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公开(公告)号：US5288768A
公开(公告)日：1994-02-22
申请号：US994016
申请日：1992-12-21
IPC分类号： C08G18/32
CPC分类号： C08G18/325 , C08G2101/0025 , C08G2101/005 , C08G2101/0058 , C08G2105/02 , Y10S521/902
摘要： Rigid urea-modified polyisocyanurate foams with improved dimensional stability and flame retardancy have densities of 0.5-20 p.c.f., a limiting oxygen index greater than 22 and dimensional changes at 100% R.H. and 70.degree. C. of less than 2% in any linear dimension and a method of making same. The method comprises reacting an organic polyisocyanate, a blowing agent and an N,N'-dialkyl aromatic diamine in the presence of a trimerization catalyst and, if water is used as the blowing agent, a blowing catalyst, wherein the N,N'-dialkyl aromatic diamine and an amine produced by water, if used, constitute the sole sources of active hydrogen.
摘要翻译： 具有改进的尺寸稳定性和阻燃性的刚性尿素改性的聚异氰脲酸酯泡沫体具有0.5-20pf的密度，大于22的极限氧指数和在100％RH和70℃下的尺寸变化，在任何线性尺度上小于2％ 一种制作方法。 该方法包括在三聚催化剂存在下使有机多异氰酸酯，发泡剂和N，N'-二烷基芳族二胺反应，如果使用水作为发泡剂，则发泡催化剂，其中N， 二烷基芳族二胺和由水生成的胺（如果使用的话）构成活性氢的唯一来源。
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公开(公告)号：US4960620A
公开(公告)日：1990-10-02
申请号：US368462
申请日：1989-06-19
申请人： David W. House , Ray V. Scott, Jr.
发明人： David W. House , Ray V. Scott, Jr.
CPC分类号： C08G18/168 , C08G18/10 , C08G18/161
摘要： The polyurethanes and polyureas resulting from ambient-temperature-curing isocyanate-terminated urethane prepolymers with N-alkyl-substituted aromatic polyamines and, optionally, with an added polyol, but primary amine-free, in the presence of a combination catalyst comprising an aliphatic carboxylic acid, e.g., adipic, stearic, oleic acids, and an organometallic catalyst containing, e.g., tin, mercury, bismuth, etc. are broadly useful as coating on the surface of objects made of metal, wood, glass, plastic or masonry materials such as concrete, bricks, etc. or as castings cured in situ. One-shot and quasi-prepolymer systems are also disclosed. The diamine N,N'-di-(sec-butyl)-4,4'-methylenedianiline is a particularly useful diamine.
摘要翻译： 由包含N-烷基取代的芳族多胺的环境温度固化的异氰酸酯封端的氨基甲酸酯预聚物和任选地与添加的多元醇但不含伯胺的聚氨酯和聚脲在包含脂族羧酸的组合催化剂存在下得到的聚氨酯和聚脲 酸，例如己二酸，硬脂酸，油酸和含有例如锡，汞，铋等的有机金属催化剂可广泛用于在由金属，木材，玻璃，塑料或砖石材料制成的物体的表面上涂覆，例如 作为混凝土，砖等，或作为原位固化的铸件。 还公开了单稳态和准预聚体系。 二胺N，N'-二（仲丁基）-4,4'-亚甲基二苯胺是特别有用的二胺。
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23.发明授权Secondary aromatic diamines as curing agents in polyurethane and polyurea manufacture by reaction injection molding 失效二级芳族二胺作为聚氨酯和聚脲的固化剂通过反应注射成型制备
公开(公告)号：US4801674A
公开(公告)日：1989-01-31
申请号：US28511
申请日：1987-03-20
申请人： Ray V. Scott, Jr. , David W. House
发明人： Ray V. Scott, Jr. , David W. House
CPC分类号： C08G18/325 , C08G18/6529 , C08G2120/00
摘要： N,N'-disubstituted diamines are effective curing agents in combination with other polyamines and polyols in reaction injection molding for a diverse class of polyisocyanates. The diamines provide a broad spectrum of cure times, as well as giving elastomers an interesting and useful diversity of properties. Such diamines may be used as a constituent in a blend of polyamines as the isocyanate-reactive component, in which case the elastomer may be viewed as predominantly a polyurea, or as a constituent in a blend with polyols, in which case the elastomer may be viewed as an elastomer with both urethane and urea segments.
摘要翻译： N，N'-二取代的二胺是在多种多异氰酸酯的反应注射成型中与其它多胺和多元醇组合的有效固化剂。 二胺提供广泛的固化时间，以及赋予弹性体一种有趣和有用的多样性。 这种二胺可以作为多胺的混合物中的组分用作异氰酸酯反应性组分，在这种情况下，弹性体可以主要视为聚脲，或作为与多元醇的共混物中的组分，在这种情况下，弹性体可以是 被视为具有氨基甲酸酯和尿素段的弹性体。
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公开(公告)号：US4714512A
公开(公告)日：1987-12-22
申请号：US821722
申请日：1986-01-23
申请人： David W. House , Ray V. Scott, Jr.
发明人： David W. House , Ray V. Scott, Jr.
CPC分类号： C08G18/325 , C08G18/10 , Y10T428/31551
摘要： The polyurethanes resulting from curing isocyanate-terminated urethane prepolymers with a N,N'-dialkylmethylenedianiline are broadly useful as coatings on the surface of objects made of metal, wood, glass, or plastic. Such coatings may be made based on either a 1-pack systemor 2-pack system. The diamine N,N'-di(2-butyl)4,4'-methylenedianiline is a particularly useful diamine.
摘要翻译： 由固化异氰酸酯封端的氨基甲酸酯预聚物与N，N'-二烷基亚甲基二苯胺得到的聚氨酯广泛用作金属，木材，玻璃或塑料制成的物体表面上的涂层。 这种涂层可以基于1包装系统或2包装系统制成。 二胺N，N'-二（2-丁基）4,4'-亚甲基二苯胺是特别有用的二胺。
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25.发明授权Alkylated triamines and higher polyamines as curing agents in polyurethane manufacture 失效烷基化三胺和较高的多胺作为聚氨酯制造中的固化剂
公开(公告)号：US4709003A
公开(公告)日：1987-11-24
申请号：US836872
申请日：1986-03-06
CPC分类号： C08G18/10
摘要： Largely alkylated polyamines which may be viewed as low molecular weight polymers of x-amino-y-methylenephenyl are effective curing agents for a diverse class of urethane prepolymers. The resulting polyurethanes are thermosetting polymers with excellent compression set and tensile strength. Because the properties of the resulting polyurethane vary only slightly near the optimum stoichiometry of curing agent-prepolymer, the use of the curing agents of this invention presents the advantage of being very tolerant of operator mixing error.
摘要翻译： 可被视为x-氨基-y-亚甲基苯基的低分子量聚合物的大量烷基化多胺是用于各种类型的氨基甲酸酯预聚物的有效固化剂。 所得聚氨酯是具有优异的压缩永久变形和拉伸强度的热固性聚合物。 由于所得聚氨酯的性质在固化剂 - 预聚物的最佳化学计量附近仅略微变化，所以使用本发明的固化剂具有非常容忍操作者混合误差的优点。
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公开(公告)号：US4505845A
公开(公告)日：1985-03-19
申请号：US619742
申请日：1984-06-11
申请人： David W. House
发明人： David W. House
摘要： The polymers resulting from reaction of a 1,1,2,2-tetrahaloethane with a diamine of the type H.sub.2 NANH.sub.2, where A is a divalent aromatic moiety, may be doped with a variety of materials to afford electrically conducting polymeric compositions. Poly(ethyleneiminobenzene) is an especially useful material which may be prepared in good yield from the reactants in a dipolar aprotic solvent in the presence of a base.
摘要翻译： 由1,1,2,2-四卤乙烷与H 2 NANH 2的二胺（其中A是二价芳族部分）反应得到的聚合物可掺杂各种材料以提供导电聚合物组合物。 聚（亚乙基亚氨基苯）是一种特别有用的材料，其可以在碱的存在下在偶极非质子溶剂中由反应物以良好的产率制备。
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公开(公告)号：US4459222A
公开(公告)日：1984-07-10
申请号：US377112
申请日：1982-05-11
申请人： David W. House
发明人： David W. House
CPC分类号： H01B1/128
摘要： Although poly(nitrilo-1,4-phenylene nitrilomethylidine-1,4-phenylene methylidine) is an insulator, it can be doped with both electron acceptors and electron donors to afford p- and n-type semiconductors. The iodine doped material is more stable in air than many prior art conducting polymers.
摘要翻译： 虽然聚（亚硝基-1,4-亚苯基亚氮基亚甲基-1,4-亚苯基亚甲基）是绝缘体，但是它可以掺杂有电子受体和电子给体以提供p-型和n型半导体。 碘掺杂材料在空气中比许多现有技术的导电聚合物更稳定。
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28.发明授权Bis-(N-alkylaminocyclohexyl)methanes as curing agents in polyurethane and polyurea flexible foam manufacture 失效双 - （N-烷基氨基环己基）甲烷作为聚氨酯和聚脲柔性泡沫制造中的固化剂
公开(公告)号：US5470890A
公开(公告)日：1995-11-28
申请号：US262106
申请日：1994-06-17
CPC分类号： C08G18/8009 , C08G18/10 , C08G18/3234 , C08G18/6685 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： Flexible foam resistant to both photochemical and oxidative degradation result from the use of bis(N-alkylaminocyclohexyl)methanes as curing agents for polyisocyanates or polyisocyanate prepolymers. The chain extenders may be used alone or in combination with other polyamines and with polyols. Where the polyisocyanate or polyisocyanate prepolymer is also aliphatic there is outstanding resistance to yellowing.
摘要翻译： 由于使用双（N-烷基氨基环己基）甲烷作为多异氰酸酯或多异氰酸酯预聚物的固化剂，耐光化学和氧化降解的柔性泡沫体。 扩链剂可以单独使用或与其它多胺和多元醇组合使用。 当多异氰酸酯或多异氰酸酯预聚物也是脂肪族时，其具有突出的耐黄变性。
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29.发明授权
公开(公告)号：US5223551A
公开(公告)日：1993-06-29
申请号：US813559
申请日：1991-12-26
IPC分类号： C08G18/32
CPC分类号： C08G18/325 , C08G2101/0025 , C08G2101/005 , C08G2101/0058 , C08G2105/02 , Y10S521/902
摘要： Rigid urea-modified polyisocyanurate foams with improved dimensional stability and flame retardancy have densities of 1-12 p.c.f., a limiting oxygen index greater than 22 and dimensional changes at 100% R.H. and 70.degree. C. of less than 2% in any linear dimension and a method of making same. The method comprises reacting an organic polyisocyanate, a blowing agent and an N,N'-dialkyl aromatic diamine in the presence of a trimerization catalyst and, if water is used as the blowing agent, a blowing catalyst, wherein the N,N'-dialkyl aromatic diamine and an amine produced by water, if used, constitute the sole sources of active hydrogen.
摘要翻译： 具有改进的尺寸稳定性和阻燃性的刚性脲改性聚异氰脲酸酯泡沫具有1-12pcf的密度，大于22的极限氧指数和在100％RH和70℃下的尺寸变化在任何线性尺寸上小于2％ 一种制作方法。 该方法包括在三聚催化剂存在下使有机多异氰酸酯，发泡剂和N，N'-二烷基芳族二胺反应，如果使用水作为发泡剂，则发泡催化剂，其中N， 二烷基芳族二胺和由水生成的胺（如果使用的话）构成活性氢的唯一来源。
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30.发明授权N,N'-dialkylphenylenediamines as curing agents in polyurethane and polyurea manufacture by reaction injection molding 失效N，N'-二烷基苯二胺作为聚氨酯和聚脲的固化剂通过反应注射成型制备
公开(公告)号：US4948861A
公开(公告)日：1990-08-14
申请号：US265098
申请日：1988-10-31
CPC分类号： C08G18/6529 , C08G18/325 , C08G2120/00
摘要： N,N'-dialkyl- and diarylphenylenediamines are effective curing agents in combination with other polyamines and polyols in reaction injection molding for a diverse class of polyisocyanates. The diamines provide a broad spectrum of cure times, as well as giving elastomers an interesting and useful diversity of properties. Such polyamines may be used as a constituent in a blend of polyamines as the isocyanate-reactive component, in which case the elastomer may be viewed as predominantly a polyurea, or as a constituent in a blend with polyols, in which case the elastomer may be viewed as an elastomer with both urethane and urea segments.
摘要翻译： N，N'-二烷基 - 和二芳基苯二胺是在多种多异氰酸酯的反应注射成型中与其它多胺和多元醇组合的有效固化剂。 二胺提供广泛的固化时间，以及赋予弹性体一种有趣和有用的多样性。 这种多胺可以作为多胺的混合物中的组分用作异氰酸酯反应性组分，在这种情况下，弹性体可以主要看作聚脲，或作为与多元醇的共混物中的组分，在这种情况下，弹性体可以是 被视为具有氨基甲酸酯和尿素段的弹性体。
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