Photographic products employing novel nondiffusible metal complexes of
azo dyes
    21.
    发明授权
    Photographic products employing novel nondiffusible metal complexes of azo dyes 失效
    使用偶氮染料的新型非扩散金属络合物的摄影产品

    公开(公告)号:US4598030A

    公开(公告)日:1986-07-01

    申请号:US761932

    申请日:1985-08-02

    Inventor: James A. Reczek

    CPC classification number: G03C8/10 C09B45/14

    Abstract: Photographic elements, diffusion transfer assemblages and coordination complexes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible dye moiety having the formula: ##STR1## wherein: (a) D.sup.1, D.sup.2 and D.sup.3 each independently represents the atoms necessary to complete an aromatic heterocyclic nucleus having at least one ring of 5 to 7 atoms;(b) Z.sup.1 and Z.sup.2 each independently represents the atoms necessary to complete an aromatic carbocyclic or heterocyclic nucleus having at least one ring of 5 to 7 atoms or a ketomethine group;(c) G.sup.1 and G.sup.2 each independently represents a metal chelating group;(d) Me is a polyvalent, hexacoordinate metal ion,(e) CAR represents a ballasted carrier moiety capable of releasing the diffusible dye moiety as a function of development of the silver halide emulsion layer under alkaline conditions; and(f) n is 1, 2 or 3.

    Abstract translation: 描述了摄影元件,扩散转移组合物和配位络合物,其使用能够释放具有下式的至少一个可扩散染料部分的新型不扩散化合物:其中:(a)D1,D2和D3各自独立地表示 完成具有至少一个5至7个原子的环的芳族杂环核; (b)Z1和Z2各自独立地表示完成具有至少一个5至7个环的酮或酮基苯基的芳族碳环或杂环核所必需的原子; (c)G1和G2各自独立地表示金属螯合基团; (d)Me是多价六价金属离子,(e)CAR表示在碱性条件下能够释放可扩散染料部分作为卤化银乳剂层的功能的压载载体部分; 和(f)n为1,2或3。

    Photographic elements and processes utilizing imagewise reduction of
ferric ions
    22.
    发明授权
    Photographic elements and processes utilizing imagewise reduction of ferric ions 失效
    利用成像还原铁离子的照相元件和工艺

    公开(公告)号:US4568633A

    公开(公告)日:1986-02-04

    申请号:US688477

    申请日:1985-01-02

    CPC classification number: G03C7/26 G03C5/40

    Abstract: A process for obtaining highly stable color photographic images utilizes a silver halide photographic element comprising an essentially colorless, immobile compound which is capable of complexing with ferrous ions to form a dye. The complexing compound contains a complexing moiety which is represented by the formula: ##STR1## wherein m is zero or a positive integer 1 to 3, n and p are independently 0 or 1 and represents a single or double bond. Z is R.sup.1 --N.dbd., O.dbd., S.dbd., R.sup.1 --P.dbd., (R.sup.1).sub.2 P-- or (R.sup.1).sub.3 P.dbd., and when Z is (R.sup.1).sub.2 P--, n is 1, otherwise n is 0. R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently hydrogen, amino, hydroxy, mercapto, alkoxy, alkyl, aryl or a heterocyclic moiety. When R.sup.6 is so defined, p is 1 and is a single bond. If m is 0, R.sup.1 and R.sup.2, R.sup.2 and R.sup.3, and R.sup.3 and R.sup.4 taken together can independently represent the carbon and heteroatoms necessary to complete a substituted or unsubstituted carbocyclic or heterocyclic nucleus, or if m is 1 to 3, R.sup.1 and R.sup.2, R.sup.5 and R.sup.6, and R.sup.3 and R.sup.4 can independently represent the carbon and heteroatoms necessary to complete a substituted or unsubstituted heterocyclic nucleus. When R.sup.5 and R.sup.6 are so defined, p is 0 when is a double bond, and p is 1 when is a single bond.

    Abstract translation: 用于获得高度稳定的彩色照相图像的方法使用包含基本上无色的固定化合物的卤化银照相元件,其能够与亚铁离子络合以形成染料。 络合化合物包含由下式表示的络合部分:其中m为0或正整数1至3,n和p独立地为0或1,并且表示单键或双键。 Z为R1-N =,O =,S =,R1-P =,(R1)2P-或(R1)3P =,当Z为(R1)2P-时,n为1,否则n为0. R1 ,R2,R3,R4,R5和R6独立地是氢,氨基,羟基,巯基,烷氧基,烷基,芳基或杂环部分。 当R6如此定义时,p是1并且是单键。 如果m为0,则R 1和R 2,R 2和R 3以及R 3和R 4一起可以独立地表示完成取代或未取代的碳环或杂环核所需的碳和杂原子,或者如果m为1至3,则R1和R2, R 5和R 6,并且R 3和R 4可以独立地表示完成取代或未取代的杂环核所必需的碳和杂原子。 当R5和R6如此定义时,当双键时p为0,当单键为p时,p为1。

    Photographic products and processes employing novel nondiffusible cyan
dye-releasing compounds and precursors thereof
    23.
    发明授权
    Photographic products and processes employing novel nondiffusible cyan dye-releasing compounds and precursors thereof 失效
    使用新型不溶性青色染料释放化合物及其前体的摄影产品和方法

    公开(公告)号:US4476207A

    公开(公告)日:1984-10-09

    申请号:US578720

    申请日:1984-02-09

    CPC classification number: C09B27/00 G03C8/10

    Abstract: Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible cyan dye moiety comprising a 6-heterocyclylazo-3-pyridinol, the compound having the formula: ##STR1## wherein: (a) Y represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible cyan dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(c) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(d) n is 0, 1 or 2 with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.

    Abstract translation: 描述了摄影元件,扩散转移组合物,配位络合物和方法,其使用能够释放包含6-杂环基偶氮-3-吡啶酚的至少一种可扩散的青色染料部分的新型非扩散性化合物,该化合物具有下式:其中: (a)Y表示完成5-或6-元芳族杂环稠环所必需的原子; (b)CAR表示在碱性条件下能够释放可扩散青色染料部分作为卤化银乳剂层的功能的压载载体部分; (c)R表示羟基,其盐或其可水解的前体,或通过其上的氧原子与染料部分连接的CAR; 和(d)n为0,1或2,条件是当n为0时,R为通过其上的氧原子与染料部分连接的CAR。

    SCANNER METAMERISM CORRECTION
    24.
    发明申请
    SCANNER METAMERISM CORRECTION 失效
    扫描仪元素校正

    公开(公告)号:US20080239334A1

    公开(公告)日:2008-10-02

    申请号:US11694098

    申请日:2007-03-30

    CPC classification number: H04N1/6094 H04N1/603

    Abstract: A method for automatically compensating for scanner metamerism errors associated with scanning input images using a digital color image scanner, wherein the input images can be on a variety of different input media having colorants with different spectral characteristics, comprising scanning an input image on a digital color image scanner to produce a scanned image; determining one or more estimated color balance error values in a color balance parameter space by analyzing the scanned image using a color balance analysis algorithm; assigning an input medium from a set of possible input media for the scanned input image in response to the estimated color balance error values; selecting a scanner metamerism correction color transform associated with the assigned input medium; and applying the selected scanner metamerism correction color transform to the scanned image to produce a corrected image compensated for scanner metamerism errors.

    Abstract translation: 一种用于自动补偿与使用数字彩色图像扫描器扫描输入图像相关的扫描器同色异谱误差的方法,其中所述输入图像可以在具有不同光谱特性的着色剂的各种不同输入介质上,包括以数字颜色扫描输入图像 图像扫描仪产生扫描图像; 通过使用颜色平衡分析算法分析扫描图像来确定颜色平衡参数空间中的一个或多个估计的颜色平衡误差值; 响应于估计的颜色平衡误差值,从扫描的输入图像的一组可能的输入介质中分配输入介质; 选择与分配的输入介质相关联的扫描器同色异谱校正颜色变换; 以及将所选择的扫描器同色异谱校正颜色变换应用于扫描图像,以产生补偿扫描器同色异谱误差的校正图像。

    Recording element printing and treating system and method
    25.
    发明授权
    Recording element printing and treating system and method 有权
    记录元素印刷和处理系统及方法

    公开(公告)号:US07025450B2

    公开(公告)日:2006-04-11

    申请号:US10731705

    申请日:2003-12-09

    CPC classification number: B41J11/002

    Abstract: A recording element printing and treating system and method are provided. The system includes a printhead for dispensing a liquid comprising a carrier onto a recording element. A carrier removal station positioned downstream from the printhead removes a predetermined percentage of carrier present in the recording element. A converting station positioned downstream from the carrier removal station increases a durability characteristic of the recording element. In one embodiment, printing, carrier removal, and converting are accomplished in a single unit. In an alternative embodiment, printing is accomplished in a stand alone unit while carrier removal and converting are accomplished in a second stand alone unit. In this alternative embodiment, transfer of the recording element can be accomplished automatically using a mechanical device or manually by a system user.

    Abstract translation: 提供了一种记录元件印刷和处理系统和方法。 该系统包括用于将包括载体的液体分配到记录元件上的打印头。 位于打印头下游的载体移除台移除存在于记录元件中的载体的预定百分比。 位于载体移除站下游的转换站增加了记录元件的耐久性。 在一个实施例中,打印,载体移除和转换在单个单元中完成。 在替代实施例中,印刷是在独立单元中实现的,而载体移除和转换在第二独立单元中完成。 在该备选实施例中,记录元件的传送可以使用机械装置自动完成或由系统用户手动完成。

    Method of selecting ink jet inks in a color set
    26.
    发明授权
    Method of selecting ink jet inks in a color set 失效
    在彩色组中选择喷墨油墨的方法

    公开(公告)号:US06666553B2

    公开(公告)日:2003-12-23

    申请号:US10034285

    申请日:2001-12-28

    CPC classification number: C09D11/322

    Abstract: A method of selecting inks within an inkjet ink set for color printing includes: a) providing at least two color inks, each ink having a carrier and a pigment; b) printing the above inks onto a receiver using test images consisting of single color patches of a Dmax density (100% dot coverage); c) measuring the gloss level of each patch at a predefined specular angle; d) calculating the Relative Gloss Variability (RGV) values of the ink set based on the definition in Equation A; and e) selecting inks for the color set such that the Relative Gloss Variability (RGV) among inks is less than 10% when 60° is used as the specular angle: RGV ⁡ ( % ) = ∑ I = 1 N ⁢ | ( Gloss ⁡ ( Imaged ⁢   ⁢ Area ) I - AG ) | AG / N Equation ⁢   ⁢ ( A ) Where AG = ∑ I = 1 N ⁢ Gloss ⁡ ( Imaged ⁢   ⁢ Area ) I N I is a variable which identifies a certain color patch used in the evaluation, N is the total number of color patches used in the evaluation.

    Abstract translation: 在彩色打印用喷墨油墨组内选择油墨的方法包括:a)提供至少两种颜色的油墨,每种油墨具有载体和颜料; b)使用由Dmax密度(100%点覆盖)的单个色块组成的测试图像将上述油墨印刷到接收器上; c)以预定的镜面角度测量每个贴片的光泽度; d)基于等式A中的定义计算墨水组的相对光泽变化(RGV)值; 和e)选择用于颜色组合的油墨,使得当使用60°作为镜面角度时,油墨中的相对光泽度变化(RGV)小于10%。其中,I是识别评估中使用的某个色标的变量, N是评估中使用的色块的总数。

    Ink jet printing process
    27.
    发明授权
    Ink jet printing process 失效
    喷墨打印过程

    公开(公告)号:US06547865B2

    公开(公告)日:2003-04-15

    申请号:US09813581

    申请日:2001-03-21

    CPC classification number: C09D11/30 C09D11/328

    Abstract: An ink jet printing process for improving the ozone stability an ink jet image comprising: a) providing an ink jet recording element comprising a support having thereon a porous image-receiving layer having interconnecting voids; and b) applying droplets of a liquid ink on the image-receiving layer in an image-wise manner, the ink comprising water, humectant and a metallized, phthalocyanine dye, the metallized, phthalocyanine dye comprising the formula: MPc(SO3X)a(SO2NRR′)b.

    Abstract translation: 一种用于改善臭氧稳定性的喷墨印刷方法,包括:a)提供喷墨记录元件,其包括其上具有互连空隙的多孔图像接收层的支撑体; 以及b)以图像方式将液体墨水滴涂在图像接收层上,该油墨包含水,湿润剂和金属化的酞菁染料,金属化的酞菁染料,其包含下式:

    Polymeric mordant containing nitrogen-coordinating ligand for
metallizable dyes
    28.
    发明授权
    Polymeric mordant containing nitrogen-coordinating ligand for metallizable dyes 失效
    含有金属化染料的氮配位配体的聚合媒染剂

    公开(公告)号:US4581314A

    公开(公告)日:1986-04-08

    申请号:US688205

    申请日:1985-01-02

    CPC classification number: G03C8/56 Y10S430/142

    Abstract: Photographic elements and diffusion transfer assemblages are described which contain a novel mordant comprising a polymeric backbone having appended thereto nitrogen-coordinating ligands having the formula: ##STR1## wherein D.sup.1, D.sup.2, D.sup.3 each independently represents the atoms necessary to complete an aromatic heterocyclic nucleus having at least one ring of 5 to 7 atoms.In a preferred embodiment, the mordant comprises recurring units having the formula: ##STR2## wherein: R.sup.1 and R.sup.2 each independently represents hydrogen or an alkyl or substituted alkyl group having from 1 to about 6 carbon atoms;Link represents a bivalent linking group; andLIG represents a nitrogen-coordinating ligand as described above.

    Abstract translation: 描述了摄影元件和扩散转移组合物,其包含新颖的媒染剂,其包含具有附加有下式的氮配位配体的聚合物主链:其中D1,D2,D3各自独立地表示完成芳族杂环核所必需的原子, 至少一个5至7个原子的环。 在优选的实施方案中,媒染剂包含具有下式的重复单元:其中:R 1和R 2各自独立地表示氢或具有1至约6个碳原子的烷基或取代的烷基; Link表示二价连接基团; 并且LIG表示如上所述的氮配位配体。

    Photographic element and process for providing metal complex color images
    29.
    发明授权
    Photographic element and process for providing metal complex color images 失效
    用于提供金属复合彩色图像的照相元件和工艺

    公开(公告)号:US4555478A

    公开(公告)日:1985-11-26

    申请号:US688478

    申请日:1985-01-02

    CPC classification number: G03C7/30547

    Abstract: A process of obtaining highly stable color images comprises use of an element which has a support having thereon at least one silver halide emulsion layer having associated therewith an essentially colorless, immobile, ligand-releasing compound of the structure LIG-X. In this structure, LIG is a ligand which is capable of complexing with metal ions (e.g. ferrous ions) to form a metal complex dye, and X is a group which, as a function of silver halide development, is cleaved from LIG. A color image is formed by developing the described element after imagewise exposure with a developing agent to imagewise cleave the bond between the LIG and X, and treating the developed element with metal ions (e.g. ferrous ions) to form a metal complex dye image.

    Abstract translation: 获得高度稳定的彩色图像的方法包括使用具有其上具有至少一个卤化银乳剂层的载体的元件,所述卤化银乳剂层具有结构LIG-X的基本上无色的,固定的配体释放化合物。 在该结构中,LIG是能够与金属离子(例如亚铁离子)络合以形成金属络合物染料的配体,X是作为卤化银显影的函数从LIG切割的基团。 通过在用显影剂成像曝光后显影所述元件形成彩色图像,以成像切割LIG和X之间的结合,并用金属离子(例如亚铁离子)处理显影元件以形成金属络合染料图像。

    Non-diffusible cyan compound capable of releasing a
6-heterocyclylazo-3-pyridinol
    30.
    发明授权
    Non-diffusible cyan compound capable of releasing a 6-heterocyclylazo-3-pyridinol 失效
    能够释放6-杂环基偶氮-3-吡啶酚的非扩散性青色化合物

    公开(公告)号:US4495100A

    公开(公告)日:1985-01-22

    申请号:US504693

    申请日:1983-06-15

    CPC classification number: G03C8/10 C09B27/00

    Abstract: Nondiffusible compounds capable of releasing at least one diffusible cyan dye moiety having the formula: ##STR1## wherein: (a) Y represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible cyan dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(c) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(d) n is 0, 1 or 2 with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.

    Abstract translation: 能够释放具有下式的至少一个可扩散的青色染料部分的非扩散性化合物:其中:(a)Y表示完成5-或6-元芳族杂环稠环所必需的原子; (b)CAR表示在碱性条件下能够释放可扩散青色染料部分作为卤化银乳剂层的功能的压载载体部分; (c)R表示羟基,其盐或其可水解的前体,或通过其上的氧原子与染料部分连接的CAR; 和(d)n为0,1或2,条件是当n为0时,R为通过其上的氧原子与染料部分连接的CAR。

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