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公开(公告)号:US5100930A
公开(公告)日:1992-03-31
申请号:US544978
申请日:1990-06-28
申请人: Yoshiharu Fukui , Kazuhisa Kuroda
发明人: Yoshiharu Fukui , Kazuhisa Kuroda
摘要: Disclosed herein is a food container of a resin composition composed of a polyolefin and an inorganic filler, said resin composition containing (i) a phenolic antioxidant and (ii) a slip agent and/or antistatic agent, said phenolic antioxidant being at least one kind selected from .beta.-(4-hydroxy-3-t-butyl-5-alkylphenyl)propionic acid esters, hindered phenols having an isocyanuric acid ester, 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, specific phenol compounds, and 6-hydroxychroman compounds. The food container has a low level of offensive odors and discoloration.
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公开(公告)号:US5086099A
公开(公告)日:1992-02-04
申请号:US606940
申请日:1990-10-31
申请人: Yoshiharu Fukui , Kazuhisa Kuroda
发明人: Yoshiharu Fukui , Kazuhisa Kuroda
IPC分类号: C08K5/1575 , C08K5/20
CPC分类号: C08K5/1575 , C08K5/20
摘要: An inorganic filler-containing polyolefin composition which comprises100 parts by weight of a polyolefin,1-100 parts by weight of an inorganic filler,0.01-1.0 part by weight of a phenolic antioxidant represented by the general formula (I) shown below, andat least one compound selected from the group consisting of the compounds represented by the general formulas (II) to (IV) shown below, and optionally 0.01-1.0 part by weight of a sulfur antioxidant and/or 0.01-2.0 parts by weight of a light stabilizer. ##STR1## wherein R.sub.1 represents an alkyl group of 1-3 carbon atoms,R.sub.2 --CO--NH--(CH.sub.2).sub.n --HN--CO--R.sub.2 (II) wherein R.sub.2 represents an alkyl group or an alkenyl group of 5-21 carbon atoms, and n is an integer of 1 to 6.R.sub.3 --CONH.sub.2 (III) wherein R.sub.3 represents an alkyl group of an alkenyl group of 5-21 carbon atoms, ##STR2## wherein R.sub.4 represents an alkyl group, an alkenyl group or an acyl group (R'--CO) of 8-18 carbon atoms, m and n are integers which meet m+n=2 to 10, R' represents an aliphatic carbon chain which may be saturated or unsaturated, and R.sub.5 represents an alkyl group or an alkenyl group of 7-17 carbon atoms.Excellent thermal-oxidation stability and/or light stability are obtained.
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公开(公告)号:US4985480A
公开(公告)日:1991-01-15
申请号:US348418
申请日:1989-05-08
申请人: Yoshiharu Fukui , Kazuhisa Kuroda
发明人: Yoshiharu Fukui , Kazuhisa Kuroda
IPC分类号: C08K5/1575 , C08K5/20
CPC分类号: C08K5/1575 , C08K5/20
摘要: An inorganic filler-containing polyolefin composition which comprises100 parts by weight of a polyolefin,1-100 parts by weight of an inorganic filler.0.01-1.0 part by weight of a phenolic antioxidant represented by the general formula (I) shown below, andat least one compound selected from the group consisting of the compounds represented by the general formulas (II) to (IV) shown below, and optionally 0.01-1.0 part by weight of a sulfur antioxidant and/or 0.01-2.0 parts by weight of a light stabilizer. ##STR1## wherein R.sub.1 represents an alkyl group of 1-3 carbon atoms,R.sub.2 --CO--NH--(CH.sub.2).sub.n --HN--CO--R.sub.2 (II) wherein R.sub.2 represents an alkyl group or an alkenyl group of 5-21 carbon atoms, and n is an integer of 1 to 6.R.sub.3 --COHN.sub.2 (III) wherein R.sub.3 represents an alkyl group or an alkenyl group of 5-21 carbon atoms. ##STR2## wherein R.sub.4 represents an alkyl group, an alkenyl group or an acyl group (R'-CO) of 8-18 carbon atoms, m and n are integers which meet m+n=2 to 10, R' represents an aliphatic carbon chain which may be saturated or unsaturated, and R.sub.5 represents an alkyl group or an alkenyl group of 7-17 carbon atoms.Excellent thermal-oxidation stability and/or light stability are obtained.
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公开(公告)号:US4603174A
公开(公告)日:1986-07-29
申请号:US686865
申请日:1984-12-27
申请人: Tadayuki Okada , Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
发明人: Tadayuki Okada , Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
IPC分类号: B29C55/00 , B29C55/02 , B29K23/00 , B29L7/00 , C08J5/18 , C08L23/12 , C08L23/14 , C08L23/20 , C08L23/04
CPC分类号: C08J5/18 , C08L23/12 , C08L23/142 , C08J2323/10 , C08L23/20 , C08L2314/02 , Y10S428/91 , Y10T428/31913
摘要: A stretched polypropylene film having excellent see-through characteristics, which is prepared by stretching in at least one direction a polypropylene resin sheet containing 0.05 ppm to 10,000 ppm by weight of a 3-position branched .alpha.-olefin unit and/or a vinyl cycloalkane unit, each having at least 6 carbon atoms.
摘要翻译: 一种拉伸聚丙烯薄膜,具有优异的透视特性,其通过至少一个方向拉伸含有0.05ppm至10,000ppm重量的3-位支链α-烯烃单元和/或乙烯基环烷烃单元的聚丙烯树脂板 各自具有至少6个碳原子。
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公开(公告)号:US4433110A
公开(公告)日:1984-02-21
申请号:US255005
申请日:1981-04-17
IPC分类号: C08F297/08
CPC分类号: C08F297/08 , Y10S526/916
摘要: A propylene block copolymer produced by polymerizing propylene, ethylene and an .alpha.-olefin having 4 to 8 carbon atoms in two stages with a Zieglar-Natta catalyst by a process which comprises (A) supplying propylene and ethylene in the first stage and propylene and the .alpha.-olefin in the second stage, or (B) supplying propylene and the .alpha.-olefin in the first stage and propylene and ethylene in the second stage, to the polymerization system, wherein the amounts of propylene and ethylene supplied in the first stage of (A) or in the second stage of (B) are 90 to 99 wt % and 10 to 1 wt % based on the total amount of propylene and ethylene supplied in the first stage of (A) or in the second stage of (B), respectively, the amounts of propylene and the .alpha.-olefin supplied in the second stage of (A) or in the first stage of (B) are 60 to 98 wt % and 40 to 2 wt % based on the total amount of propylene and the .alpha.-olefin supplied in the second stage of (A) or in the first stage of (B), respectively, and the amounts of copolymers formed in the first and second stages are 20 to 90 wt % and 80 to 10 wt % based on the final block copolymer, respectively.
摘要翻译: 通过包括(A)在第一阶段中供应丙烯和乙烯的方法,用齐格列 - 纳塔催化剂将丙烯,乙烯和具有4至8个碳原子的碳原子的α-烯烃分两步制备的丙烯嵌段共聚物,其中丙烯和 第二阶段中的α-烯烃或(B)将第一阶段中的丙烯和α-烯烃和第二阶段中的丙烯和乙烯供应到聚合体系中,其中在第一阶段中供应的丙烯和乙烯的量 (A)或(B)的第二阶段中(A)或(B)的第二阶段中的丙烯和乙烯的总量为90〜99重量%,10〜1重量% )在(A)或第(B)的第一阶段中供应的丙烯和α-烯烃的量分别为基于丙烯总量的60至98重量%和40至2重量% 和在(A)或第一阶段的第二阶段中提供的α-烯烃 (B),第一和第二阶段中形成的共聚物的量分别为最终嵌段共聚物的20〜90重量%和80〜10重量%。
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公开(公告)号:US4963605A
公开(公告)日:1990-10-16
申请号:US324538
申请日:1989-03-16
申请人: Yoshiharu Fukui , Kazuhisa Kuroda , Tamaki Ishii , Manji Sasaki
发明人: Yoshiharu Fukui , Kazuhisa Kuroda , Tamaki Ishii , Manji Sasaki
IPC分类号: C08K5/00 , C08K5/1575 , C08K5/378
CPC分类号: C08K5/1575 , C08K5/00 , C08K5/378
摘要: The invention relates to a stabilized polyolefin composition, which composition is stabilized against deterioration caused by contact with heavy metals and improved in coloration properties. This is achieved by blending a polyolefin with:(A) a phenolic compound represented by the formula (I), ##STR1## wherein R.sub.1 represents a C.sub.1 -C.sub.3 alkyl group, (B) a metal deactivator having one or more ##STR2## groups in the side chain, and (C) a sulfur-containing compound represented by the formula (II-1), (II-2), (II-3) or (II-4): ##STR3## wherein R.sub.2 represents a C.sub.4 -C.sub.20 alkyl group, ##STR4## wherein R.sub.3 represents a C.sub.4 -C.sub.20 alkyl group, ##STR5## wherein R.sub.4 represents a C.sub.3 -C.sub.18 alkyl group, and R.sub.5 and R.sub.6 independently represent a hydrogen atom or a C.sub.1 -C.sub.6 alkyl group, ##STR6## wherein R.sub.7 represents a C.sub.3 -C.sub.18 alkyl group.
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公开(公告)号:US4748207A
公开(公告)日:1988-05-31
申请号:US753082
申请日:1985-07-09
IPC分类号: C08L23/00 , C08F210/06 , C08L7/00 , C08L21/00 , C08L23/12 , C08L23/14 , C08L23/18 , C08L23/20 , C08L77/00 , C08L101/00 , C08J5/18 , C08L53/00
CPC分类号: C08L23/12 , C08L23/142 , C08F210/06 , C08L23/20 , C08L2314/02
摘要: A crystalline polypropylene sheet is described, characterized by containing a polymer of a vinylcycloalkane having at least 6 carbon atoms in an amount of 0.05 wt ppm to 1 wt % (calculated as a vinylcycloalkane unit). This sheet is excellent in stiffness and transparency and is suitable for use in the production of various articles such as containers and trays.
摘要翻译: 描述了结晶聚丙烯片材,其特征在于含有0.05重量%至1重量%(以乙烯基环烷烃单元计算)的具有至少6个碳原子的乙烯基环烷烃的聚合物。 该片材的刚度和透明度优异,适用于各种制品如容器和托盘的生产。
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