/12

CPC classification number: C08J5/12 ,  C07F7/0889 ,  C07F7/182 ,  C07F7/1836 ,  C07F7/1892 ,  C08J2323/02

Abstract: Silyl-functional fumarates are formed through the reaction of a methyl ester of a maleate with a chloroalkyl silane or disiloxane in the presence of an amine or phosphine catalyst. These materials are useful as adhesion promoters for polyolefins.

公开(公告)号：US5006573A

公开(公告)日：1991-04-09

申请号：US917950

申请日：1986-10-14

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C07F7/12 ,  C07F7/18 ,  C08F30/08

CPC classification number: C07F7/1836

Abstract: A novel organosilane coupling agent is disclosed and its use as an adhesion promoter in mineral-filled unsaturated polymer systems is described. Additionally, use of the organosilane as a primer for various substrates is presented. The coupling agent comprises the reaction product of an isocyanatoalkyl ester of acrylic or methacrylic acid with an aminoorganosilane. The organosilane so formed links the acryloxyalkyl or methacryloxyalkyl functionality to an alkylene, or aminoalkylene, group on the silicon atom through a urea group. Use of the organosilane as a coupling agent in a mineral-filled unsaturated polymer results in superior resistance to moisture, particularly when the polymer is selected from the group of corrosion resistant unsaturated polyesters.

Abstract translation: 公开了一种新的有机硅烷偶联剂，并且描述了其在矿物填充的不饱和聚合物体系中作为粘合促进剂的用途。 另外，提出了使用有机硅烷作为各种底物的底漆。 偶联剂包括丙烯酸或甲基丙烯酸的异氰酸烷基酯与氨基有机硅烷的反应产物。 如此形成的有机硅烷通过脲基将丙烯酰氧基烷基或甲基丙烯酰氧基烷基官能团连接到硅原子上的亚烷基或氨基亚烷基。 在矿物填充的不饱和聚合物中使用有机硅烷作为偶联剂导致优异的耐湿性，特别是当聚合物选自耐腐蚀不饱和聚酯的组时。

公开(公告)号：US4912239A

公开(公告)日：1990-03-27

申请号：US245480

申请日：1988-09-19

Applicant: Howard M. Bank ,  Edwin P. Plueddemann

Inventor： Howard M. Bank ,  Edwin P. Plueddemann

IPC: C07F7/18

CPC classification number: C07F7/1872

Abstract: A method for stabilizing an unsaturated organosilicone is disclosed wherein a stabilizing amount of a hydroxylamine compound is added to the organosilicone to prevent thermal polymerization of the latter. The organosilicone may be an alkoxysilane or an organopolysiloxane having in its molecule a reactive organic group bearing at least one radical selected from acryloxy, methacryloxy, acrylamide, methacrylamide, styryl or vinylbenzyl radicals. The hydroxylamine compound may be added either to the organosilicone or during the preparation of the alkoxysilane from its respective reactants.

公开(公告)号：US4876154A

公开(公告)日：1989-10-24

申请号：US249061

申请日：1988-09-26

Applicant: Gerald L. Witucki ,  Edwin P. Plueddemann

Inventor： Gerald L. Witucki ,  Edwin P. Plueddemann

IPC: B27N3/00 ,  C08K5/5419 ,  C08K5/544 ,  C08L31/04 ,  C09J131/04

CPC classification number: C08K5/544 ,  C09J131/04 ,  Y10T428/31663 ,  Y10T428/3179 ,  Y10T428/31895 ,  Y10T428/31906

Abstract: The present invention relates to water-born emulsion adhesives based on polymers or copolymers of vinyl acetate and having uniformly dispersed therein an adhesion promoter consisting essentially of an alkoxysilane and up to about 80% by weight of a plasticizer for the poly(vinyl acetate). The alkoxysilane useful herein may be selected from ##STR1## in which R is independently selected from alkyl or alkoxyalkyl radicals having 1-4 carbon atoms. The modified adhesives have improved bond strength to wood, particularly after exposure to moisture.

公开(公告)号：US4718944A

公开(公告)日：1988-01-12

申请号：US916260

申请日：1986-10-07

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C09K3/10 ,  B05D3/10 ,  B32B17/10 ,  C07F7/18 ,  C08J3/20 ,  C08K5/5455 ,  C08K9/06 ,  C08L101/00 ,  C09J5/02 ,  C08K5/09 ,  C08K5/54

CPC classification number: C07F7/1836 ,  C08K5/5455

Abstract: A coupling agent composition comprised of the reaction product of (a) about two mole parts of maleic anhydride with (b) about one mole part of a diamine functional silane compound of the general formula ##STR1## where R denotes an alkyl radical, R' denotes an alkyl radical, R" and R'" denote alkylene radicals and x is 0 or 1; and (c) sufficient solvent to solubilize (a) and (b).

Abstract translation: 由（a）约2摩尔份马来酸酐与（b）约1摩尔通式为“IMAGE”的二胺官能化硅烷化合物的反应产物组成的偶联剂组合物，其中R表示烷基，R' 表示烷基，R“和R”表示亚烷基，x为0或1; 和（c）足够的溶剂以溶解（a）和（b）。

公开(公告)号：US4650889A

公开(公告)日：1987-03-17

申请号：US803043

申请日：1985-11-29

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C07F7/12 ,  C07F7/18 ,  C08F30/08 ,  C07F7/10

CPC classification number: C07F7/1836

Abstract: A novel organosilane coupling agent is disclosed and its use as an adhesion promoter in mineral-filled unsaturated polymer systems is described. Additionally, use of the organosilane as a primer for various substrates is presented. The coupling agent comprises the reaction product of an isocyanatoalkyl ester of acrylic or methacrylic acid with an aminoorganosilane. The organosilane so formed links the acryloxyalkyl or methacryloxyalkyl functionality to an alkylene, or aminoalkylene, group on the silicon atom through a urea group. Use of the organosilane as a coupling agent in a mineral-filled unsaturated polymer results in superior resistance to moisture, particularly when the polymer is selected from the group of corrosion resistant unsaturated polyesters.

Abstract translation: 公开了一种新的有机硅烷偶联剂，并且描述了其在矿物填充的不饱和聚合物体系中作为粘合促进剂的用途。 另外，提出了使用有机硅烷作为各种底物的底漆。 偶联剂包括丙烯酸或甲基丙烯酸的异氰酸烷基酯与氨基有机硅烷的反应产物。 如此形成的有机硅烷通过脲基将丙烯酰氧基烷基或甲基丙烯酰氧基烷基官能团连接到硅原子上的亚烷基或氨基亚烷基。 在矿物填充的不饱和聚合物中使用有机硅烷作为偶联剂导致优异的耐湿性，特别是当聚合物选自耐腐蚀不饱和聚酯的组时。

公开(公告)号：US4503242A

公开(公告)日：1985-03-05

申请号：US467695

申请日：1983-02-18

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C01B33/32 ,  C07F7/08 ,  C07F7/10 ,  C07F7/18 ,  C08G77/28 ,  C08L83/02 ,  C09K5/20 ,  C23F11/10 ,  C23F11/16 ,  C23F11/18

CPC classification number: C01B33/325 ,  C07F7/1836 ,  C08G77/28 ,  C08L83/02 ,  C09K5/20 ,  C23F11/10

Abstract: Alkali siliconates of silylorganosulfonates are capable of stabilizing solutions of water soluble silicates and enhancing their usefulness as corrosion inhibitors for metals that come in contact with aqueous, alcoholic or aqueous-alcoholic solutions. The disclosed alkali siliconates of silylorganosulfonates are also useful stabilizers for aqueous silicates in such applications as treating boiler water, geothermal water and cooling coil water. Methods of using the alkali siliconates of silylorganosulfonates to provide corrosion inhibiting antifreeze and coolant solutions are disclosed.

Abstract translation: 甲硅烷基有机磺酸盐的碱性硅酸盐能够稳定水溶性硅酸盐的溶液，并且增强其作为与含水，醇或水溶液接触的金属的腐蚀抑制剂的用途。 公开的甲硅烷基有机磺酸盐的碱性硅酸盐也可用于处理锅炉水，地热水和冷却盘管水等应用中的硅酸水溶液的有用的稳定剂。 公开了使用甲硅烷基有机磺酸盐的碱性硅酸盐提供防腐防冻剂和冷却剂溶液的方法。

公开(公告)号：US4093641A

公开(公告)日：1978-06-06

申请号：US836451

申请日：1977-09-26

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C08G77/00 ,  B01J21/00 ,  B01J27/00 ,  C07B61/00 ,  C07F9/02 ,  C07F9/09 ,  C07F9/32 ,  C08G77/06 ,  C08G77/08 ,  C08G77/22 ,  C08G77/28 ,  C08G77/38 ,  C08G79/04 ,  C07F7/08

CPC classification number: C07F9/02 ,  C08G79/04

Abstract: What is disclosed is a novel method of preparing silylalkyl esters of phosphorus using amines or phosphines, which are capable of forming onium compounds with the reactants, as catalysts. They are useful as flame retardant additives and lubricants on metals and textiles.

Abstract translation: 公开的是使用能够与反应物形成鎓化合物的胺或膦作为催化剂制备磷的甲硅烷基烷基酯的新方法。 它们可用作金属和纺织品上的阻燃添加剂和润滑剂。