Abstract:
A method for preparing a high purity (e.g. greater than 70 wt. %) mono-hydrolyzed acyl halide compound as a precipitate from solution comprising the steps of preparing a solution comprising: i) at least 80 v/v % of a hydrocarbon solvent, ii) water at a molar concentration greater than its solubility limit within the solvent but less that its solubility limit in solution, iii) a tri-hydrocarbyl phosphate compound, and iv) a polyfunctional acyl halide compound at molar ratio to both water and the tri-hydrocarbyl phosphate compound of at least 1:1.
Abstract:
The invention includes a spiral wound module comprising at least one membrane sheet wrapped about a permeate collection tube wherein the membrane sheet (14) comprises a plurality of capillary channels in parallel arrangement with each other and which are in fluid communication with the permeate collection tube (12). Many additional embodiments are disclosed along with methods for making and using the module and corresponding components.
Abstract:
The present invention is directed toward spiral wound modules including membrane sheets with regions (70,72) having different permeabilities. Said regions are arranged either axially or radially or both.
Abstract:
New methods and apparatus are described for assessing the integrity of a separation module or filtration system. A principle embodiment concerns use of a transient pulse of challenge species to probe a spiral wound module. The resulting time-dependent concentration of challenge species in the permeate is detected, recorded, and compared to a reference. An apparatus is further claimed for detecting permeate conductivity at multiple points within the permeate collection tube of a spiral wound module. Also disclosed is a process whereby the permeate stream from a filtration system is concentration by a high recovery membrane apparatus prior to measurement of challenge species concentration.
Abstract:
The invention includes a spiral wound module comprising at least one membrane sheet wrapped about a permeate collection tube wherein the membrane sheet (14) comprises a plurality of capillary channels in parallel arrangement with each other and which are in fluid communication with the permeate collection tube (12). Many additional embodiments are disclosed along with methods for making and using the module and corresponding components.
Abstract:
Methods are provided for controlling sessile microorganisms and removing biofilm from an aqueous or moisture-containing system. The methods comprise treating the system with an effective amount of a compound of the formula I: wherein X, R and R1 are as defined herein.
Abstract:
A package assembly comprising a sealed water-impermeable bag enclosing: a spiral wound filtration element comprising a piperazine-based membrane, and an aqueous solution comprises a substantially non-oxidizable buffer having capacity to sequester at least 0.0025 moles per liter of hydrogen ions. The assembly preferably further includes a reducing agent. The assembly provides improved preservation for piperazine-based membranes and elements incorporating such membranes.
Abstract:
A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.
Abstract:
A method for making a composite polyamide membrane including the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a subject monomer comprising at least one carboxylic acid group linked to an aromatic moiety and wherein the aromatic moiety is further substituted with at least one of an acyl halide or anhydride functional group and ii) applying the subject monomer to the thin film polyamide layer. The invention includes many additional embodiments.
Abstract:
A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.