公开(公告)号：US11834544B2

公开(公告)日：2023-12-05

申请号：US16980320

申请日：2019-03-11

Applicant: 3M Innovative Properties Company ,  The Penn State Research Foundation

Inventor： Michael A. Yandrasits ,  Carl A. Laskowski ,  Timothy M. Gillard ,  Michael Hickner ,  Liang Zhu

IPC: C08F8/32 ,  C08F8/44 ,  C08F210/08 ,  C08F212/12 ,  C08F214/16 ,  C08F214/18 ,  C08J5/22 ,  H01M8/1004

CPC classification number: C08F8/32 ,  C08F8/44 ,  C08F210/08 ,  C08F212/12 ,  C08F214/16 ,  C08F214/18 ,  C08J5/2243 ,  H01M8/1004

Abstract: Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.

公开(公告)号：US20210002407A1

公开(公告)日：2021-01-07

申请号：US15733579

申请日：2019-03-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Timothy M. Gillard ,  Carl A. Laskowski ,  Michael A. Yandrasits

IPC: C08F297/02 ,  C08F8/32

Abstract: Described herein are nitrogen-containing multi-block copolymers, as well as methods for making such multi-block copolymers, and articles comprising such multi-block copolymers. The nitrogen-containing multi-block copolymers contains at least one A block comprising polyisoprene; and at least one B block comprising amino-functionalized polybutadiene, the amino-functionalized polybutadiene comprising nitrogen-containing pendant groups.

公开(公告)号：US09276284B2

公开(公告)日：2016-03-01

申请号：US14100132

申请日：2013-12-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Eric J. Iverson ,  Daniel M. Pierpont ,  Michael A. Yandrasits ,  Steven J. Hamrock ,  Stephan J. Obradovich ,  Donald G. Peterson

IPC: H01M8/02 ,  H01M8/24 ,  H01M8/10

CPC classification number: H01M8/2418 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/0286 ,  H01M8/1004 ,  H01M8/1016 ,  H01M8/242 ,  H01M2008/1095 ,  Y02E60/521 ,  Y02P70/56

Abstract: A fuel cell roll good subassembly is described that includes a plurality of individual electrolyte membranes. One or more first subgaskets are attached to the individual electrolyte membranes. Each of the first subgaskets has at least one aperture and the first subgaskets are arranged so the center regions of the individual electrolyte membranes are exposed through the apertures of the first subgaskets. A second subgasket comprises a web having a plurality of apertures. The second subgasket web is attached to the one or more first subgaskets so the center regions of the individual electrolyte membranes are exposed through the apertures of the second subgasket web. The second subgasket web may have little or no adhesive on the subgasket surface facing the electrolyte membrane.

Abstract translation: 描述了包括多个单独的电解质膜的燃料电池辊良好的子组件。 一个或多个第一子垫连接到单独的电解质膜。 每个第一子垫具有至少一个孔，并且第一子垫被布置成使得各个电解质膜的中心区域通过第一子垫的孔露出。 第二子垫包括具有多个孔的腹板。 第二子网腹板附接到一个或多个第一子垫，使得各个电解质膜的中心区域通过第二子网幅的孔露出。 第二子网网在面向电解质膜的子垫表面上可能具有很少或没有粘合剂。

公开(公告)号：US20140134518A1

公开(公告)日：2014-05-15

申请号：US14157875

申请日：2014-01-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Samantha D. Smith ,  Gene H. Shipman ,  Robert M. Floyd ,  Harold Todd Freemyer ,  Steven J. Hamrock ,  Michael A. Yandrasits ,  David G. S. Walton

IPC: H01M8/10

CPC classification number: H01M8/1044 ,  B01D67/0009 ,  B01D67/0011 ,  B01D67/0016 ,  B01D67/0027 ,  B01D69/141 ,  B01D71/34 ,  B01D2323/46 ,  B01D2325/022 ,  B01D2325/20 ,  B01D2325/24 ,  C08J5/2281 ,  C08J2327/16 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1048 ,  H01M8/106 ,  H01M8/1079 ,  H01M8/1083 ,  Y02E60/521 ,  Y02P70/56 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/249953 ,  Y10T428/249958 ,  Y10T428/249959 ,  Y10T428/249978 ,  Y10T428/249987 ,  Y10T428/3154

Abstract: Shaped microporous articles are produced from polyvinylidene fluoride (PVDF) and nucleating agents using thermally induced phase separation (TIPS) processes. The shaped microporous article is oriented in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0. The shaped article may also comprise a diluent, glyceryl triacetate. The shaped microporous article may also have the micropores filled with a sufficient quantity of ion conducting electrolyte to allow the membrane to function as an ion conductive membrane. The method of making a microporous article comprises the steps of melt blending polyvinylidene fluoride, nucleating agent and glyceryl triacetate; forming a shaped article of the mixture; cooling the shaped article to cause crystallization of the polyvinylidene fluoride and phase separation of the polyvinylidene fluoride and glyceryl triacetate; and stretching the shaped article in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0.

Abstract translation: 成型微孔制品由聚偏氟乙烯（PVDF）和使用热诱导相分离（TIPS）工艺的成核剂制备。 成形的微孔制品以至少约1.1至1.0的拉伸比在至少一个方向上取向。 成型制品还可以包含稀释剂，三乙酸甘油酯。 成形的微孔制品也可以具有填充足量的离子导电电解质的微孔，以允许膜用作离子导电膜。 制造微孔制品的方法包括熔融共混聚偏二氟乙烯，成核剂和三乙酸甘油酯的步骤; 形成混合物的成型制品; 冷却成型制品以引起聚偏二氟乙烯的结晶和聚偏二氟乙烯和甘油三乙酸酯的相分离; 并且以至少约1.1至1.0的拉伸比在至少一个方向上拉伸成形制品。

公开(公告)号：US20140093807A1

公开(公告)日：2014-04-03

申请号：US14100132

申请日：2013-12-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Eric J. Iverson ,  Daniel M. Pierpont ,  Michael A. Yandrasits ,  Steven J. Hamrock ,  Stephan J. Obradovich ,  Donald G. Peterson

IPC: H01M8/24

CPC classification number: H01M8/2418 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/0286 ,  H01M8/1004 ,  H01M8/1016 ,  H01M8/242 ,  H01M2008/1095 ,  Y02E60/521 ,  Y02P70/56

Abstract: A fuel cell roll good subassembly is described that includes a plurality of individual electrolyte membranes. One or more first subgaskets are attached to the individual electrolyte membranes. Each of the first subgaskets has at least one aperture and the first subgaskets are arranged so the center regions of the individual electrolyte membranes are exposed through the apertures of the first subgaskets. A second subgasket comprises a web having a plurality of apertures. The second subgasket web is attached to the one or more first subgaskets so the center regions of the individual electrolyte membranes are exposed through the apertures of the second subgasket web. The second subgasket web may have little or no adhesive on the subgasket surface facing the electrolyte membrane.

Abstract translation: 描述了包括多个单独的电解质膜的燃料电池辊良好的子组件。 一个或多个第一子垫连接到单独的电解质膜。 每个第一子垫具有至少一个孔，并且第一子垫被布置成使得各个电解质膜的中心区域通过第一子垫的孔露出。 第二子垫包括具有多个孔的腹板。 第二子网腹板附接到一个或多个第一子垫，使得各个电解质膜的中心区域通过第二子网幅的孔露出。 第二子网网在面向电解质膜的子垫表面上可能具有很少或没有粘合剂。