Unsaturated oxime ethers and their use as fungicides and insecticides
    21.
    发明授权
    Unsaturated oxime ethers and their use as fungicides and insecticides 失效
    不饱和肟醚及其作为杀菌剂和杀虫剂的用途

    公开(公告)号:US06177462B1

    公开(公告)日:2001-01-23

    申请号:US09237403

    申请日:1999-01-26

    IPC分类号: C07C32700

    摘要: Compounds with fungicidal and insecticidal properties having formula wherein X is N or CH; Y is O, S or NR6; A is independently hydrogen, halo, cyano, (C1-C12)alkyl, or (C1-C12)alkoxy; R1 and R6 is independently hydrogen or (C1-C4)alkyl; R2 is independently hydrogen, (C1-C12)alkyl, halo(C1-C12)alkyl, (C3-C7)cycloalkyl, (C2-C8)alkenyl, halo(C2-C8)alkenyl, (C2-C8)alkynyl, halo(C2-C8)alkynyl, aryl, aralkyl, heterocyclic, or heterocyclic(C1-C4)alkyl; R3 is independently hydrogen or (C1-C4)alkyl; R4 and R5 is independently hydrogen, (C1-C4)alkyl, aryl, aralkyl, aryl(C2-C8)alkenyl, aryl(C2-C8)alkynyl, heterocyclic, or heterocyclic(C1-C4)alkyl wherein if one of R4 and R5 is hydrogen or (C1-C4)alkyl than the other of R4 and R5 is other than hydrogen or (C1-C4)alkyl, and its enantiomers and stereoisomers and agronomically acceptable salts.

    摘要翻译: 具有杀虫和杀虫性质的化合物,其具有式(X)的化合物是N或CH; Y是O,S或NR6; A独立地是氢,卤素,氰基,(C1-C12)烷基或(C1-C12)烷氧基; R1和R6独立地是氢或(C1-C4)烷基; R2独立地是氢 ,(C 1 -C 12)烷基,(C 1 -C 12)烷基,(C 3 -C 7)环烷基,(C 2 -C 8)烯基,卤代(C 2 -C 8)烯基,(C 2 -C 8)炔基, (C 1 -C 4)烷基; R 4和R 5独立地是氢,(C 1 -C 4)烷基,芳基,芳烷基,芳基(C 1 -C 4) (C 2 -C 8)烷基,其中如果R 4和R 5中的一个是氢或(C 1 -C 4)烷基,其中R 4和R 5中的另一个不是 氢或(C 1 -C 4)烷基,及其对映异构体和立体异构体和农艺学上可接受的盐。

    Aryl and heteroarylcyclopropyl oxime ethers and their use as fungicides
and insecticides

    公开(公告)号:US6063956A

    公开(公告)日:2000-05-16

    申请号:US238196

    申请日:1999-01-27

    摘要: Compounds with fungicidal and insecticidal properties having formula ##STR1## wherein X is N or CH; Z is O, S or NR.sub.8 ; A is hydrogen, halo, cyano, (C.sub.1 -C.sub.12)alkyl, or (C.sub.1 -C.sub.12)alkoxy; R.sub.1 and R.sub.8 are independently hydrogen or (C.sub.1 -C.sub.4)alkyl; R.sub.2 is hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, aryl, aralkyl, heterocyclic, heterocyclic(C.sub.1 -C.sub.4)alkyl or C(R.sub.10).dbd.N--OR.sub.9 ; R.sub.3 is hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, aryl, aralkyl, aryl(C.sub.3 -C.sub.7)cycloalkyl, heterocyclic or heterocyclic(C.sub.1 -C.sub.4)alkyl; R.sub.4 and R.sub.5 are independently hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, halo, cyano, (C.sub.1 -C.sub.4)alkoxycarbonyl, aryl, aralkyl, aryl(C.sub.3 -C.sub.7)cycloalkyl, heterocyclic or heterocyclic(C.sub.1 -C.sub.4)alkyl; R.sub.6 is hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, halo, cyano, (C.sub.1 -C.sub.4)alkoxycarbonyl, aryl, aralkyl, aryl(C.sub.3 -C.sub.7)cycloalkyl, heterocyclic or heterocyclic(C.sub.1 -C.sub.4)alkyl; R.sub.7 is aryl, aralkyl, heterocyclic or heterocyclic(C.sub.1 -C.sub.4)alkyl; R.sub.9 is hydrogen, (C.sub.1 -C.sub.12,)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, (C.sub.1 -C.sub.4)alkylcarbonyl, (C.sub.1 -C.sub.4)alkoxycarbonyl, aryl, or aralkyl; and R.sub.10 is hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, aryl, aralkyl, heterocyclic, or heterocyclic(C.sub.1 -C.sub.4)alkyl.

    Benzyloxy substituted aromatics and their use as fungicides and
insecticides
    26.
    发明授权
    Benzyloxy substituted aromatics and their use as fungicides and insecticides 失效
    苄氧基取代的芳族化合物及其作为杀真菌剂和杀虫剂的用途

    公开(公告)号:US5886015A

    公开(公告)日:1999-03-23

    申请号:US867376

    申请日:1997-06-02

    摘要: Compounds with fungicidal and insecticidal properties having formula ##STR1## wherein A is N or CH; V is O or NH; m and n are independently 0 and 1 provided that m+n is not 2, and U and W are independently O or N;such that when U and W are both N and n is 0 and m is 1, the bond between the 1 and 5 atoms is a double bond and the bond between the C.sub.3 -C.sub.4 atoms is a single or double bond, and when n is 1 and m is 0, the bond between the 2 and 3 atoms is a double bond and the bond between the C.sub.4 -C.sub.5 atoms is a single or double bond;and that when U is O and W is N and n=m=0, the bond between the 1 and 5 atoms is a double bond and the bond between the C.sub.3 -C.sub.4 atoms is a single or double bond;and that when U is N and W is O and n=m=0, the bond between the 2 and 3 atoms is a double bond and the bond between the C.sub.4 -C.sub.5 atoms is a single or double bond;X is independently selected from hydrogen, halo, (C.sub.1 -C.sub.4)alkyl, and C.sub.1 -C.sub.4)alkoxy;R is independently selected from hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl(C.sub.1 -C.sub.12)alkoxy(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.4)alkyl, aryl, aralkyl, heterocyclic andR.sub.1 is independently selected from hydrogen, (C.sub.1 -C.sub.6)alkyl, and aryl; andZ is selected from (C.sub.1 -C.sub.6)alkyl, halo(C.sub.1 -C.sub.6)alkyl, (C.sub.3 -C.sub.7) cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.4)alkyl, aryl and aralkyl.

    摘要翻译: 具有式(I)的具有杀真菌和杀虫性质的化合物,其中A是N或CH; V是O或NH; m和n分别为0和1,条件是m + n不为2,U和W独立地为O或N; 使得当U和W均为N且n为0且m为1时,1至5个原子之间的键为双键,并且C 3 -C 4原子之间的键为单键或双键,并且当n为 1和m为0,2和3原子之间的键是双键,C4-C5原子之间的键是单键或双键; 当U为O且W为N且n = m = 0时,1与5原子之间的键为双键,C3-C4原子之间的键为单键或双键; 当U为N且W为O且n = m = 0时,2和3原子之间的键为双键,C4-C5原子之间的键为单键或双键; X独立地选自氢,卤素,(C1-C4)烷基和C1-C4)烷氧基; (C 1 -C 12)烷基,(C 2 -C 8)烯基,(C 2 -C 8)炔基(C 1 -C 12)烷氧基(C 1 -C 12)烷基, -C 7)环烷基,(C 3 -C 7)环烷基(C 1 -C 4)烷基,芳基,芳烷基,杂环和R 1独立地选自氢,(C 1 -C 6)烷基和芳基; (C 1 -C 6)烷基,(C 3 -C 7)环烷基,(C 3 -C 7)环烷基(C 1 -C 4)烷基,芳基和芳烷基。